5,554 results on '"WOOD"'
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2. WOOD HEMICELLULOSES. I.
- Author
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TIMELL TE
- Subjects
- Cellulose, Chemical Phenomena, Chemistry, Polysaccharides, Research, Wood
- Published
- 1964
3. MOUSE-PROTECTIVE ANTIGENS IN CULTURE FLUIDS OF STAPHYLOCOCCUS AUREUS, STRAIN WOOD 46.
- Author
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ROBSON JE and FISHER S
- Subjects
- Adsorption, Animals, Mice, Antibody Formation, Antigens, Chemical Phenomena, Chemistry, Chemistry Techniques, Analytical, Chromatography, Coagulase, Culture Media, DNA, Deoxyribonucleases, Electrophoresis, Hemolysin Proteins, Hydrogen-Ion Concentration, Leukocidins, Precipitin Tests, Proteins, Research, Staphylococcus, Staphylococcus aureus, Toxicology, Wood
- Published
- 1965
4. [ON QUINONES ISOLATED FROM THE WOOD OF TABEBUIA AVELLANEDAE LOR. EX GRISEB].
- Author
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CASINOVI CG, MARINI BETTOLO GB, LIMAOG DA, DALIAMAIA ME, and D ALBUQUERQUE IL
- Subjects
- Chemical Phenomena, Chemistry, Quinones, Research, Tabebuia, Wood
- Published
- 1963
5. A BIBLIOMETRIC REVIEW OF RESEARCH TRENDS IN WOOD ANATOMY AND CHEMISTRY.
- Author
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ANTWI, Kwaku, BIH, Francis Kofi, and APPIAH-YEBOAH, Joseph
- Subjects
- *
LITERATURE reviews , *EVIDENCE gaps , *WOOD chemistry , *WOOD , *BIBLIOMETRICS , *RESEARCH personnel , *BIBLIOGRAPHIC databases - Abstract
Those who work with wood should have a basic knowledge of wood anatomy and chemistry so they can understand how different anatomical and chemical features influence wood properties and, in turn, how these properties contribute to different treatments and final wood utilization. However, little attempt has been made to map global research trends in wood anatomy and chemistry. This paper presents a bibliometric review of research trends in wood anatomy and chemistry to determine research trends and gaps in these research areas. A total of 183 publications on wood anatomy and chemistry from 1974 to 2023 were reviewed. The analysis was done with the VOSviewer software (version 1.6.13). The analysis focused on the bibliographic coupling of countries, co-authorship of authors, citation of documents, and co-occurrence of keywords, which were presented as network visualization maps. The findings revealed that the wood anatomy and chemistry publication trends, although not completely gradient, have been upwards since 2000. Countries including Germany, the United States, Switzerland, the United Kingdom, Brazil, the Netherlands, China, Italy, Mexico, Spain, the Czech Republic, Canada, Australia, Chile, Finland, France, Sweden, and Japan had a great impact on this research area. It also became evident that African countries lag in this area of research. Only one data source - Scopus - was used. It has a wide coverage of publications from diverse areas and provides researchers with information on the most important academic literature in any specific scientific domain. Therefore, the representation of publications presented in this study is limited to only the Scopus data source. [ABSTRACT FROM AUTHOR]
- Published
- 2024
6. A Wooden Carbon-Based Photocatalyst for Water Treatment
- Author
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Chang Zhang, Shangjie Ge-Zhang, Yudong Wang, and Hongbo Mu
- Subjects
photocatalyst ,biochar ,sewage treatment ,wood sponge ,wood ,Biology (General) ,QH301-705.5 ,Chemistry ,QD1-999 - Abstract
Due to a large number of harmful chemicals flowing into the water source in production and life, the water quality deteriorates, and the use value of water is reduced or lost. Biochar has a strong physical adsorption effect, but it can only separate pollutants from water and cannot eliminate pollutants fundamentally. Photocatalytic degradation technology using photocatalysts uses chemical methods to degrade or mineralize organic pollutants, but it is difficult to recover and reuse. Woody biomass has the advantages of huge reserves, convenient access and a low price. Processing woody biomass into biochar and then combining it with photocatalysts has played a complementary role. In this paper, the shortcomings of a photocatalyst and biochar in water treatment are introduced, respectively, and the advantages of a woody biochar-based photocatalyst made by combining them are summarized. The preparation and assembly methods of the woody biochar-based photocatalyst starting from the preparation of biochar are listed, and the water treatment efficiency of the woody biochar-based photocatalyst using different photocatalysts is listed. Finally, the future development of the woody biochar-based photocatalyst is summarized and prospected.
- Published
- 2024
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7. Flexible Polyurethane Adhesives: Predictive Numerical Model Calibration through Experimental Testing at Elevated Temperature
- Author
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Armando La Scala, Klaudia Śliwa-Wieczorek, Fabio Rizzo, Maria Francesca Sabbà, and Bogusław Zając
- Subjects
elevated temperature ,flexible adhesives ,polyurethane ,wood ,numerical analysis ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The thermo-mechanical behavior of polyurethane adhesive joints in wood structures is a crucial aspect that needs to be understood to ensure the durability and safety of timber structures, especially in seismic regions. As mass timber, particularly cross-laminated timber, continues to gain popularity as a building material, it is important to pay special attention to the behavior of connections between the timber elements. The use of flexible polyurethane adhesives presents a promising alternative to conventional mechanical connections in seismic-resistant timber structures. This research highlights the potential of polyurethane-based joints at elevated service temperature, offers a promising alternative to traditional wood joints, and suggests viability for post-fire restoration of wood structures. The response at the interface between wood and polyurethane under flexural stresses is also evaluated, underscoring the broader application possibilities of flexible adhesives in wood construction for mechanical and physical improvements.
- Published
- 2024
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8. Computational Analysis for the Evaluation of Fire Resistance in Constructive Wooden Elements with Protection
- Author
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Domingos Pereira, Elza M. M. Fonseca, and Miguel Osório
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fire ,char layer ,residual cross-section ,wood ,parametric model ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Wood is a material whose properties vary depending on different conditions, being particularly vulnerable to changes induced by high temperatures. When exposed to a fire situation, the wood properties suffer degradation, causing a char layer formation. Despite ensuring the protection of the inner core of the wood, the char layer reduces its resistant section. The evaluation of wood behavior under fire conditions is possible through experimental tests, simplified analytical models, and numerical models. To overcome difficulties in the development of experimental tests and in the approximations made to analytical methods, numerical models allow the evaluation of the fire resistance in a parametric way. First, this study will present a numerical model validated with an experimental test, using the finite element method. The validation of the results is based on the evolution of the temperature field, the char layer formation on the wooden elements, and its residual section, as well as the application of the thermal insulation criterion. The second part of the study evaluates the influence of geometric parameters, associated with different wooden constructive models with gypsum board exposed to fire. Different numerical tests are presented to evaluate the thermal and transient analysis of different wooden constructive elements with gypsum board. This type of constructive element presents cavities, making the numerical analysis in the study complex when approaching real models. The methodology applied allowed us to conclude that, at the same time, a smaller distance between wooden centers, a greater dimension of the wooden beam in height and width, as well as a greater thickness of gypsum board guarantee a better performance of the constructive wooden model.
- Published
- 2024
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9. Light-Induced Colour Changes in Wood Surfaces in Indoor Conditions Determined by an Artificial Accelerated Test: Influence of Wood Species and Coating Materials
- Author
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Mihai-Junior Torcătoru and Maria Cristina Timar
- Subjects
wood ,colour ,clear waterborne coatings ,UV-VIS radiation ,accelerated artificial test ,colour changes ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Stabilising the natural colour of wood species exposed to light in indoor conditions is a challenge that could be better addressed based on a deeper understanding of the occurring phenomena and influencing factors. This paper investigates comparatively the light-induced colour changes for three hardwood species, namely, European maple (Acer pseudoplatanus L.), European ash (Fraxinus excelsior L.) and European walnut (Juglans regia L.), as well as the influence of finishing with three types of clear, colourless waterborne lacquers: acrylic-polyurethane (F1), acrylic (F2) and polyurethane (F3) on their colour stability. Colour measurements in the CIELab system in conjunction with an artificial accelerated ageing test under the action of UV-VIS radiation, simulating natural light passing through window glass, and two types of test samples were employed to highlight the influence and contributions of the wood substrate and of the coating films to the global colour modifications. Coating films applied on 1 mm clear glass slides were employed as a sort of “detachable” finish for this purpose. Direct exposure to UV-VIS light caused visible colour changes for both uncoated and coated wood surfaces, the values of the calculated colour differences (ΔE) after a 72 h exposure being dependant on both the wood species and the coating material. Excepting two situations for walnut, statistically significantly higher colour differences were obtained for the uncoated samples: maple (9.36 units), ash (8.39 units), walnut (6.20 units), compared to the coated ones: maple (4.92–5.71 units), ash (2.25–3.94 units), walnut (4.74–7.70 units). The wood substrates underlying the coating films were found to bring the maximum contribution to the overall colour changes in the clear coated surfaces, while the coating films employed in this research demonstrated a fairly good colour stability to UV-VIS light exposure, with maximum colour changes (∆E) up to only 1.30 units. Overall, the wood species and the type of coating were found as influencing factors in interaction with the light-induced colour changes in wood surfaces in indoor conditions.
- Published
- 2024
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10. Wood-derived carbon anode for sodium-ion batteries
- Author
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Bing Feng, Laiqiang Xu, Zhaoyang Yu, Gonggang Liu, Yuanyuan Liao, Shanshan Chang, and Jinbo Hu
- Subjects
Sodium-ion battery ,Wood ,Wood-derived anode materials ,Hard carbons ,Industrial electrochemistry ,TP250-261 ,Chemistry ,QD1-999 - Abstract
Sodium-ion batteries (SIBs) are utilized as a promising alternative to commercial lithium-ion batteries (LIBs) where hard carbons (HCs) are anticipated to be the first commercially available anode material for SIBs. Among various hard carbon precursors, the wood accounts for more than 30% of the global land cover, making it one of the most abundant sources of biomass materials on the planet. In addition to superior renewability, sustainability and biodegradability, wood and its derivatives still possess some unique advantages such as anisotropic graded porous structure, good mechanical stability and biocompatibility. The purpose of this review is to present a comprehensive overview of the development of research on wood and wood-derived HCs anodes. The basic structural and chemical properties of wood and wood-derived materials are indeed reviewed, as is the performance of wood-derived HCs in SIBs to provide an in-depth comprehension and guidance for the preparation of high-performance wood-based SIBs.
- Published
- 2023
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11. A Bilayered Wood-Poly(3,4-ethylenedioxythiophene):Polystyrene Sulfonate Hydrogel Interfacial Evaporator for Sustainable Solar-Driven Sewage Purification and Desalination
- Author
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Xinye Xu, Qi Zhao, Qi Liu, Junxiao Qiu, Shutong Yuan, Zhixin Wu, Ruping Yang, Jie Cao, Lina Wang, Jingkun Xu, and Baoyang Lu
- Subjects
solar water purification ,interfacial evaporator ,sewage purification and desalination ,PEDOT:PSS hydrogel ,wood ,Chemistry ,QD1-999 - Abstract
Solar-driven interfacial evaporation and purification is a promising solar energy conversion technology to produce clean water or solve water scarcity. Although wood-based photothermal materials have attracted particular interest in solar water purification and desalination due to their rapid water supply and great heat localization, challenges exist given their complicated processing methods and relatively poor stability. Herein, we propose a facile approach for fabricating a bilayered wood-poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (wood-PEDOT:PSS) hydrogel interfacial evaporator by direct drop-casting and dry-annealing. Benefiting from the unique combined merits of the wood-PEDOT:PSS hydrogel evaporator, i.e., excellent light absorption (~99.9%) and efficient photothermal conversion of nanofibrous PEDOT:PSS and the strong hydrophilicity and fast water transport from wood, the as-fabricated bilayered wood-PEDOT:PSS hydrogel evaporator demonstrates a remarkably high evaporation rate (~1.47 kg m−2 h−1) and high energy efficiency (~75.76%) at 1 kW m−2. We further demonstrate the practical applications of such an evaporator for sewage purification and desalination, showing outstanding performance stability and partial salt barrier capability against a continuous 10-day test in simulated seawater and an ultrahigh ion removal rate of 99.9% for metal ion-containing sewage. The design and fabrication of such novel, efficient wood-based interfacial evaporators pave the way for large-scale applications in solar water purification.
- Published
- 2023
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12. Sound Wave Absorption Coefficient and Sound Velocity in Thermally Modified Wood
- Author
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Przemysław Mania, Artur Flach, and Marta Pilarska
- Subjects
wood ,sound absorption coefficient ,sound velocity ,dynamic modulus of elasticity ,heat treatment ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The present work analyses the absorption coefficient of sound waves and the speed of sound propagation in thermally modified wood. The high resistance to weathering, fungi, and better dimensional stability, and therefore the broad physical properties of this material, are well known. However, the literature lacks numerous analyses of its acoustic characteristics. During the study, high-density species, such as oak, red oak, and beech were used, in contrast to pine. Pine wood during this test was characterised by a most rapid increase in the sound absorption coefficient value, in the range of 1000–6300 Hz, and reached the highest value from all wood species. Among all species, the highest value of the examined parameter was obtained for beech wood and pine wood, which were 0.213 (at frequency 3 kHz) and 0.183 (at 6.3 kHz), respectively. The sound velocity decreased for all species only in the tangential direction.
- Published
- 2023
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13. Convolutional Neural Network for Segmenting Micro-X-ray Computed Tomography Images of Wood Cellular Structures
- Author
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Xavier Arzola-Villegas, Carlos Báez, Roderic Lakes, Donald S. Stone, Jane O’Dell, Pavel Shevchenko, Xianghui Xiao, Francesco De Carlo, and Joseph E. Jakes
- Subjects
wood ,cellular structure ,X-ray computed tomography ,convolutional neural network ,segmentation ,relative humidity ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
To further enhance the performance of wood products, improved tools are needed to study in situ cellular scale phenomena like mechanical deformations and moisture swelling. Micro-X-ray computed tomography (μXCT) using brilliant synchrotron light sources now has the spatial and temporal resolution for real-time visualization of phenomena in three-dimensional cellular structures. However, the tradeoff for speed includes the loss of intensity contrast between different types of materials within the imaged structure, such as cell wall and air in wood. This loss of contrast prevents traditional histogram-based segmentation methods from being used effectively. A new convolutional neural network (CNN) approach was therefore developed to segment fast μXCT images of wood into cell wall and air volumes. The fast μXCT and segmentation were demonstrated in the study of moisture swelling in loblolly pine (Pinus taeda) earlywood and latewood cellular structures conditioned at 0%, 33%, 75%, and 95% relative humidity (RH). The CNN segmentation results had a mean intersection over union (IoU) metric accuracy of 96%. Initial analysis of the swelling in the latewood revealed cell walls swelled about 25% when conditioned from 0% to 95% RH. Additionally, the widths of ray cell lumina in the transverse plane of latewood could be observed to increase at higher RH. The segmentation method presented here will facilitate future quantitative analyses in in situ μXCT studies of wood and other similar cellular materials.
- Published
- 2023
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14. Robust, Fire-Retardant, and Water-Resistant Wood/Polyimide Composite Aerogels with a Hierarchical Pore Structure for Thermal Insulation
- Author
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Lu Zhao, Junyong Chen, Defang Pan, and Yan Hou
- Subjects
wood ,polyimide ,hydrophobicity ,thermal insulation ,fire-retardant ,Science ,Chemistry ,QD1-999 ,Inorganic chemistry ,QD146-197 ,General. Including alchemy ,QD1-65 - Abstract
The use of energy-saving materials is an effective strategy for decreasing energy consumption and carbon emission. Wood is a type of biomass material with a natural hierarchical structure, which results in its high thermal insulation. It has been widely used in construction. However, developing wood-based materials without flammability and dimensional instability is still a challenge. Herein, we developed a wood/polyimide composite aerogel with a well-preserved hierarchical pore structure and dense hydrogen bonds inside, resulting in its excellent chemical compatibility and strong interfacial interactions between its two components. This novel wood-based composite was fabricated by removing most hemicellulose and lignin from natural wood, followed by the fast impregnation using an ‘in situ gel’ process. The introduction of polyimide into delignified wood substantially improved its mechanical properties, with the compression resistance being improved by over five times. Notably, the thermal conductivity coefficient of the developed composite was approximately half that of natural wood. Furthermore, the composite exhibited excellent fire-retardancy, hydrophobicity, thermal insulation, and mechanical properties. This study provides a novel method for wood modification, which not only aids interfacial compatibility between wood and polyimide but also retains the properties of the two components. The developed composite can effectively reduce energy consumption, making it promising for practical and complex thermal insulation applications.
- Published
- 2023
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15. Heat and Moisture Induced Stress and Strain in Wooden Artefacts and Elements in Heritage Buildings: A Review
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Giulia Grottesi, Guilherme B. A. Coelho, and Dimitrios Kraniotis
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cultural heritage ,wood ,heat and moisture transport ,stress and strain ,mechanosorptive ,non-destructive techniques (NDT) ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
In the world of cultural heritage, a wide range of artefacts and buildings are made of wood and, therefore, are subjected to moisture-induced stress and strain cycles, owing to environmental fluctuations. Simultaneous action of moisture and mechanical loads lead to a mechanosorptive effect on wood. Therefore, an increase in time-dependent creep, due to mechanical loads, is observed. The assessment of these complex phenomena entails the use of advance and interdisciplinary approaches. Consequently, this article reviews experimental and mathematical methods to study these degradation mechanisms in wooden artefacts and timber elements in heritage buildings. The paper presents the results of a six-step descriptive literature review, providing an overall picture of the ongoing research. Experimental techniques need to be improved so that they are in line with the conservation principles. The combination of experiments and simulations is a reliable predictive approach for better assessing the potential risk damages due to temperature, humidity cycles, and mechanical loads in complex structures. Thus, advanced numerical simulations and mathematical modelling include climate data and experimental measurements. This work also provides an overview of research performed on different categories of cultural heritage characterised by multi-layer structures. The mechanical response to wood–moisture relation is affected by the level of complexity of these structures. Finally, the use of realistic models is limited by knowledge about the material properties and the behaviour of complex structures over time. In addition, research gaps, limitations, and possible future research directions are also provided. This review may represent a starting point for future research on the thermo-hygro-mechanical behaviour of wood heritage.
- Published
- 2023
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16. Advances in Sol-Gel-Based Superhydrophobic Coatings for Wood: A Review
- Author
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Yudong Wang, Shangjie Ge-Zhang, Pingxuan Mu, Xueqing Wang, Shaoyi Li, Lingling Qiao, and Hongbo Mu
- Subjects
wood ,superhydrophobicity ,sol-gel method ,micro-nanomaterials ,Biology (General) ,QH301-705.5 ,Chemistry ,QD1-999 - Abstract
As the focus of architecture, furniture, and other fields, wood has attracted extensive attention for its many advantages, such as environmental friendliness and excellent mechanical properties. Inspired by the wetting model of natural lotus leaves, researchers prepared superhydrophobic coatings with strong mechanical properties and good durability on the modified wood surface. The prepared superhydrophobic coating has achieved functions such as oil-water separation and self-cleaning. At present, some methods such as the sol-gel method, the etching method, graft copolymerization, and the layer-by-layer self-assembly method can be used to prepare superhydrophobic surfaces, which are widely used in biology, the textile industry, national defense, the military industry, and many other fields. However, most methods for preparing superhydrophobic coatings on wood surfaces are limited by reaction conditions and process control, with low coating preparation efficiency and insufficiently fine nanostructures. The sol-gel process is suitable for large-scale industrial production due to its simple preparation method, easy process control, and low cost. In this paper, the research progress on wood superhydrophobic coatings is summarized. Taking the sol-gel method with silicide as an example, the preparation methods of superhydrophobic coatings on wood surfaces under different acid-base catalysis processes are discussed in detail. The latest progress in the preparation of superhydrophobic coatings by the sol-gel method at home and abroad is reviewed, and the future development of superhydrophobic surfaces is prospected.
- Published
- 2023
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17. pH-RESPONSIVE WOOD SLICES FOR THE CONTINUOUS SEPARATION OF LIGHT OIL/WATER/HEAVY OIL TRIPHASE MIXTURES
- Author
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Yanbiao Zhou, Kaige Qu, Lihui Zhang, and Ming La
- Subjects
wood ,pH-responsive ,triphase mixtures ,continuous separation ,Chemistry ,QD1-999 - Abstract
Light oil/water/heavy oil triphase mixtures are common in industrial wastewater, while nearly all separation materials with superwettability can only separate biphase mixtures of light oil/water or/and heavy oil/water. Here, a balsa wood slice with superhydrophilic/superoleophilic property in air was fabricated by a blade-cutting and ethanol-treating process. Therefore, the slice could be dually prewetted with both water and oil and thus showed underwater superoleophobic and underoil superhydrophobic properties without any further chemical modification. Such a slice showed underoil superhydrophobicity in nonbasic environment while transition into underoil superhydrophilicity under basic condition. Combining with the porous structure possessed by wood designed to transport liquids, this superwettability of the treated wood slice could be leveraged in the continuous separation of light oil/water/heavy oil triphase mixtures only driven by gravity with a high permeation flux and separation efficiency. After each separation, the slice was easily recovered by washing with acidic solution, and it could be recycled up to 15 times without any loss of pH responsibility. During repeated cycling separation, the slice exhibited excellent separation stability.
- Published
- 2021
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18. Inhibition of Listeria monocytogenes by Broth Cultures of Surface Microbiota of Wooden Boards Used in Cheese Ripening
- Author
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Kirty Wadhawan, Andrew Steinberger, Scott Rankin, Garret Suen, and Charles Czuprynski
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wood ,cheese ,bacteria ,inhibition ,safety ,Listeria monocytogenes ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Listeria monocytogenes is a significant concern in cheese production. It has been assumed by some that wood surfaces pose a greater risk for pathogen contamination during cheese production. The goal of this study was to evaluate the effect of the microbiota obtained from wooden boards used in cheese ripening on the growth of Listeria monocytogenes. Bacterial communities from the surface of wooden boards obtained from cheese-ripening facilities were inoculated into tryptic soy broth (TSB) and incubated at 11 °C for 48 h. These communities (108 CFU/mL stationary phase cells) were co-incubated with 104–105 CFU/mL L. monocytogenes 2203 at 11 °C for up to eight days. At various times, samples were removed, diluted in sterile saline and plated on modified Oxford agar. Bacterial communities from each of the five boards from three different facilities significantly inhibited growth of L. monocytogenes in vitro, compared to growth of L. monocytogenes 2203 alone. Using 16S rRNA analysis, we identified sequences belonging to the genera Carnobacterium, Leuconostoc and Staphylococcus as the most abundant in the communities grown in TSB. Leuconostoc mesenteroides and Staphylococcus equorum isolated from the most inhibitory community significantly inhibited growth of L. monocytogenes in TSB at 11 °C, compared to growth of L. monocytogenes 2203 alone. These findings suggest that some members of the complex microbial communities on wooden boards in cheese aging facilities might inhibit the growth of L. monocytogenes.
- Published
- 2023
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19. An Analysis on Finnish Wooden Bridge Practices
- Author
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Miro Seppälä, Hüseyin Emre Ilgın, Markku Karjalainen, and Sami Pajunen
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wood ,timber ,wooden bridges ,girder bridge ,structural design ,experts ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
To date, the share of research, teaching materials, and practices related to the use of timber in bridge projects in Finland are quite limited compared to other materials, such as concrete. This article, which also includes a structural design example for dimensioning a girder bridge, focuses on the status, applications and prospects of wood use in bridge construction, reflecting the Finnish professionals’ point of view. Key findings highlighted that: (1) the ideal use of wood would be in private road bridges and light traffic bridges; (2) while the use of wood in the bridge was assessed to be advantageous in terms of ecology, aesthetics, and environmental friendliness, it was reported to be disadvantageous in terms of long-term durability and connection details; (3) concrete and steel, whose prices fluctuate, could gradually be replaced by wood, a renewable material; (4) timber-concrete composite bridges were expected to become widespread in the future; (5) cross-laminated timber (CLT) could open up an opportunity for bridge decks; and (6) service limit state is often decisive for the dimensioning of wooden bridges. It is recommended to implement large-scale public projects for the wooden bridges by creating sustainable business models that will be supported both legitimately and economically by the local government. In this sense, close cooperation between authorities and other key market stakeholders is crucial.
- Published
- 2023
- Full Text
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20. Studies on Some Mechanical Properties of PVC-Wood Fiber Composite
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David Arthur, Danzarami Danlami, Emmanuel Uwaiya, and Augustina Aroh
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wood ,pvc ,composite ,tensile strength formulation ,Chemistry ,QD1-999 - Abstract
In this study some mechanical properties of PVC-Wood fibre composite were investigated. The wood fibre was gotten from a mahogany tree. The sample was moulded and shaped at a temperature of 150oC using a hadraulic hot press and pressure of 3bar for 5mins and the mechanical properties were studied base on varying the wood fibre contents from 0% to 50%. The hardness test carried out using the durometer hardness tester show a decrease in the hardness of the composite as the wood fibre is varied from 0%, 10%, 20%, 30% 40% and 50% and the impact strength of the composite decreases as well in that order. The tensile strength conducted using the Mensato Tensometer show a decrease at 10% wood fibre, while an increase in the wood fibre to 20% show an increase in the tensile strength on further addition of the wood fibre a decrease is noticed. This decrease in tensile strength decreases the strain of the PVC-wood fibre composite and hence increasing the modulus of elasticity of the PVC-wood fibre composite as the wood fibre is been added.
- Published
- 2021
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21. Cas9/gRNA-Mediated Mutations in PtrFLA40 and PtrFLA45 Reveal Redundant Roles in Modulating Wood Cell Size and SCW Synthesis in Poplar
- Author
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Cheng Zhen, Xinguo Hua, Xue Jiang, Guimin Tong, Chunming Li, Chuanping Yang, and Yuxiang Cheng
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PtrFLAs ,Xylem cell size ,SCW synthesis ,Cas9/gRNA ,Populus trichocarpa ,wood ,Biology (General) ,QH301-705.5 ,Chemistry ,QD1-999 - Abstract
Fasciclin-like arabinogalactan proteins (FLAs) play an important role in plant development and adaptation to the environment. However, the roles of FLAs in wood formation remain poorly understood. Here, we identified a total of 50 PtrFLA genes in poplar. They were classified into four groups: A to D, among which group A was the largest group with 28 members clustered into four branches. Most PtrFLAs of group A were dominantly expressed in developing xylem based on microarray and RT-qPCR data. The roles of PtrFLA40 and PtrFLA45 in group A were investigated via the Cas9/gRNA-induced mutation lines. Loss of PtrFLA40 and PtrFLA45 increased stem length and diameter in ptrfla40ptrfla45 double mutants, but not in ptrfla40 or ptrfla45 single mutants. Further, our findings indicated that the ptrfla40ptrfla45 mutants enlarged the cell size of xylem fibers and vessels, suggesting a negative modulation in stem xylem cell size. In addition, wood lignin content in the ptrfla40fla45 mutants was increased by nearly 9%, and the lignin biosynthesis-related genes were significantly up-regulated in the ptrfla40fla45 mutants, in agreement with the increase in wood lignin content. Overall, Cas9/gRNA-mediated mutations in PtrFLA40 and PtrFLA45 reveal redundant roles in modulating wood cell size and secondary cell wall (SCW) synthesis in poplar.
- Published
- 2022
- Full Text
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22. Laboratory Investigations of Mold Growth on Transverse and Longitudinal Wood Surfaces
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Pavla Ryparová, Pavel Kopecký, Kamil Staněk, Jan Richter, and Jan Tywoniak
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wood ,mold growth ,laboratory experiments ,growth curves ,mold index ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The possible influence of anatomical sections of wood on mold growth was investigated by means of a laboratory experiment. The selected fungi, Aspergillus sp., Penicillium sp., and Alternaria sp. were inoculated by spraying on the surface of wood specimens prepared from pine (Pinus sylvestris) and spruce (Picea abies). The incubation was carried out under stable environmental conditions (temperature of 22 °C, relative humidity of 75, 87, and 95%) over three months. Mold growth was evaluated based on regular microscopic and macroscopic observations. The recorded mold coverage fractions and the qualitative indicators of mold development were later expressed by a dimensionless mold index. The differences in mold growth in the anatomical sections of wood were found to be relatively insignificant. In contrast, comparison of measured data with other experimental studies showed large differences, especially in the initial growth phase. The discrepancy is probably related to differences among the experimental protocols. It is concluded that laboratory mold growth studies would be improved if a common standardized methodology was developed and followed.
- Published
- 2022
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23. VARIATION OF THE TECHNOLOGICAL PROPERTIES OF WOOD FROM Ochroma pyramidale IN THE LONGITUDINAL AND RADIAL SENSE OF THE SLEW.
- Author
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Stange, Rafaela, Buss, Rodrigo, de Souza, Luana Muller, Melo, Natalia Durigon, Monteiro, Thiago Campos, and Rios, Polliana D'Angelo
- Subjects
- *
WOOD chemistry , *WOOD , *THERMAL insulation , *PAPER pulp , *PARTICLE board ,WOOD density - Abstract
The work aimed to characterize the wood of the species Ochroma pyramidale in the longitudinal and radial direction of the tree. For the study, five six-year old trees were used. Discs were removed at different heights of the stem. The samples were obtained from each disk in different regions between the pith and bark. The preparation and the anatomical analysis of the permanent and temporary slides, chemical analyzes, and basic density measure of the stem wood were carried out according to technical standards. As a result, it was observed that the highest averages for pore diameter and fiber length were found in the region close to the bark at all heights. Regarding to the rays, it was noted that there was an interaction between the longitudinal x radial factors for most of the parameters evaluated, except for the width of the rays. For fiber lumen diameter and vessel length, the same trend line was found, the highest average observed in the region close to the pith. In the chemical analyzes, it was possible to observe that there was no significant difference in the longitudinal direction of the wood except for solubility in cold water. For basic density, there was an increase in the region closer to the pith compared to the region closer to the bark. However, in relation to the longitudinal position of the bole, the highest values were found at the base of the bole. It could be seen that the Ochroma pyramidale species has potential use for products linked to thermal and acoustic insulation, production of particleboards and pulp and paper production. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
24. Behavior and Damage Characterization of Impulsively Loaded Cross-Laminated Timber Panels
- Author
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Noel R. Flores, Russell Gentry, and Lauren K. Stewart
- Subjects
wood ,cross-laminated timber ,CLT ,impulsive loading ,damage ,shock ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
This research bridges the gap between the quasi-static and high-strain-rate loading regimes in cross-laminated timber (CLT) by investigating two areas that have remained unstudied or elusive, i.e., rolling shear failure of CLT under impulsive, blast-like loading and intermediate strain rates in CLT. To study the conditions that would promote shear modes of failure, a novel, highly adaptable center-point testing system and methodology were developed that permitted the application of impulsive loading to undamaged CLT panels in a highly controlled and repeatable manner. The loading condition and low span-to-depth ratio (6.40 ≤ L:h ≤ 6.55) CLT were selected to encourage the development of shear modes of failure. Changes to the rotational rigidity at the boundary conditions allowed for the empirical simulation of realistic boundary conditions. Digital Image Correlation (DIC) and load cell data were used to identify failure modes following loss in resistance in the specimens. Overall, the experiment was successful in consistently eliciting shear modes of failure and providing damage characterization in impulsively loaded CLT. Shear modes of failure resulted in the dramatic loss of resistance in all specimens tested. Strain-rate enhancement in the dynamic apparent flexural stiffness of CLT of 1.3 to 7.2 times was observed. Lower levels of damage were observed in specimens with higher levels of boundary-condition rotational rigidity.
- Published
- 2022
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25. Ultraviolet-Assisted Modified Delignified Wood with High Transparency
- Author
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Xiaoli Chen, Shangjie Ge-Zhang, Yu Han, Hong Yang, Wenao Ou-Yang, Haotong Zhu, Junyi Hao, and Jinxin Wang
- Subjects
wood ,ultraviolet rays ,delignification ,transmittance ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The substrate of solar cells with high haze, transparent, flexible, green and low coatings will be needed in the future. This paper reports a method for ultraviolet-assisted delignification of wood in an alkaline solution environment to improve the transmittance of “transparent wood”. Scanning electron microscope (SEM), X-ray diffraction image (XRD), Fourier transform infrared (FTIR) spectroscopy and transmittance-haze and chemical composition analysis were used to explore the mechanisms underlying the effect of ultraviolet-assisted lignin modification on the optical properties of “transparent wood”. The results show that UV-assisted delignification accelerates the rate of removal of lignin and chromogenic groups, which in turn improves the optical properties of the “transparent wood”, with UV-assisted lignin modification for 2 h increasing the light transmission of the “transparent wood” by 20%. UV-assisted delignification for 4 h and impregnation resulted in “transparent wood” with a transparency of 71% and a haze of 90%. This report provides a rapid and easy method to prepare high-quality “transparent wood”. The “transparent wood” with high transmittance and high haze is a potential candidate for transparent solar substrates. Meanwhile, this method is enlightening for high quality, fast and green preparation of other derived functional materials based on lignin wood.
- Published
- 2022
- Full Text
- View/download PDF
26. Investigation into the Effects of Roller Pressing on Hardness, Roughness and Elastic Modulus of Wooden Workpieces
- Author
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Vladimir Kocovic, Dragan Dzunic, Sonja Kostic, Ljiljana Brzakovic, Branko Tadic, Miljana Prica, and Djordje Vukelic
- Subjects
roller pressing ,wood ,hardness ,elastic modulus ,roughness ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The paper investigates the effects of roller pressing on the hardness, roughness, and elastic modulus of wooden workpieces. For research purposes, a roller pressing device based on purely mechanical processing was designed and developed. Four different levels of pressing force have been applied to eight different types of wood: cherry, fir, alder, linden, beech, walnut, oak, and ash. The obtained results indicate that the proposed processing method can significantly improve the hardness, elastic modulus, and surface quality of wooden workpieces. The ash sample exhibited the largest relative increase in hardness (175.9%), while the most significant relative increase in the elastic modulus (66.73%) was measured on the linden sample. The largest relative decrease in surface roughness (54.75%) was achieved on the alder sample. For all types of wood except for fir, in which case an increase in pressing force did not produce the desired reduction of roughness, correlation coefficients indicate a strong relationship between the pressing force as an input variable and the elastic modulus, hardness, and roughness as output variables.
- Published
- 2022
- Full Text
- View/download PDF
27. Nano-AgCu Alloy on Wood Surface for Mold Resistance
- Author
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Yanran Qi, Xiaohan Dai, Lianxiang Wei, Hongxue Luo, Yiliang Liu, Xiaoying Dong, Dequan Yang, and Yongfeng Li
- Subjects
wood ,nanoscale alloy ,mold resistance ,protection efficiency ,leaching rate ,Chemistry ,QD1-999 - Abstract
The mold infection of wood reduces the quality of its surface and potentially endangers human health. One category of the most popular mold inhibitors on the market is water-soluble fungicides. However, easy leaching due to ionic forms is a problem, which reduces the effectiveness of their antimicrobial action, as well as causing environmental pollution. Interestingly, nanometer-sized sterilizing agents present strong permeability and highly fungicidal behavior, and they are not easily leached, due to the unique nanoscale effect, and they have become alternative candidates as marketable anti-mold agents for wood protection. In this study, we first designed and explored a nanoscale alloy (nano silver–copper alloy, nano-AgCu) to treat wood surfaces for mold growth resistance. The results showed that three molds, i.e., Aspergillus niger, Penicillium citrinum and Trichoderma viride, mainly grew on the surface of wood within a depth of 100 μm; and that the nano-AgCu alloy with a particle size of ~15 nm presented improved retention and anti-mold efficiency at a nanomaterial concentration on the wood surface. Its leaching rate increased non-linearly with the increase in nano-AgCu retention and then it showed a gradually decreasing trend. When the concentration reached 1000 mg/L, the nano-AgCu alloy uniformly distributed on the wood surface in a monodispersed state and exhibited a lower retention of 0.342 g/m2, with an anti-mold efficiency of more than 75% and a leaching rate of only 7.678%. Such results positioned 1000 mg/L as the toxic threshold concentration of nano-AgCu against the three molds. This study can provide a scientific basis for the analysis of the anti-mold mechanisms of nano-AgCu alloy on wood surfaces and guide the application of nano-metal alloy materials in the field of wood antimicrobials.
- Published
- 2022
- Full Text
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28. An Investigation of Wood Baseball Bat Durability as a Function of Bat Profile and Slope of Grain Using Finite Element Modeling and Statistical Analysis
- Author
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Blake Campshure, Patrick Drane, and James A. Sherwood
- Subjects
baseball ,wood ,finite elements ,durability ,slope of grain ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
To counter a perceived increase in multi-piece fracturing of wood baseball bats, Major League Baseball implemented standards to regulate the quality of wood used in the making of professional-grade baseball bats. These specifications included a minimum density as a function of wood species and a standard related to slope of grain (SoG). Following the implementation of these specifications in 2008, there was a 65% reduction in the multi-piece failure rate. It is hypothesized that a further reduction in the breakage rate can be realized through the implementation of regulations on allowable bat profiles. In the current work, a parametric study was conducted to develop a quantitative understanding of the relationship between bat durability (i.e., resistance to breaking), SoG, and bat profile, thereby obtaining data to support or refute the hypothesis. Finite element models of the bat/ball impact of four different popular bat profiles were created using LS-DYNA software. Similarities and differences between bat profiles impacted at two relatively vulnerable axial locations are presented and discussed. Lastly, the respective bat durabilities for all of the profiles were compared using a probability analysis that considers the SoG, impact location, impact velocity, and it predicts an in-service bat durability.
- Published
- 2022
- Full Text
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29. Multiscale Mechanical Performance of Wood: From Nano- to Macro-Scale across Structure Hierarchy and Size Effects
- Author
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Yuri I. Golovin, Alexander A. Gusev, Dmitry Yu. Golovin, Sergey M. Matveev, and Inna A. Vasyukova
- Subjects
wood ,nano-, micro-, meso-, and macro-structure ,multiscale mechanical properties ,size effects ,Hall-Petch law ,dendrochronology ,Chemistry ,QD1-999 - Abstract
This review describes methods and results of studying the mechanical properties of wood at all scales: from nano- to macro-scale. The connection between the mechanical properties of material and its structure at all these levels is explored. It is shown that the existing size effects in the mechanical properties of wood, in a range of the characteristic sizes of the structure of about six orders of magnitude, correspond to the empirical Hall-Petch relation. This “law” was revealed more than 60 years ago in metals and alloys and later in other materials. The nature, as well as the particular type of the size dependences in different classes of materials can vary, but the general trend, “the smaller the stronger”, remains true both for wood and for other cellulose-containing materials. The possible mechanisms of the size effects in wood are being discussed. The correlations between the mechanical and thermophysical properties of wood are described. Several examples are used to demonstrate the possibility to forecast the macromechanical properties of wood by means of contactless thermographic express methods based on measuring temperature diffusivity. The research technique for dendrochronological and dendroclimatological studies by means of the analysis of microhardness and Young’s modulus radial dependences in annual growth rings is described.
- Published
- 2022
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30. Conditions Influencing Mould Growth for Effective Prevention of Wood Deterioration Indoors
- Author
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Edgars Kuka, Dace Cirule, Ingeborga Andersone, Bruno Andersons, and Velta Fridrihsone
- Subjects
mould growth ,wood ,temperature ,relative humidity ,moisture content ,surface wetting ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Effective prevention of mould growth indoors is still an important topic considering that mould growth is frequently observed in buildings, it causes serious health hazards and can irreversibly damage infected objects. Several studies have been conducted and mould growth models developed. Despite that, some potentially important aspects such as water damage and spore contamination have received only little attention. The objective of the present study was to investigate the effect of the initial moisture content of wood and spore contamination on mould development indoors. The mould tests were performed in constant temperature (10, 20 and 30 °C) and relative humidity (91% and 97%) conditions. The results show that wetting of wood specimens prior to the test significantly accelerates mould growth at a temperature of 10 °C. For the other temperatures, the effect was insignificant. Similar results were obtained for the test involving dry (conditioned at RH 50%) and conditioned specimens (RH 91% or RH 97%). The results regarding initial spore contamination show that significantly longer periods are required for mould to develop without spore contamination at 10 °C and 20 °C, while at 30 °C the effect is relatively small.
- Published
- 2022
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31. Adsorption Mechanism of Lead on Wood/Nano-Manganese Oxide Composite
- Author
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Jamal Al-Abdullah, Abdul Ghaffar Al Lafi, Tasneem Alnama, Wafa’a Al Masri, Yusr Amin, and Mohammed Nidal Alkfri
- Subjects
wood ,manganese oxide ,adsorption ,kinetics ,lead ,Chemical engineering ,TP155-156 ,Chemistry ,QD1-999 - Abstract
Discharge of untreated industrial wastewater containing heavy metals such as Pb2+ is hazardous to the environment due to their high toxicity. This study reports on the adsorption, desorption, and kinetic study on Pb2+ removal from aqueous solutions using wood/Nano-manganese oxide composite (WB-NMO). The optimum pH, contact time and temperature for adsorption were found to be 5.0, 4 h and 333 K, respectively. Pseudo-second-order kinetics best described the adsorption process with an initial sorption rate of 4.0 mg g min-1, and a half-adsorption time t1/2 of 31.6 min. Best fit for adsorption isotherm was obtained with the Brunauer-Emmett-Teller (BET) model with a maximum adsorption capacity of 213 mg/g for an initial metal concentration of 60 mg/L. Both intra-particle diffusion and film diffusion contribute to the rate-determining step. Desorption experiments with 0.5 mol/L HCl, inferred the reusability of the composite. Adsorption experiment of Pb2+ from industrial wastewater confirmed that the prepared WB-NMO is a promising candidate for wastewater treatment. The WB-NMO demonstrated high Pb2+ removal efficiency and is considered as a promising alternative and reusable composite for lead removal from contaminated effluents.
- Published
- 2018
32. Effects of forest clearcutting in New England on stream chemistry
- Author
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Federer, C
- Published
- 2020
33. A multiscale model of wood pyrolysis in fire to study the roles of chemistry and heat transfer at the mesoscale.
- Author
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Richter, Franz and Rein, Guillermo
- Subjects
- *
MULTISCALE modeling , *HEAT transfer , *CHEMISTRY , *HEAT flux , *COAL pyrolysis , *FUELWOOD , *PYROLYSIS , *FIRE - Abstract
Pyrolysis is a key process in all stages of wood burning from ignition to extinction. Understanding each stage is crucial to tackle wildfires and assess the fire safety of timber buildings. A model of appropriate complexity of wood pyrolysis and oxidation is missing, which limits the understanding of fires fuelled by wood. Progress towards this aim has been slow in recent years, as the role of chemical kinetics is still debated. Three predominant theories hypothesis that chemistry is either infinitely fast (de Ris), a function of char depth (Atreya), or a function of heat flux (Suuberg). This paper proposes a novel multi-scale model of wood pyrolysis and oxidation for predicting the charring of timber. The chemical kinetics sub-model was previously validated at the microscale (mg-samples). We favourably compare the complete model against a large range of mesoscale experiments (g-samples) found in the literature of different moisture contents (0–30%), heat fluxes (0–60 kW/m2), oxygen concentrations (0–21%), grain directions (parallel/perpendicular), and combinations thereof. The model was then used to calculate the transient Damköhler number of wood at different depths and heat fluxes. This analysis showed that chemistry and heat transfer are both important at all heat fluxes and stages of burning relevant to fire, which unifies the three theories by Suuberg, Atreya, and de Ris. We argue that the model is of currently appropriate complexity to predict the charring of timber. These findings improve our understanding of wood pyrolysis and the modelling of timber burning across scales. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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34. Simulation of Wood Combustion in PATO Using a Detailed Pyrolysis Model Coupled to fireFoam
- Author
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Hermes Scandelli, Azita Ahmadi-Senichault, Franck Richard, and Jean Lachaud
- Subjects
numerical simulations ,wood ,pyrolysis ,combustion ,puffing effect ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The numerical simulation of fire propagation requires capturing the coupling between wood pyrolysis, which leads to the production of various gaseous species, and the combustion of these species in the flame, which produces the energy that sustains the pyrolysis process. Experimental and numerical works of the fire community are targeted towards improving the description of the pyrolysis process to better predict the rate of production and the chemical nature of the pyrolysis gases. We know that wood pyrolysis leads to the production of a large variety of chemical species: water, methane, propane, carbon monoxide and dioxide, phenol, cresol, hydrogen, etc. With the idea of being able to capitalize on such developments to study more accurately the physics of fire propagation, we have developed a numerical framework that couples a detailed three-dimensional pyrolysis model and fireFoam. In this article, we illustrate the capability of the simulation tool by treating the combustion of a wood log. Wood is considered to be composed of three phases (cellulose, hemicellulose and lignin), each undergoing parallel degradation processes leading to the production of methane and hydrogen. We chose to simplify the gas mixture for this first proof of concept of the coupling of a multi-species pyrolysis process and a flame. In the flame, we consider two separate finite-rate combustion reactions for methane and hydrogen. The flame evolves during the simulation according to the concentration of the two gaseous species produced from the material. It appears that introducing different pyrolysis species impacts the temperature and behavior of the flame.
- Published
- 2021
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35. Influence of Chemical Activation Temperatures on Nitrogen-Doped Carbon Material Structure, Pore Size Distribution and Oxygen Reduction Reaction Activity
- Author
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Aleksandrs Volperts, Ance Plavniece, Kätlin Kaare, Galina Dobele, Aivars Zhurinsh, and Ivar Kruusenberg
- Subjects
wood ,activated carbons ,porous structure ,fuel cells ,metal-free catalyst ,oxygen reduction reaction ,Chemical technology ,TP1-1185 ,Chemistry ,QD1-999 - Abstract
The goal of this research was to synthesize activated nitrogen-doped nanocarbons with high specific surface area and adjustable pore size distribution using wood charcoal as a raw material. The resulting carbon materials were tested for possible application as oxygen reduction reaction catalysts in alkaline media. Activated carbons were obtained using a thermochemical activation method with NaOH. Nitrogen was introduced into activated carbons using dicyandiamide solution. It was demonstrated that the content of introduced nitrogen depends on oxygen content in the structure of the activated carbon. The oxygen reduction reaction activity of the activated and nitrogen-doped carbon material was comparable with a commercial 20% Pt/C catalyst. Electrocatalytic properties of the synthesized N-doped wood-derived carbon catalysts may be associated with the highly developed surface area, specific ratio of micro- and mesopores, as well as the high percentage of pyridinic nitrogen.
- Published
- 2021
- Full Text
- View/download PDF
36. An Overview of Natural Polymers as Reinforcing Agents for 3D Printing
- Author
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Beatrice Sabbatini, Alessandra Cambriani, Marco Cespi, Giovanni Filippo Palmieri, Diego Romano Perinelli, and Giulia Bonacucina
- Subjects
cellulose ,lignin ,chitosan ,wood ,keratin ,hemp ,Chemistry ,QD1-999 - Abstract
Three-dimensional (3D) printing, or additive manufacturing, is a group of innovative technologies that are increasingly employed for the production of 3D objects in different fields, including pharmaceutics, engineering, agri-food and medicines. The most processed materials by 3D printing techniques (e.g., fused deposition modelling, FDM; selective laser sintering, SLS; stereolithography, SLA) are polymeric materials since they offer chemical resistance, are low cost and have easy processability. However, one main drawback of using these materials alone (e.g., polylactic acid, PLA) in the manufacturing process is related to the poor mechanical and tensile properties of the final product. To overcome these limitations, fillers can be added to the polymeric matrix during the manufacturing to act as reinforcing agents. These include inorganic or organic materials such as glass, carbon fibers, silicon, ceramic or metals. One emerging approach is the employment of natural polymers (polysaccharides and proteins) as reinforcing agents, which are extracted from plants or obtained from biomasses or agricultural/industrial wastes. The advantages of using these natural materials as fillers for 3D printing are related to their availability together with the possibility of producing printed specimens with a smaller environmental impact and higher biodegradability. Therefore, they represent a “green option” for 3D printing processing, and many studies have been published in the last year to evaluate their ability to improve the mechanical properties of 3D printed objects. The present review provides an overview of the recent literature regarding natural polymers as reinforcing agents for 3D printing.
- Published
- 2021
- Full Text
- View/download PDF
37. FTIR Spectroscopy for Identification and Intra-Species Characterization of Serpula lacrymans
- Author
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Rony Barboux, Faisl Bousta, and Patrick Di Martino
- Subjects
Serpula lacrymans ,biodegradation ,wood ,cultural heritage ,FTIR ,identification ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The dry rot fungus Serpula lacrymans is the most destructive fungal agent of wood building materials in Europe, Russia, North America, and Japan. The identification of this wood-deteriorating agent and the discrimination of different fungal isolates is very important for the control of buildings in general and for the preservation of cultural heritage in particular. The objective of the study was to develop a Fourier transform infrared (FTIR) method coupled with a partial least square discriminant analysis (PLS-DA) for the sample preparation and identification of S. lacrymans. Five distinct S. lacrymans strains were analysed and compared to two strains of unrelated fungal species. Different methods of mycelial growth, sample preparation, and FTIR spectral data normalisation were compared. FTIR analysis of a harvested mycelium grown on the surface of a polyether sulfone microfiltration membrane deposited on a malt extract agar medium, followed by vector normalization and PLS-DA statistical analysis, resulted in 100% correct attribution at phylum, species, and strain level, regardless of the type of standardization used. This study confirms the applicability of FTIR spectroscopy for the identification of S. lacrymans and the discrimination of different strains belonging to this species.
- Published
- 2021
- Full Text
- View/download PDF
38. Influence of Rice Husk and Wood Biomass Properties on the Manufacture of Filaments for Fused Deposition Modeling
- Author
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Marie-Joo Le Guen, Stefan Hill, Dawn Smith, Beatrix Theobald, Evamaria Gaugler, Abdellatif Barakat, and Claire Mayer-Laigle
- Subjects
3D printing ,rice husk ,wood ,biomass ,composites ,extrusion ,Chemistry ,QD1-999 - Abstract
Additive manufacturing or 3D printing has the potential to displace some of the current manufacturing techniques and is particularly attractive if local renewable waste resources can be used. In this study, rice husk, and wood powders were compounded in polylactic acid (PLA) by twin screw extrusion to produce filaments for fused-deposition modeling 3D printing. The biomasses were characterized in terms of physical features (e.g., particle size, density) and chemical compositions (e.g., solid state nuclear magnetic resonance, ash content). The two biomasses were found to have a different impact on the rheological behavior of the compounds and the extrusion process overall stability. When comparing the complex viscosity of neat PLA to the biomass/PLA compounds, the integration of wood powder increased the complex viscosity of the compound, whereas the integration of rice husk powder decreased it. This significant difference in rheological behavior was attributed to the higher specific surface area (and chemical reactivity) of the rice husk particles and the presence of silica in rice husks compared to the wood powder. Color variations were also observed. Despite the biomass filler and rheological behavior differences, the mechanical properties of the 3D printed samples were similar and predominantly affected by the printing direction.
- Published
- 2019
- Full Text
- View/download PDF
39. Alkylimidazolium Ionic Liquids Absorption and Diffusion in Wood
- Author
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Catalin Croitoru and Ionut Claudiu Roata
- Subjects
wood ,ionic liquids ,wood preservatives ,diffusion ,swelling ,lignocellulose ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Ionic liquids represent a class of highly tunable organic compounds responsible for many applications in the domain of wood-based materials. It has often been emphasized that the use of ionic liquids derives from their high affinity for lignocellulose and their good penetration ability into wood structures. This paper discusses the sorption ability of different types of 1-alkyl-3-methylimidazolium ionic liquids with lateral alkyl chains, ranging from ethyl to hexyl into spruce and beech wood, as a function of their cation molecular mass, anion type (chloride, tetrafluoroborate, acetate), and intrinsic properties (surface tension and kinematic viscosity) at room temperature. All the studied ionic liquids present high relative uptake values at the equilibrium, ranging from 11.2% to 69.7%. The bulk diffusion coefficients of the ionic liquids into the wood range from 2 × 10−3 to 28 × 10−3 mm2/min, being higher in the longitudinal direction for both types of wood. The value of the diffusion coefficients for 1-ethyl-3-methylimidazolium chloride is only 25% lower than that for water, despite the obvious differences in viscosity and surface tension, demonstrating a good penetration ability and the potential for wood industry-related applications (as impregnation compound carriers and preservatives).
- Published
- 2021
- Full Text
- View/download PDF
40. Calibration of Acoustic Emission Parameters in Relation to the Equilibrium Moisture Content Variations in a Pinus sylvestris Beam
- Author
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Beatrice Bartolucci, Francesca Frasca, Anna Maria Siani, and Chiara Bertolin
- Subjects
wood ,acoustic emission ,non-destructive evaluation ,equilibrium moisture content ,cultural heritage ,condition monitoring ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Under constant temperature conditions, air relative humidity variations affect hygroscopic objects, such as wood, modifying their moisture content and provoking, at low values, damages and fractures. The parameters (amplitude, counts, and energy) derived from the acoustic emission non-destructive technique are calibrated with respect to equilibrium moisture content values using 14 samplings of Pinus sylvestris. The experimental procedure uses multi-technique approaches involving a universal testing machine, digital image correlation, and acoustic emissions, and notes that the three parameters of acoustic emission strictly depend on the equilibrium moisture content. For a better interpretation, a statistical approach is applied to model the equilibrium moisture content variations radially and longitudinally. Amplitude, counts, and energy are calibrated as a function of the equilibrium moisture content, indicating that all three parameters are necessary to have an integral vision of the conservation of a wooden material. Moreover, the shape of the macro-fractures that occur at the surface can be associated with the level of moisture or dryness of the sample. Finally, the proposed method can be used in situ because, through acoustic emission monitoring, it is possible to quantify the fingerprint of the state of conservation of a material.
- Published
- 2021
- Full Text
- View/download PDF
41. Mechanics of Screw Joints Solved as Beams Placed in a Tangential Elastic Foundation
- Author
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Karel Frydrýšek, Šárka Michenková, Leopold Pleva, Jan Koutecký, Jiří Fries, Kateřina Peterek Dědková, Roman Madeja, Antonín Trefil, Pavel Krpec, Tomáš Halo, Leopold Hrabovský, Lubor Bialy, Roland Jančo, and Jiří Pokorný
- Subjects
screw joints ,tensile stress ,pull-out test ,analytical and experimental solution ,wood ,tangential elastic foundation ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
This article deals with a new original analytical solution of deformation, force and stress states in wood screw joints up to the limit values of pulling out/breaking the screw. The screws are under tension. The wood-to-screw interaction is effectively simplified by introducing several physical model variants using a tangential elastic non-linear foundation. The experimental verification of the proposed models using pull-out tests (i.e., pulling out screws from dry spruce wood in laboratory conditions) confirms the correctness of the proposed models of the elastic linear/non-linear foundation. The validity of the model is also analytically and experimentally verified in the biomechanical model of pulling out screws from the femur of a bovine/human cadaver, which confirms and expands the validity of newly designed screw joint models outside the timber structure area.
- Published
- 2021
- Full Text
- View/download PDF
42. A new approach for estimating living vegetation volume based on terrestrial point cloud data.
- Author
-
Li, Le and Liu, Changfu
- Subjects
- *
POINT cloud , *LIDAR , *FOREST ecology , *PLANTS , *INSPECTION & review , *PINACEAE - Abstract
Living vegetation volume (LVV), one of the most difficult tree parameters to calculate, is among the most important factors that indicates the biological characteristics and ecological functions of the crown. Obtaining precise LVV estimates is, however, challenging task because the irregularities of many crown shapes are difficult to capture using standard forestry field equipment. Terrestrial light detection and ranging (T-LiDAR) can be used to record the three-dimensional structures of trees. The primary branches of Larix olgensis and Quercus mongolica in the Qingyuan Experimental Station of Forest Ecology at the Chinese Academy of Sciences (CAS) were taken as the research objects. A new rapid LVV estimation method called the filling method was proposed in this paper based on a T-LiDAR point cloud. In the proposed method, the branch point clouds are divided into leaf points and wood points. We used RiSCAN PRO 1.64 to manually separate the leaf points and wood points under careful visual inspection, and calculated that leaf points and wood points accounted for 91% and 9% of the number of the point clouds of branches. Then, the equation LVV = V1N (where N is the number of leaf points, and V1 is cube size) is used to calculate LVV. When the laser transmission frequency is 300,000 points/second and the point cloud is diluted to 30% using the octree method, the point cloud can be replaced by a cube (V1) of 6.11 cm3 to fill the branch space. The results showed that good performance for this approach, the measuring accuracy for L. olgensis and Q. mongolica at the levels of α = 0.05 and α = 0.01, respectively (94.35%, 90.01% and 91.99%, 85.63%, respectively). The results suggest that the proposed method can be conveniently used to calculate the LVV of coniferous and broad-leaf species under specific scanning settings. This work is explorative because hypotheses or a theoretical framework have not been previously defined. Rather, we would like to contribute to the formation of hypotheses as a background for further studies. [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
- View/download PDF
43. Quantitative genetic parameters for growth and wood properties in Eucalyptus “urograndis” hybrid using near-infrared phenotyping and genome-wide SNP-based relationships.
- Author
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Marco de Lima, Bruno, Cappa, Eduardo P., Silva-Junior, Orzenil B., Garcia, Carla, Mansfield, Shawn D., and Grattapaglia, Dario
- Subjects
- *
WOOD chemistry , *WOOD , *CELLULOSE fibers , *GENETIC correlations , *WOOD-pulp , *TREE breeding - Abstract
A thorough understanding of the heritability, genetic correlations and additive and non-additive variance components of tree growth and wood properties is a requisite for effective tree breeding. This knowledge is essential to maximize genetic gain, that is, the amount of increase in trait performance achieved annually through directional selection. Understanding the genetic attributes of traits targeted by breeding is also important to sustain decade-long genetic progress, that is, the progress made by increasing the average genetic value of the offspring as compared to that of the parental generation. In this study, we report quantitative genetic parameters for fifteen growth, wood chemical and physical traits for the world-famous Eucalyptus urograndis hybrid (E. grandis × E. urophylla). These traits directly impact the optimal use of wood for cellulose pulp, paper, and energy production. A population of 1,000 trees sampled in a progeny trial was phenotyped directly or following the development and use of near-infrared spectroscopy calibration models. Trees were genotyped with 33,398 SNPs and 24,001 DArT-seq genome-wide markers and genomic realized relationship matrices (GRM) were used for parameter estimation with an individual-tree additive-dominant mixed model. Wood chemical properties and wood density showed stronger genetic control than growth, cellulose and fiber traits. Additive effects are the main drivers of genetic variation for all traits, but dominance plays an equally or more important role for growth, singularly in this hybrid. GRM´s with >10,000 markers provided stable relationships estimates and more accurate parameters than pedigrees by capturing the full genetic relationships among individuals and disentangling the non-additive from the additive genetic component. Low correlations between growth and wood properties indicate that simultaneous selection for wood traits can be applied with minor effects on genetic gain for growth. Conversely, moderate to strong correlations between wood density and chemical traits exist, likely due to their interdependency on cell wall structure such that responses to selection will be connected for these traits. Our results illustrate the advantage of using genome-wide marker data to inform tree breeding in general and have important consequences for operational breeding of eucalypt urograndis hybrids. [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
- View/download PDF
44. Genome, transcriptome, and secretome analysis of wood decay fungus postia placenta supports unique mechanisms of lignocellulose conversion
- Author
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Cullen, Dan [FOREST PRODUCTS LAB]
- Published
- 2008
45. Nanostructurally Controllable Strong Wood Aerogel toward Efficient Thermal Insulation
- Author
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Jonas Garemark, Jesus E. Perea-Buceta, Daniel Rico del Cerro, Stephen Hall, Barbara Berke, Ilkka Kilpeläinen, Lars A. Berglund, Yuanyuan Li, Department of Chemistry, Helsinki Institute of Sustainability Science (HELSUS), and Synthesis and Analysis
- Subjects
116 Chemical sciences ,aerogel ,NANOFIBRILLATED CELLULOSE ,Materialkemi ,THERMAL INSULATION ,Nanoscience ,IONIC LIQUIDS ,CHEMISTRY ,sustainable materials ,KEYWORDS ,aerogel wood ionic liquid thermal insulation sustainable materials ,Materials Chemistry ,NANOCELLULOSE ,FOAMS ,CHLORIDE ,General Materials Science ,AEROGELS ,CONDUCTIVITY ,wood ,ionic liquid - Abstract
Eco-friendly materials with superior thermal insulation and mechanical properties are desirable for improved energy- and space-efficiency in buildings. Cellulose aerogels with structural anisotropy could fulfill these requirements, but complex processing and high energy demand are challenges for scaling up. Here we propose a scalable, nonadditive, top-down fabrication of strong anisotropic aerogels directly from wood with excellent, near isotropic thermal insulation functions. The aerogel was obtained through cell wall dissolution and controlled precipitation in lumen, using an ionic liquid (IL) mixture comprising DMSO and a guanidinium phosphorus-based IL [MTBD][MMP]. The wood aerogel shows a unique structure with lumen filled with nanofibrils network. In situ formation of a cellulosic nanofibril network in the lumen results in specific surface areas up to 280 m2/g and high yield strengths >1.2 MPa. The highly mesoporous structure (average pore diameter ∼20 nm) of freeze-dried wood aerogels leads to low thermal conductivities in both the radial (0.037 W/mK) and axial (0.057 W/mK) directions, showing great potential as scalable thermal insulators. This synthesis route is energy efficient with high nanostructural controllability. The unique nanostructure and rare combination of strength and thermal properties set the material apart from comparable bottom-up aerogels. This nonadditive synthesis approach is believed to contribute significantly toward large-scale design and structure control of biobased aerogels. QC 20221019
- Published
- 2022
46. Characterization of a Spirit Beverage Produced with Strawberry Tree (Arbutus unedo L.) Fruit and Aged with Oak Wood at Laboratorial Scale
- Author
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Ofélia Anjos, Soraia Inês Pedro, Débora Caramelo, Andreia Semedo, Carlos A. L. Antunes, Sara Canas, and Ilda Caldeira
- Subjects
Arbutus unedo ,spirit ,ageing ,wood ,volatile compounds ,sensory analysis ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Arbutus unedo spirit is a valuable product in Mediterranean countries. This spirit is usually marketed in Portugal without wood ageing. This work aims to characterize the ageing effect on the Arbutus unedo spirit, for three and six months with oak wood (Quercus robur L.) submitted to different toasting levels, based on its chemical composition and its sensory properties. For this purpose, several parameters were analysed: acidity, pH, dry extract, and volatile compounds (methanol, acetaldehyde, ethyl acetate and fusel alcohols). The volatile compounds were identified by GC-MS and quantified by GC-FID. Sensory analysis was performed by a trained panel, who have profiled this beverage, as well as the changes acquired during ageing. Spectroscopic techniques, namely FTIR–ATR, were applied to discriminate the different beverages produced. The results highlighted an increase in Arbutus unedo spirit’s quality with the wood contact, mainly based on the sensory attributes. Additionally, they showed that the best beverages were produced using oak wood with medium toasting levels during three months of ageing.
- Published
- 2021
- Full Text
- View/download PDF
47. The Effect of High Lignin Content on Oxidative Nanofibrillation of Wood Cell Wall
- Author
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Simon Jonasson, Anne Bünder, Linn Berglund, Magnus Hertzberg, Totte Niittylä, and Kristiina Oksman
- Subjects
cellulose nanofibrils ,wood ,lignin ,TEMPO-oxidation ,Chemistry ,QD1-999 - Abstract
Wood from field-grown poplars with different genotypes and varying lignin content (17.4 wt % to 30.0 wt %) were subjected to one-pot 2,2,6,6-Tetramethylpiperidin-1-yl)oxyl catalyzed oxidation and high-pressure homogenization in order to investigate nanofibrillation following simultaneous delignification and cellulose oxidation. When comparing low and high lignin wood it was found that the high lignin wood was more easily fibrillated as indicated by a higher nanofibril yield (68% and 45%) and suspension viscosity (27 and 15 mPa·s). The nanofibrils were monodisperse with diameter ranging between 1.2 and 2.0 nm as measured using atomic force microscopy. Slightly less cellulose oxidation (0.44 and 0.68 mmol·g−1) together with a reduced process yield (36% and 44%) was also found which showed that the removal of a larger amount of lignin increased the efficiency of the homogenization step despite slightly reduced oxidation of the nanofibril surfaces. The surface area of oxidized high lignin wood was also higher than low lignin wood (114 m2·g−1 and 76 m2·g−1) which implicates porosity as a factor that can influence cellulose nanofibril isolation from wood in a beneficial manner.
- Published
- 2021
- Full Text
- View/download PDF
48. Compressive Behavior of Pieces of Wood Reinforced with Fabrics Composed of Carbon Fiber and Basalt Fiber
- Author
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Pilar de la Rosa, María de las Nieves González, María Isabel Prieto, and Enrique Gómez
- Subjects
carbon fiber reinforced polymer ,basalt fiber reinforced polymer ,wood ,mechanical properties ,compression tests ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Given the importance of wood as a building material for hundreds of years, it is often necessary to increase the resilience of existing wood elements. Due to their notable adaptability and high mechanical capacities, materials composed of polymers that have been reinforced with fibers represent a good alternative to traditional reinforcement systems. This study looks at the compressive behavior of prismatic wild pinewood test pieces confined with three types of fabric—one of carbon fiber reinforced polymer (CFRP) and two of basalt fiber reinforced polymer (BFRP) featuring two very different grammages. The reinforced pieces attain at least 96% greater resistance than the unreinforced pieces (FC300), reaching as much as 133% more resistance in the case of the pieces reinforced with FB600; however, the ductility of the reinforced pieces is much lower than that of the unreinforced, by approximately one-sixth and one-quarter, respectively. The study also allowed us to conclude that there is no relationship between the mechanical capacity of the reinforcement and the ultimate strength of the test piece tested, but there is a strong relationship between the rigidity of the reinforcement and modulus of elasticity and the ultimate strain of the reinforced pieces.
- Published
- 2021
- Full Text
- View/download PDF
49. Thermal Decomposition and Combustion of Microwave Pre-Treated Biomass Pellets
- Author
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Linards Goldšteins, Raimonds Valdmanis, Maija Zaķe, Alexandr Arshanitsa, and Anna Andersone
- Subjects
microwave pretreatment ,reactivity ,heating value ,wheat straw ,wood ,peat ,Chemical technology ,TP1-1185 ,Chemistry ,QD1-999 - Abstract
The objective of the study was to investigate a more effective use of commercially available biomass pellets (wheat straw, wood, peat) using microwave pretreatment to improve heat production. Pellets were pretreated using the originally designed microwave torrefaction device. The effects of microwave (mw) pretreatment were quantified, providing measurements of the weight loss and elemental composition of pellets and estimating the effect of mw pretreatment on their porosity, surface area and calorific values at pretreatment temperatures of T = 448–553 K. Obtained results show that the highest structural variations and elemental composition during mw pretreatment were obtained for wheat straw pellets, with an increase in reactivity, a decreasing in the duration of the thermal decomposition by about 40% and an increase in the yield of combustible volatiles. Increased reactivity of pretreated pellets enhanced the ignition and burnout of volatiles, decreasing the duration of the burnout of pretreated wheat straw, wood and peat pellets by 40%, 24% and 9%, respectively, and increasing the peak and average values of the flame temperature, heat output, and produced heat energy by 40–50%, with a correlating increase of combustion efficiency and the mass fraction of carbon-neutral CO2 emission. Thus, the applicability of microwave pretreatment for the control and improvement of heat production was confirmed.
- Published
- 2021
- Full Text
- View/download PDF
50. Rapid lignin quantification for fungal wood pretreatment by ATR-FTIR spectroscopy
- Author
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Nikolett Wittner, János Slezsák, Waut Broos, Jordi Geerts, Szilveszter Gergely, Siegfried E. Vlaeminck, and Iris Cornet
- Subjects
Chemistry ,Fourier Analysis ,Hydrolysis ,Spectroscopy, Fourier Transform Infrared ,Lignin ,Wood ,Instrumentation ,Engineering sciences. Technology ,Spectroscopy ,Atomic and Molecular Physics, and Optics ,Analytical Chemistry - Abstract
Lignin determination in lignocellulose with the conventional two-step acid hydrolysis method is highly laborious and time-consuming. However, its quantification is crucial to monitor fungal pretreatment of wood, as the increase of acid-insoluble lignin (AIL) degradation linearly correlates with the achievable enzymatic saccharification yield. Therefore, in this study, a new attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy method was developed to track fungal delignification in an easy and rapid manner. Partial least square regression (PLSR) with cross-validation (CV) was applied to correlate the ATR-FTIR spectra with the AIL content (19.9%–27.1%). After variable selection and normalization, a PLSR model with a high coefficient of determination (𝑅2 = 0.87) and a low root mean square (RMSECV = 0.60%) were obtained despite the heterogeneous nature of the fungal solid-state fermentation. These results show that ATR-FTIR can reliably predict the AIL content in fungus-treated wood while being a high-throughput method. This novel method can facilitate the transition to the woodbased economy.
- Published
- 2023
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