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A highly electroactive Ni-based catalyst for urea oxidation is prepared by a sol-gel method with bubbling of gel mixture. It is observed that the conditions for the gel formation strongly affect the morphology and electrochemical properties of the catalyst materials. As synthesized Ni-catalysts are characterized by X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, and transmission electron microscopy. The Ni-based catalyst prepared at optimum conditions in the scope of this study exhibits the urea oxidation activity of 570 mA mg-1 (at 0.54 V). In a single urea/hydrogen peroxide fuel cell test, the Ni-catalyst provides maximum power densities of 19.6 and 36.4 mW cm-2 at 30 and 70 °C, respectively. Additionally, the cell catalyst shows a stable voltage for 3 days. Thus, this work suggests that a novel Ni-based catalyst derived from a facile method can be used for urea oxidation and as an efficient anode material for urea fuel cells.

Ni-based catalysts are considered as an efficient anode material for urea fuel cells due to the low cost and high activity in alkaline media. Herein, we demonstrate that Ni-Co bimetallic hydroxide particles with highly porous nanostructures can be synthesized using mesoporous silica nanoparticles as templates. The replicated nanostructures of the Ni-Co hydroxide samples from the mesoporous silica templates are observed. The porous Ni0.8Co0.2(OH)2 particles exhibited considerably enhanced electro-catalytic activity for urea oxidation reaction by providing a high surface area and fast mass transport for urea oxidation reaction. It is also found that the Co-doping at 20% significantly reduce the overpotential and increase the peak current of urea oxidation reaction. A direct urea/H2O2 fuel cell with the porous Ni0.8Co0.2(OH)2 as anode material shows an excellent performance with maximum power densities of 11.2 and 25.6 mW cm−2 at 20 °C and 70 °C with 0.5 M urea in 5 M KOH, respectively. Thus, this work suggests that the highly porous Ni0.8Co0.2(OH)2-derived from the mesoporous silica templates can be used for urea oxidation and as an efficient anode material for urea-based fuel cells.