1. Structure and dynamic properties of a polymer-induced sponge phase
- Author
-
Frédéric Nallet, I. Javierre, M. Maugey, and A.-M. Bellocq
- Subjects
Chemistry ,Stereochemistry ,technology, industry, and agriculture ,Analytical chemistry ,Neutron scattering ,Condensed Matter Physics ,Small-angle neutron scattering ,Light scattering ,Dynamic light scattering ,Phase (matter) ,General Materials Science ,Microemulsion ,Lamellar structure ,Hexanol - Abstract
The effect of polyethyleneglycol (PEG) on the phase behaviour of oil-rich sodium dodecyl sulphate, hexanol, water and dodecane mixtures has been investigated. PEG causes the disappearance of the `sponge' phase and induces the formation of a new isotropic phase, labelled L5 , located between the microemulsion, L2 , and the lamellar, L , phases. Small angle neutron scattering and electrical conductivity results show that at local scales the L5 phase consists of inverted bilayers, connected at larger scales. These features suggest a sponge-like structure for the L5 phase, a hypothesis which is further supported by a static and dynamic light scattering study.
- Published
- 2000
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