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The results of research on the efficiency and technological reliability of domestic wastewater purification in two household wastewater treatment plants (WWTPs) with activated sludge are presented in this paper. The studied facilities were located in the territory of the Roztocze National Park (Poland). The mean wastewater flow rate in the WWTPs was 1.0 and 1.6 m3/day. In 2017–2019, 20 series of analyses were done, and 40 wastewater samples were taken. On the basis of the received results, the efficiency of basic pollutant removal was determined. The technological reliability of the tested facilities was specified using the Weibull method. The average removal efficiencies for the biochemical oxygen demand in 5 days (BOD5) and chemical oxygen demand (COD) were 66–83% and 62–65%, respectively. Much lower effects were obtained for total suspended solids (TSS) and amounted to 17–48%, while the efficiency of total phosphorus (TP) and total nitrogen (TN) removal did not exceed 34%. The analyzed systems were characterized by the reliability of TSS, BOD5, and COD removal at the level of 76–96%. However, the reliability of TN and TP elimination was less than 5%. Thus, in the case of biogenic compounds, the analyzed systems did not guarantee that the quality of treated wastewater would meet the requirements of the Polish law during any period of operation. This disqualifies the discussed technological solution in terms of its wide application in protected areas and near lakes, where the requirements for nitrogen and phosphorus removal are high.

The study investigated the efficiency of removal of iron, manganese and indicator bacteria from potable groundwater by using carbonate-silica rock (opoka). The tests were performed in a laboratory in three filter columns supplied with water containing increased concentrations of iron and manganese. Two of the columns were filled with carbonate-silica rock with particle sizes of 2-5 mm; retention time for water in the columns was set at 1 h and 2 h. A third column was filled with 1-2 mm rock particles, with hydraulic retention time set at 1 h. High removal efficiencies were determined for iron, manganese and coliform bacteria and low removal efficiencies for psychro- and mesophilic bacteria. An increase in the alkalinity of the investigated water was also observed.

The paper presents the results of application of hydrogen peroxide (H2O2) for the optimization of the effects of ammonia nitrogen removal from domestic wastewater. The investigations were carried out at a model wastewater treatment plant consisting of a preliminary sedimentation tank and a sand filter with a horizontal flow of wastewater at a constant hydraulic load of 1.44 L/day. The efficiency of ammonia nitrogen removal was analyzed for different wastewater oxygenation levels: 0–10%, 10–20%, 20–30%, 30–40% and 40–50%, maintained by controlled application of a 0.1% H2O2 solution. It was demonstrated that the gradual increase in oxygen concentration in treated wastewater due to H2O2 dosing resulted in an increase in ammonia nitrogen removal from 39.0 to 81.2%. The best removal efficiency was obtained when the oxygenation level was in the range of 30–40%. It was also shown that application of hydrogen peroxide resulted in an effective removal of biochemical oxygen demand (BOD5). The highest BOD5 removal efficiency (94.3%) was obtained at the oxygenation level of 30–40%. The results indicate that oxygenation of wastewater with hydrogen peroxide can be applied for the optimization of the nitrification process in wastewater treatment plants.

The aim of this work was to determine the technological reliability of pollutions removal in different seasons in one-stage constructed wetland system with horizontal flow operating in the conditions of moderate climate. In the above-mentioned system, willow (Salix Viminalis L.) was planted and the average flow of domestic sewage were 1.2 m3/d. The analyzed system is located in south-eastern Poland, where the climate is moderate transitional. The tests were carried out during the 14-year exploitation of the wastewater treatment plant (1997–2010). During this period, sewage samples were collected in 4 seasons (winter – February, spring – may, summer – August and autumn – November) to be analyzed. The average long-term air temperatures in these months were respectively: −1.8; 13.8; 18.3 and 3.5 °C. Altogether 56 series of analyzes were carried out during the research and 112 samples of the sewage, both from the inflow and the outflow of the wastewater treatment plant, were collected. The measured parameters were: BOD5, COD, total nitrogen, total phosphorus. On the grounds of the reliability analysis performed on the basis of the Weibull probability model, it was found that the reliability of pollutions removal in the tested constructed wetland system are higher in summer and autumn (August, November) than in winter and in spring (February, May). It was shown that exceedance of the admissible values ​​of pollutant indicators in treated wastewater is dependent on the season (air temperature) and it occurred mainly in the winter period (February). It was proved that the tested CW does not provide effective elimination of biogenic indicators (nitrogen and phosphorus), as evidenced by small values ​​of reliability. To increase the technological reliability of the tested treatment plant, it is proposed to expand the existing system and create a hybrid system consisting of two beds with vertical and horizontal flow and a special P-filter. info:eu-repo/semantics/acceptedVersion

tThe aim of the study was to determine the influence of the particle size of carbonate–silica rock (opoka)used in rock filters on the efficiency of phosphorus removal from domestic wastewater. The investigationswere carried out in a laboratory using a model consisting of three vertical flow filters with carbonate–silicarock of different particle sizes (G1= 1–2 mm; G2= 2–5 mm; G3= 5–10 mm). The tested rock was subjectedto decarbonising at 900◦C and consisted primarily of 51.7% SiO2, 23.2% CaO, and 7.6% Al2O3. In the firstthree weeks of the study (1–3), the hydraulic load of each filter was Q1= 0.72 l/day and the hydraulicresidence time was HRT1= 24 h; in the next three weeks (4–6) Q2= 1.08 l/day and HRT2= 16 h, and duringthe last three weeks (7–9) Q3= 1.44 l/day and HRT3= 12 h. A significant influence of the size of rock parti-cles and the hydraulic load (hydraulic residence time) on the efficiency of total phosphorus removal andon phosphorus concentration in the wastewater discharged from the system was observed ( = 0.05).Statistically, the best removal of phosphorus from wastewater – an average of 97%, was found in thesubstrate with the smallest particle size (rock G1, 1–2 mm) at the lowest hydraulic load of 0.72 l/dayand at a hydraulic residence time of 24 h. The lowest phosphorus removal efficiency was observed inthe filter containing rock G3with a particle size of 5–10 mm (mean

Under conditions of low funding for the production of “green energy” in Poland, it became necessary to search for other – cheaper sources of biomass and the development of more efficient technologies. The maize straw is waste material arising in the production of grain. Therefore currently has no wider application and the cost of acquisition is several times lower than in case of maize silage. This paper presents the results of research on biogas efficiency of the maize straw silage, the dynamics of the fermentation process and the decomposition time of biomass under the meso- and thermophilic conditions. Moreover, the exploitation costs of a biogas plant working on this substrate and maize silage have been compared. It has been proved that thermophilic fermentation is significantly shorter (17%) than mesophilic and permits to increase biogas production (8.6%) and methane content (9.3%). In turn, mesophilic fermentation has more stable pH changes in comparison with the thermophilic technology. However, it is related to inhibition of the propionic acid, which can be of great importance in case of continuous fermentation. On the basis of energetic calculations it was shown that the substitution of the maize silage with the maize straw silage allows for nearly three-fold costs reduction and thus increase of the biogas plant profitability.

The hydraulic loading of biofilter (HL), temperature and C/N ratio - these factors influence on nitrogen and carbon removal efficiency from airport wastewater containing de-icing agents. The vast area of airports and significant fluctuations in atmospheric precipitation contribute to huge differences in wastewater flows discharged to treatment systems. The aim of the study was to determine the influence of the hydraulic loading on nitrogen and organic compounds removal in biofilters in low temperatures. The novelty of the paper results from low temperatures (0, 4 and 8 °C), specific wastewater and biofilter filling (light weight aggregates prepared from fly ashes from sewage sludge thermal treatment (FASST LWA). The study was divided into four series differing in the hydraulic loading (1.0, 3.0, 5.0, and 10.0 L·m−2·d−1). In each series, biofilters (filled with FASST LWA) were operated at the temperature of 0, 4, 8 °C and 25 °C. The organic carbon to nitrogen ratio was 0.5. The study showed the effective removal of nitrogen at low temperatures, even at high HL. The highest efficiency of nitrogen removal at the temperature of 0 °C (34.93 ± 4.54%) was obtained at 5.0 L·m−2·d−1. The hydraulic loading and temperature affected the efficiency of nitrogen and COD removal. The presented experiment demonstrated that the use of biofilters filled with FASST LWA may offer an effective and sustainable method for the treatment of airport de-icing wastewater.

This paper reports a comparative study on kinetics of organic matter expressed as BOD5 and nitrogen removal in constructed wetlands operated in Poland. Analyzed data were collected at eight wetland systems, composed of subsurface flow beds: horizontal flow (HF) and vertical flow (VF), in different number and sequences. The analysis involved particularly mass removal rates (MRR) and first-order removal rate coefficients of BOD5 and total nitrogen (kA and kv for VF and HF filters, respectively, and k20 as a parameter averaged for a temperature of 20 °C). It was found that the higher the load of pollutants applied to the beds, the higher MRR values were obtained. The average k-rates in analyzed systems were mostly lower than those reported in the literature, especially in the case of total nitrogen. Its removal obtained in horizontal flow beds was kv = 0.002–0.042 d−1, while in vertical flow systems kA varied from 0.007 m d−1 to 0.0037 m d−1. According to data given by previous studies, first-order reaction rates for nitrogen removal varied in range from kv = 0.048 d−1 to kv = 0.19 d−1 and kA from 0.007 to 0.1 m d−1 in HF and VF beds, respectively. Regarding BOD5 shown in literature, removal rate kv for HF beds varied from 0.071 to 6.11 d−1, and kA for VF beds varied from 0.019 to 1.0 m d−1, while in this study lower k-rates were obtained: kv = 0.005–0.085 d−1 and kA = 0.015–0.130 m d−1. Relatively long monitoring period, for some of constructed wetland up to 16 years, resulted in good data set and enables creation of the graphs, which could be helpful in evaluation and designing of constructed wetlands for PE bigger than 50, in moderate climate conditions.

The aim of this work was to determine the potential of phytoremediation of Vetiveria zizanioides and Oryza sativa to nitrate (NO3−-N) and organic matter (COD – chemical oxygen demand) removal in subsurface vertical flow constructed wetland systems (VFCWs). The tests were carried out in models of 2 beds with a surface of 0.24 m2 and depth 0.70 m each at various hydraulic loads (HL) and COD constant in influente wastewater. The VFCW-1 bed was planted with the Vetiveria zizanioides and the VFCW-2 bed with the Oryza sativa. During the 22 weeks of research, the hydraulic load of the analyzed beds was: HL1 = 148 dm3·m−2·d−1, HL2 = 239 dm3·m−2·d−1, HL3 = 350 dm3·m−2·d−1, HL4 = 473 dm3·m−2·d−1. The VFCWs were fed from two reservoirs, one with mineral medium and nitrate, and the other one with fructose as organic matter. Based on the conducted tests, it was found that in both analyzed systems (VFCW-1 and VFCW-2) the highest NO3−-N removal rate was found under HL2 – the median is 59 and 42% respectively. The most effective removal of COD in the VFCW-1 system was obtained at a HL2 – 55%, while in the system VFCW-2 at a HL1 – 43%. The research shows that the low HL and high COD/NO3−-N ratio ensures good effects of nitrate and organic matter removal in VF type constructed wetland systems. It has been shown that the analyzed plants, especially Vetiveria zizanioides have good phytoremediation potential in the field of nitrate nitrogen and organic substance removal and can be recommended for use on a full scale of technology.

The paper presents preliminary results of a study on the application of the SCD Probiotics Technology to improve surface water quality. The Technology is based on the principles of the effective microorganism (EM) technology developed in Japan over thirty years ago by Dr Teuro Higa. The study was carried out in 2006–2008 in a pond with an area of 1200 m2, receiving purified sewage discharged from a constructed wetland system with willow vegetation filter, in operation since 1994, to which the SCD Probiotics Technology was applied since September 2007 till June 2008. A decrease of biogens concentrations in the pond water was recorded after applying the tested technology – ammonium nitrate concentration decreased by 85.2%, total nitrogen by 56.9%, while total phosphorus by 77.6%. Chlorophyll a level also showed a decreasing tendency. However, more detailed studies are still required to confirm the effectiveness of the SCD Probiotics technology in the purification of surface water.

Nitrogen removal in treatment wetlands is influenced by many factors, and the presence of electron donors (biodegradable organic matter) and electron acceptors (nitrate ions) is the main limiting one; for obtaining these conditions, multistage treatment wetlands (MTWs) are required, where an extensive nitrification can be obtained in the first stages under aerobic conditions leaving then to the following anoxic/anaerobic stages the duty of the denitrification. Most of the biodegradable organic matter is however oxidised in the first stages, and therefore, the inlet to the denitrification beds is usually poor of easily degradable carbon sources. This study is comparing the long-term performances obtained at several MTWs operating in Europe (North and South) and North Africa in order to understand if there is a significant avail in making use of the influent chemical oxygen demand (COD)/N ratio during the design phase for ensuring proper performances in terms of N overall removal. The statistic analysis performed in this study have shown that MTWs are capable to ensure sufficient removal of both organic and nutrients even in unfavourable proportions of macronutrients (C and N). The usual assumptions for conventional biological treatment systems concerning adequate C/N ratios seem to be dubious in case of wastewater treatment in MTWs.

Agricultural biogas plants produce biogas and residues referred to as digested pulp. In Europe, digestate is mostly used as fertilizer for agricultural soils although it can be converted to solid fertilizer and also used for biofuel production. The aim of this study was to evaluate if solid fraction of the digestate (DSF) is a suitable material for composting. Composting of DSF was performed for 51 d in a specially designed and constructed system of composting bioreactors (each with volume of 165 l). The process was controlled by daily measurements of temperature and gaseous emissions and samples of composted material tested for dry and organic matter, pH and conductivity. The maximum temperature of the composted mixture was 70.2 °C. High temperature (over 60 °C) for at least two days will allow to annihilate most pathogens. Dynamic temperature rise was related to significant decrease in organic matter (by 39.6%) – from an initial 8.46 kg to 5.12 kg at the end of the process. Decomposition of organic matter during the thermophilic phase of composting was also related to intensive emissions of CO2. The maximum values of carbon dioxide occurred at the highest compost temperature on the third day of the experiment and amounted to 13.3% in the chamber. The results of the analysed parameters allowed us to conclude that the composting process was operating properly and that composting of DSF can a solution for the management of biogas effluent.