1. Biosorption of copper(II) onto spent biomass of Gelidiella acerosa (brown marine algae): optimization and kinetic studies
- Author
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King Pulipati, Krupanidhi Srirama, Sumalatha Boddu, John Babu Dulla, and Mohan Rao Tamana
- Subjects
Optimization ,lcsh:TD201-500 ,Aqueous solution ,Extraction (chemistry) ,Biosorption ,chemistry.chemical_element ,Biomass ,02 engineering and technology ,010501 environmental sciences ,021001 nanoscience & nanotechnology ,01 natural sciences ,Copper ,Kinetics ,Adsorption ,lcsh:Water supply for domestic and industrial purposes ,Wastewater ,chemistry ,Response surface methodology ,0210 nano-technology ,Gelidiella acerosa ,0105 earth and related environmental sciences ,Water Science and Technology ,Nuclear chemistry - Abstract
This study exclusively focused on the potential application of an inexpensive and sustainable waste macro-algal biomass as an adsorbent for biosorption of copper ions from aqueous medium. After extraction of agar from brown macro-marine algaeGelidiella acerosa, the residual biomass without any further treatment was used as an adsorbent for the expulsion of copper from wastewater. Physicochemical parameters of biosorption like initial pH, initial concentration of Cu(II) solution and biosorbent dosage were optimized using response surface methodology. The maximum copper biosorption potential of 96.36% was observed at optimum conditions of pH of 5.31, initial concentration of 23.87 mg/l and biosorbent dosage of 0.41 g/l. Adopting FTIR and SEM techniques, the surface morphological features of biosorbent were studied. The pseudo-second-order kinetic model was found to be a proper approach to describe biosorption kinetics. All these results confirmed that spentG.acerosacould be considered as an efficient, eco-friendly and economic alternative for Cu(II) removal from aqueous solution.
- Published
- 2020