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2. Interpretation of electrochemical reduction and oxidation waves of quinone–hydroquinone system in acetonitrile

Author

B. R. Eggins

Subjects
chemistry.chemical_compound, Perchlorate, Tetraethylammonium, Hydroquinone, Chemistry, Supporting electrolyte, Inorganic chemistry, Acetonitrile, Benzoquinone, Lithium perchlorate, Quinone
Abstract

When tetraethylammonium perchlorate is used as the supporting electrolyte, benzoquinone is reduced in two reversible one-electron waves, but with lithium perchlorate ion pairing can occur and the behaviour is more complex.

Published
1969
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3. Evidence for a one-electron intermediate in the anodic oxidation of hydroquinone in acetonitrile

Author

B. R. Eggins

Subjects
chemistry.chemical_compound, Hydroquinone, chemistry, Anodic oxidation, Diffusion, Electrode, Inorganic chemistry, Molecular Medicine, Electron, Photochemistry, Acetonitrile
Abstract

The oxidation of hydroquinone at rotating-disc electrodes clearly indicates a one-electron, not a two-electron, process when the diffusion coefficients of the species compared are taken into account.

Published
1972
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