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The production of long flax fiber for the subsequent production of textile yarn is accompanied by the formation of a significant amount of waste—noils, which is a mechanical mixture of long and short flax fibers and shives. Comparative studies of the structure and chemical composition of the fibrous fraction of noils and shives were carried out using IR spectroscopy. The solubility of shives and flax noils in N-methylmorpholine-N-oxide (NMMO) was studied, a comparative analysis of the rheological behavior of solutions of flax and wood cellulose was carried out and the optimal temperature–concentration conditions for obtaining flax fibers from noils were determined. It was shown for the first time that using the method of solid-phase activation of the cellulose-solvent system makes it possible to obtain fibers in a short period of time (no more than 10 min). The structure of both the raw material and the resulting fibers was studied by X-ray diffraction analysis. The thermal properties of a new type of cellulose fibers was evaluated. The complex of the conducted studies allows us to consider flax fibers from noils along with flax fibers from long-staple flax, as a real alternative to fibers from wood pulp.

This research examines the possibilities of regulating the structure of cellulose precursor fibers spun from solutions in N-methylmorpholine-N-oxide when replacing aqueous coagulation baths with thermodynamically softer alcohol baths at different temperatures. The fibers were spun by the dry jet–wet method in isobutanol coagulation baths with a temperature of 25 °C and 70 °C. The study of the phase state of the solvent–coagulant system using viscometry and point cloud methods revealed the temperature-concentration regions of the single-phase and two-phase states of the system. Using elemental analysis, DSC (differential scanning calorimetry) and XRD (X-ray diffraction) methods, it was shown that just spun fibers, due to the presence of a residual amount of solvent and coagulant in them, regardless of the temperature of the precipitator, have an amorphous structure. Additional washing with water completely washed away the solvent and coagulant as well, however, the structure of cellulose changes slightly, turning into a defective amorphous-crystalline one. A relationship was found between the phase composition, structure, and properties of just spun fibers and precursors washed with water. Thus, the loss of structural ordering of both just spun and washed cellulose fibers leads to a decrease in strength characteristics and an increase in deformation. The thermal behavior of the fibers is determined by their phase composition. Fibers just spun into hot alcohol containing a coagulant and traces of solvent acquire thermal stability up to 330 °C. During the pyrolysis of the obtained precursors up to 1000 °C, the value of the carbon yield doubles. The amorphized structure of the obtained fibers allows us to consider it as a model when analyzing the transformation of the structure of precursors during thermolysis.