Search

Your search keyword '"Mulder, Willem H."' showing total 3 results
Start Over Author "Mulder, Willem H." Topic chemicals, plastics and rubber industries
3 results on '"Mulder, Willem H."'

1. Valence-state atoms in molecules. 7. Influence of polarization and bond-charge on spectroscopic constants of diatomic molecules

Author

Donald, Kelling J., Mulder, Willem H., and Von Szenpaly, Laszlo

Subjects
Polarization (Nuclear physics) -- Influence, Molecules -- Properties, Valence -- Analysis, Chemicals, plastics and rubber industries
Abstract

The polarizable valence state potential energy curve (pVS-PEC) is derived through the systematic improvement of the valence state potential energy curve (VS-PEC) and is given as U(R) = -[(K1/R) + (K2/R (super 4)) + (K3/R (super 7)) + T/R exp (-Lambda R). The potential is tested on a broad variety of homonuclear diatoms and heteronuclear halides and hydrides.

Published
2004

2. Theory of the salt effect on solvatochromic shifts and its potential application to the determination of ground-state and excited-state dipole moments

Author

Mulder, Willem, H

Subjects
Cyclopropane compounds -- Chemical properties, Cyclopropane compounds -- Research, Isomerism -- Research, Isomerism -- Chemical properties, Polymer solutions -- Chemical properties, Polymer solutions -- Research, Chemicals, plastics and rubber industries
Abstract

The theory of solvatochromism based on a dielectric continuum description of the solvent and the classical Onsager cavity model was investigated and was extended to include the effect of an added 1:1 salt. The equations differed markedly for salt-free case, from several others reported in the literature dealing with the pure solvent effect and the discrepancy was clarified.

Published
2002

3. Additions and corrections

Author

Mulder, Willem H.

Subjects
Chemical equilibrium -- Models, Monomolecular films -- Models, Chemicals, plastics and rubber industries
Published
1998

Catalog

Books, media, physical & digital resources
See catalog results