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When using a wrench, the nut is easily damaged due to improper operation or impact. Although coating a polymer layer on the surface of the wrench can effectively solve the above problem, the layer is easy to be deboned due to the lack of adhesion between the polymer and the surface of the wrench. Herein, we implemented an anodizing treatment strategy on the surface of the wrench to obtain a porous oxide film. Interestingly, during the anodization process, micro-nanopores with a specific diameter can be obtained by adjusting the voltage, temperature, and electrolyte concentration. Furthermore, the ammonium fluoride/ethylene glycol electrolyte was used to etch the formed large hole to form the large hole sleeve small hole structure. In order to inject polyphenylene sulfide (PPS) molecules into multiscale holes to form a pinning effect, we also used nano molding technology to inject PPS into the metal surface. The results showed that the adhesion between PPS and the wrench was greatly improved compared with the commonly used dip coating method.

Three-dimensional (3D) network topological structure composite (3D-NTSC) is a new type of composite in which both the matrix phase and the reinforced phase have 3D continuous network structure and interweave with each other. Different from fiber reinforcement and particle reinforcement, the reinforcing phase in the composite material runs through the whole matrix phase in a continuous form without destroying the topological continuity of the matrix phase, so that each matrix phase in the composite material can not only maintain its own excellent performance, but also can cooperate with each other and complement each other, so that the composite material can play a greater performance advantage. In recent years, 3D-NTSC has attracted the attention of researchers and has been widely used in practical production. At present, there are no comprehensive articles summarizing the research progress of this kind of materials. In this review, we discussed the recent progress of the preparation methods, including natural flow method, vacuum infiltration process, pressure filling method, in situ filling method, and co-building method. Furthermore, research progress on mechanical properties and some regular results, shortcomings, challenges, and prospects of 3D-NTSC were also put forward, which would be helpful to people working in the related fields.