1. Ce3+/Ce4+-Doped ZrO2/CuO Nanocomposite for Enhanced Photocatalytic Degradation of Methylene Blue under Visible Light
- Author
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Manh Nhuong Chu, Lan T. H. Nguyen, Mai Xuan Truong, Tra Huong Do, Thi Tu Anh Duong, Loan T. T. Nguyen, Mai An Pham, Thi Kim Ngan Tran, Thi Cam Quyen Ngo, and Van Huan Pham
- Subjects
Chemical Health and Safety ,Ce3+/Ce4+ ,mixed semiconductor oxide ,hydrothermal ,photocatalysis ,methylene blue ,Health, Toxicology and Mutagenesis ,Toxicology - Abstract
In recent years, photocatalysis has been used as an environmentally friendly method for the degradation of organic pigments in water. In this study, Ce3+/Ce4+-doped ZrO2/CuO as a mixed semiconductor oxide was successfully prepared by a one-step hydrothermal method. The Ce3+/Ce4+-doped ZrO2/CuO has shown high degradation efficiency of methylene blue (MB), and the maximum degradation percentage was observed to be 94.5% at 180 min under irradiation visible light. The photocatalytic activity increases significantly by doping Ce3+/Ce4+ in ZrO2/CuO for MB degradation. Ce3+/Ce4+ doping is shown to reduce the (e-/h+) recombination rate and improve the charge transfer, leading to enhanced photocatalytic activity of materials. The materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), FTIR, EDS, BET and diffuse reflectance spectroscopy (DRS).
- Published
- 2022
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