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Abstract: The mechanism of methane reforming with carbon dioxide over 1.0wt.% Rh/SBA-15 catalyst has been studied by the 13C and 1H magic-angle spinning (MAS) NMR spectroscopies under controlled atmosphere condition using 13CH4 + 12CO2 and 12CH4 + 13CO2 as reactants. The effect of temperature in the region of 298–1023K on the reaction was investigated and the contents of various 13C and 1H species were obtained quantitatively by the NMR technique. When treated at 573K, the carbon exchange between methane and carbon dioxide can be observed. With the temperature rising to 773K, the adsorbed CH3O* species is formed but no reforming reaction occurs. In the high temperature range of 873–1023K, the reforming reaction was observed with concomitant appearance of the adsorbed CH2O* species and the intensity of both CH3O* and CH2O* increases with increasing temperature, indicating that the decomposition of CH3O* to CH2O* occurs and the products of dry reforming are formed from decomposition of the adsorbed CH2O* species. [Copyright &y& Elsevier]