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Your search keyword '"Rossenaar, Brenda D."' showing total 1 results
Start Over Author "Rossenaar, Brenda D." Topic charge transfer -- analysis
1 results on '"Rossenaar, Brenda D."'

1. Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 12. The primary photoprocess of (CO)(sub 5)ReMn(CO)(sub 3)(alpha-diimine) complexes studied by temperature- and pressure-dependent photochemistry and pico- and nanosecond flash photolysis

Author

Rossenaar, Brenda D., Graaf, Tim van der, Eldik, Rudi van, Langford, Cooper H., Stufkens, Derk J., and Vicek, Antonin, Jr.

Subjects
Charge transfer -- Analysis, Coordination compounds -- Research, Chemistry
Abstract

Time-resolved UV-vis absorption spectroscopy and nano-second flash photolysis analyze the photoreactions of three (CO)(5)ReMn(CO)(3) (alpha-diimine) complexes at different temperatures and pressures. Primary photoprocess in the metal-to-ligand charge-transfer excitation of these complexes is a fast CO dissociation from Mn center. High reactivities of these complexes are due to an available Mn coordination site and a weak Re-M bond.

Published
1994

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