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African woodlands form a major part of the tropical grassy biome and support the livelihoods of millions of rural and urban people. Charcoal production in particular is a major economic activity, but its impact on other ecosystem services is little studied. To address this, our study collected biophysical and social datasets, which were combined in ecological production functions, to assess ecosystem service provision and its change under different charcoal production scenarios in Gaza Province, southern Mozambique. We found that villages with longer histories of charcoal production had experienced declines in wood suitable for charcoal, firewood and construction, and tended to have lower perceived availabilities of these services. Scenarios of future charcoal impacts indicated that firewood and woody construction services were likely to trade-off with charcoal production. However, even under the most extreme charcoal scenario, these services were not completely lost. Other provisioning services, such as wild food, medicinal plants and grass, were largely unaffected by charcoal production. To reduce the future impacts of charcoal production, producers must avoid increased intensification of charcoal extraction by avoiding the expansion of species and sizes of trees used for charcoal production. This is a major challenge to land managers and policymakers in the area. [ABSTRACT FROM AUTHOR]

• Charcoal kiln soils double the amount of Soil Organic Carbon and Total Nitrogen. • The different woodland types in the study have the same benefits in SOC and TN sequestration. • SOC content found in the studied woodlands is less than half of other semi-arid woodlands. • The findings are important for the SSA countries implementing monitoring, report and verification methods (MRV). African woodland ecosystems function as important reservoirs for soil organic carbon (SOC) and total nitrogen (TN). However, these ecosystem functions are particularly sensitive to social-ecological factors, the impacts of which remain understudied. Here, we examine how SOC and TN and other soil properties vary across woodland types and how charcoal production, the main source of woodland disturbance in the study area, changes these factors in dry woodlands of southern Africa, focusing on three woodland ecosystems that represent the main types in southern Mozambique: Androstachys forest, Combretum woodland and Mopane woodlands. Drawing on data from soil surveys at 0–5 cm and 0–30 cm depth in different vegetation types as well as both distant from and proximate to sites of active charcoal production, we estimate that these woodlands in Mabalane District store on average 19 ± 10 (±SE) Mg ha−1 of SOC, and 2.2 ± 0.9 Mg ha−1 of TN at 0–30 cm, significantly lower than values reported for other woodlands in the region such as Miombo. Our analysis shows that the woodland types do not differ in terms of the amount of SOC and TN stored in soil, and that soil in the charcoal kilns had twice the amount of SOC (30.0 ± 1.8 Mg ha−1) and TN (4.5 ± 0.5 Mg ha−1) compared with non-charcoal soils. This study adds to our understanding of the impact of charcoal production on soil SOC and TN in dry woodlands of southern Africa, and demonstrates some localised impacts of charcoal production. We discuss the implications of our findings in the light of emerging carbon-based payments for ecosystem services programmes in the region. [ABSTRACT FROM AUTHOR]