1. An efficient dynamic asymmetric catalytic system within a zinc-templated network
- Author
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Ignacio Alfonso, Ciril Jimeno, Anna Serra-Pont, Jordi Solà, Consejo Superior de Investigaciones Científicas (España), Alfonso, Ignacio [0000-0003-0678-0362], Solà Oller, Jordi [0000-0002-3389-3429], Serra-Pont, Anna [0000-0002-7174-3712], Alfonso, Ignacio, Solà Oller, Jordi, and Serra-Pont, Anna
- Subjects
010405 organic chemistry ,Chemistry ,Metals and Alloys ,Enantioselective synthesis ,chemistry.chemical_element ,Cooperativity ,General Chemistry ,Zinc ,010402 general chemistry ,01 natural sciences ,Combinatorial chemistry ,Catalysis ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Bipyridine ,chemistry.chemical_compound ,Dynamic asymmetric catalytic system ,Single species ,Materials Chemistry ,Ceramics and Composites ,Stereoselectivity - Abstract
Enhanced cooperativity leading to high catalytic activity and stereoselectivity has been achieved through a complex network of simple species interacting reversibly. This novel dynamic catalytic system relies on bipyridine-based organocatalytic ligands and zinc(II) as the template. It demonstrates the effectiveness of dealing with mixtures rather than single species in asymmetric catalysis., We acknowledge support of the publication fee by the CSIC Open Access Support Initiative through its Unit of Information Resources for Research (URICI)
- Published
- 2019