1. Fabrication of microfibrillated cellulose from biomass by use of carbon nitride with high nitrogen/carbon ratio.
- Author
-
Zhang T, Feng C, Li A, Zhu Y, Jin C, Na H, Liu F, and Zhu J
- Subjects
- Cellulose chemistry, Biomass, Nitrogen chemistry, Carbon chemistry, Nitriles chemistry
- Abstract
Microfibrillated cellulose (MFC) as an attractive green bio-based material has attracted widespread attention in recent years due to its non-toxicity, degradability, excellent performance, and high aspect ratio. In this study, the g-C
3 N5 with a high nitrogen/carbon ratio was prepared as a catalyst through the self-polymerization of a nitrogen-rich precursor. The triazole groups at the edges of g-C3 N5 were proven to exhibit strong adsorption to biomass and strong alkalinity. In a low-acidic aqueous system with g-C3 N5 , MFC with diameters of 100-200 nm and lengths up to 100 μm was fabricated from various biomasses within 5 min under microwave radiation. The ultimate yield of the MFC produced from viscose reached 90 %. Young's modulus of the MFC reaches 3.7 GPa. This work provides a particular method with high efficiency to prepare MFC with excellent properties from biomass by chemical method., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
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