1. Multifunctional bacterial cellulose-based organohydrogels with long-term environmental stability.
- Author
-
Guo WY, Yuan Q, Huang LZ, Zhang W, Li DD, Yao C, and Ma MG
- Subjects
- Electric Conductivity, Humans, Hydrogels, Polyvinyl Alcohol, Cellulose, Wearable Electronic Devices
- Abstract
Sensitive strain sensors have attracted more attention due to their applications in health monitoring and human-computer interaction. However, the problems existing in conventional hydrogels, such as inherent brittleness, freezing at low temperature, low toughness, and water evaporation, have greatly hindered the practical applications. In order to solve the above problems, herein, we designed dual network multifunctionality organohydrogels using polyvinylpyrrolidone (PVP) and polyvinyl alcohol (PVA) covalent cross-linking polymer as the first network, the bacterial celluloses (BCs) and calcium chloride by ligand binding as the second network. The prepared organohydrogels showed good conductivity and sensitivity over a wide temperature range (-20 ∼ 40 ℃), and maintained long-term stability (>15 days) in the air. In addition, the dynamic combination of BCs-Ca
2 + and hydrogen bonds in the binary system further endows the organohydrogels with excellent tensile strength (≈1.0 MPa), tensile strain (≈1300%), toughness (≈6.2 MJ m-3 ), conductivity (3.4 S m-1 ), gauge factor (≈1.24), adhesion (≈0.3 MPa), and self-healing properties (self-healing tensile strain to 632%). Therefore, this organohydrogel has potential candidates for flexible electronic skin, motion monitoring, and soft robotics., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier Inc. All rights reserved.)- Published
- 2022
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