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In 1993, a fossil hominin skeleton was discovered in the karst caves of Lamalunga, near Altamura, in southern Italy. Despite the fact that this specimen represents one of the most extraordinary hominin specimens ever found in Europe, for the last two decades our knowledge of it has been based purely on the documented on-site observations. Recently, the retrieval from the cave of a fragment of bone (part of the right scapula) allowed the first dating of the individual, the quantitative analysis of a diagnostic morphological feature, and a preliminary paleogenetic characterization of this hominin skeleton from Altamura. Overall, the results concur in indicating that it belongs to the hypodigm of Homo neanderthalensis, with some phenetic peculiarities that appear consistent with a chronology ranging from 172 ± 15 ka to 130.1 ± 1.9 ka. Thus, the skeleton from Altamura represents the most ancient Neanderthal from which endogenous DNA has ever been extracted., (Copyright © 2015 Elsevier Ltd. All rights reserved.)

Lamalunga Cave (Altamura, Southern Italy) is renowned for the discovery in 1993 of an excellently preserved Neanderthal skeleton. Given the importance of the findings and the potential use of Lamalunga speleothems for paleoclimate reconstructions, a detailed monitoring program was undertaken to investigate the connections between microclimate parameters and speleothem growth. The cave air temperature is characterized by annual sinusoidal cycles with increasing phase shift and decreasing thermal amplitude from ± 2.1°C to ± 0.04°C as a function of increasing rock overburden, and daily to sub-daily cycles induced by surface air pressure (SAP) variations characterized by strong 24-hour and 12-hour solar harmonic frequencies, with thermal amplitude decreasing from 0.0054°C to 0.0021°C in the deeper parts of the cave. The ventilation regime is mainly controlled by SAP fluctuations. Fast SAP rises can trigger "emptying events" during which most of the cave air is replaced and the CO2 concentration falls towards near-atmospheric values. The steady and gentle ventilation created by SAP fluctuations also influences the growth and morphology of calcite coralloids, with larger popcorn assemblages concentrated in the northern galleries and delicate branching morphologies prevailing along the South Gallery where stable temperature and relative humidity conditions occur. The study is a seminal example of how high-precision measurements of cave air temperature can provide a wealth of information on cave ventilation and thermal regime and provide valuable support for robust paleoclimate reconstruction from speleothems. [ABSTRACT FROM AUTHOR]

Modern to Holocene tropical Pacific stalagmites are commonly difficult to date with the U-series, the most commonly used dating method for speleothems. When U-series does not provide robust age models, due to multiple sources of 230Th or little U, radiocarbon is, potentially, the best alternative. The 14C content of two stalagmites (Pu17 and Nu16) collected from Pouatea and Nurau caves in the Cook Island Archipelago of the South Pacific were measured to obtain accurate chronology for their most modern parts. The bomb-pulse soil continuum modelling indicates that bomb radiocarbon in Pu17 onsets in 1956 and reaches its maximum in 1966 CE, suggesting a fast transfer of atmospheric carbon to the stalagmite of <1 year. The modelling for Pu17 suggests a 20% contribution from C 1 - an instantaneous carbon source, which renders possible an immediate transfer of atmospheric signal into the cave. Nu16 shows a slower transfer of atmospheric carbon to the stalagmite than Pu17, with bomb radiocarbon onsetting in 1957 CE and peaking in 1972 CE. The less negative δ13C values in Nu16 than Pu17, and also the modelling corroborated this, which points out no contribution from the instantaneous carbon source. The radiocarbon age models and laminae counting age models were then spliced to achieve a single master chronology for the top part of each stalagmite. This study is an example of 14C age modelling combined with visible physical and chemical laminae counting and how it can improve the accuracy and precision of dating for otherwise hard-to-date tropical Pacific speleothems. Such accurate and precise age models pave the way to obtain sub-annually resolved paleoclimate records by further improving the calibration of climate proxy data with the current and instrumental weather parameters. [ABSTRACT FROM AUTHOR]

Sulphate concentrations in speleothems identify major volcanic eruptions, provide useful information on soil and aquifer dynamics and, in similar fashion to the 14 C bomb peak, its Anthropocene peak can be used to date recent cave formations. However, the transmission of S from the atmosphere to cave dripwater and its incorporation in speleothems is subjected to biogeochemical cycling and accurate studies of each cave site are needed in order to assess how the S atmospheric signal is modified and eventually encoded in speleothems. This study investigates the role of biogeochemical cycling and aquifer hydrology by utilising published and new dripwater and speleothem data from Grotta di Ernesto (ER) in northern Italy. Here we provide the first long-term record of sulphate concentration in cave dripwater based on over 20 years of measurements. Fast drip site st-ER1 is characterised by a continuous decrease in SO 4 concentration from a high of 7.5 ± 0.8 mg/l in 1993–1994 to a low of 2.2 ± 0.2 mg/l in 2013–2014, and replicates with a delay of ∼15 years the decline in the atmospheric SO 2 emissions. The S-series of slow flow ER78 site is further delayed by ∼4.5 years in relation to the S retention in the aquifer matrix. The dripwater data are used to extend the previously published S record (1810–1998 AD) of stalagmite ER78 and reconstruct the anthropogenic S-peak: this displays a delay of ∼20 years with respect to the atmospheric S emission peak due to biogeochemical cycling and aquifer storage. However, sulphur recycling above the cave did not operate with the same degree of efficiency through time, which resulted in a variable time delay between S deposition and incorporation into the stalagmite. In the pre-Anthropocene era, and in particular during the cold Little Ice Age, biogeochemical cycling was far less efficient than today, and the fast transmission of the atmospheric signal allowed capture of S released during major volcanic eruptions by stalagmites. [ABSTRACT FROM AUTHOR]

Carbon dioxide (CO2) concentrations in caves and parent soils in the Italian Alps have been studied along a 2100 m altitudinal range - corresponding to a mean annual temperature (MAT) range of 12°C - in order to investigate the relationship between MAT, soil pCO2 and cave air pCO2, and to test the influence of soil pCO2 on speleothem growth and fabric to ultimately gain insight into their palaeoclimatic significance in temperate climate settings. Our findings indicate that soil CO2 is linearly correlated to MAT and its mean annual concentration is described by the equation: soil CO2 (ppmv) = 1112 + 460 MAT. Soil pCO2 can also be exponentially correlated to actual evapotranspiration. The pCO2 in the aquifer is linearly correlated to MAT at the infiltration site and is more influenced by summer soil pCO2. Cave air CO2 in the innermost part of the caves exhibits a similar seasonal pattern, and commonly reaches concentrations of about 15% to 35%, with respect to the corresponding soil values, and is exponentially correlated to the MAT at the infiltration site. The combination of these parameters (soil pCO2, dripwater pCO2 and cave air pCO2) results in speleothem growth and controls their fabrics which are typical of four MAT/elevation belts broadly corresponding to the present-day vegetation zones. In the lower montane zone [100-800 m above sea level (a.s.l.)] speleothems mostly consist of columnar fabric, in the upper montane zone (800-1600 m a.s.l.) both columnar and dendritic fabrics are common, the Subalpine zone (1600-2200 m a.s.l.) is characterized mostly by moonmilk deposits, whereas in the Alpine zone (above 2200 m a.s.l.) no speleothems are forming today. Therefore, fabric changes in fossil speleothem can potentially be used to reconstruct MAT changes in temperate climate karst areas. Copyright © 2015 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

Past climate archives show the Last Interglacial (LIG) period as similar to slightly warmer than current temperatures. However, there is a lack of LIG proxy evidence regarding variations of the climate across large topographic features and how this manifests at different altitudes. Here, we analysed two flowstones from Bigonda Cave, northeast Italy, to reconstruct LIG climate conditions in a region where precipitation is strongly influenced by the presence of the Alps. Stable isotope ratios, trace element concentrations and speleothem petrography from 133 ka to 105 ka allowed the detection of various hydroclimate and environmental conditions. Composite speleothem δ18O records from northeast Italy were found to closely follow the Northern Hemisphere summer insolation curve, attesting to the influence of solar isolation on Earth's hydroclimate. Our reconstructions indicate a northward shift of the Intertropical Convergence Zone during the LIG maximum, permitting Atlantic-derived moisture to travel further east across North Africa than at present, before being directed north towards the Alps. The latter part of the LIG exhibited frequent, extreme precipitation events in the SE Prealps due to orographic lifting of moisture from both the Atlantic and Mediterranean seas. Socio-economic planning must prepare for extreme autumnal flooding events and serious summer droughts, particularly important in vulnerable mountainous regions. • Last Interglacial speleothem multi-proxy records from the NE Italian Prealps. • Three infiltration sources identified permits robust hydroclimate reconstruction. • Solar insolation was the main forcing mechanism of the oxygen isotope record. • The LIG was punctuated by hot dry summers and extreme cave flooding events. [ABSTRACT FROM AUTHOR]

Stalagmite SV1 from Grotta Savi, located at the SE margin of the European Alps (Italy), is the first Alpine speleothem that continuously spans the past c . 17 kyr. Extension rate and δ 18 O c record for the Lateglacial probably reflect a combination of temperature and rainfall, with rainfall exerting the dominant effect. Low speleothem calcite δ 18 O c values were recorded from c . 14.5 and 12.35 kyr, during GI-1 (Bølling–Allerød) interstadial, which, in our interpretation, was warm and wet. The GS-1 (Younger Dryas) was characterized by a shift to heavier δ 18 O c , coinciding with δ 13 C c enrichment and extremely low extension rate ( [ABSTRACT FROM AUTHOR]

Organic phosphorus incorporated in calcite during laboratory precipitation experiments and in natural cave deposits was investigated by solid-state NMR spectroscopy. For calcite precipitated in the presence of organic phosphoesters of varying size and functionality, solid-state 31 P{ 1 H} CP/MAS NMR shows that the phosphoesters were incorporated intact into the solid. Systematic changes in the 31 P NMR chemical shift of the phosphate group were observed between the solid phosphoester and that incorporated in the solid precipitate, yielding 31 P NMR chemical shifts of the coprecipitates in the range of +1.8 to −2.2 ppm. These chemical shifts are distinct from that of similarly prepared calcite coprecipitated with inorganic phosphate, 3.5 ppm. Only minor changes were noted in the phosphoester 31 P chemical shift anisotropy (CSA) which suggests no significant change in the local structure of the phosphate group, which is dominated by C–O–P bonding. Close spatial proximity of the organic phosphate group to calcite structural components was revealed by 31 P/ 13 C rotational echo double resonance (REDOR) experiments for coprecipitates prepared with 13 C-labeled carbonate. All coprecipitates showed significant 31 P dephasing effects upon 13 C-irradiation, signaling atomic-scale proximity to carbonate carbon. The dephasing rate for smaller organophosphate molecules is similar to that observed for inorganic phosphate, whereas much slower dephasing was observed for larger molecules having long and/or bulky side-chains. This result suggests that small organic molecules can be tightly enclosed within the calcite structure, whereas significant structural disruption required to accommodate the larger organic molecules leads to longer phosphate–carbonate distances. Comparison of 31 P NMR spectroscopic data from the synthetic coprecipitates with those from calcite moonmilk speleothems indicates that phosphorus occurs mainly as inorganic orthophosphate in the natural deposits, although small signals occur with characteristics consistent with phosphate monoesters. The results of this study indicate that trace- to minor concentrations of dissolved organic molecules can be effectively taken up during calcite precipitation and incorporated in the structure, leaving a resilient record of materials present during crystallization. [ABSTRACT FROM AUTHOR]

Conturines cave opens at the base of a cirque wall at 2775 m a.s.l. in the Dolomites(Northern Italy). Large parts of the cave floor are covered by an extensive and unusuallythick (up to 3.4 m) flowstone. This and other speleothems are inactive, corrodedand cut by fractures. Eight drill cores covering the entire stratigraphy of the basalflowstone were obtained along the course of the gallery. Four methods were applied toestablish a chronological framework of this unique long-term paleoenvironmentalarchive. 230Th ages on several cores demonstrate that calcite deposition had terminatedbefore 650 ka BP. U-Pb dating was attempted but yielded unfavourably low U/Pbratios. Polarity determinations of demagnetised samples were carried out on the full length offour cores. Most cores show already reverse magnetisation in their top parts. Two long coresdrilled in the proximal part of the speleothem show replicated evidence of several polaritychanges, providing a strong indication that the flowstone reaches back at least to thePliocene. Finally, pollen was extracted from flowstone samples in order to establish independentpalynostratigraphic constraints. The pollen density is low, but the presence of Nyssa indicatesan Early Pleistocene or Pliocene age. [ABSTRACT FROM AUTHOR]