1. Formation of core-shell Au@Ag nanorods induced by catecholamines: A comparative study and an analytical application.
- Author
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Gorbunova MV, Apyari VV, Dmitrienko SG, and Garshev AV
- Subjects
- Cetrimonium, Cetrimonium Compounds chemical synthesis, Cetrimonium Compounds chemistry, Molecular Structure, Particle Size, Surface Properties, Catecholamines chemistry, Gold chemistry, Nanotubes chemistry, Silver chemistry
- Abstract
Gold nanorods (AuNRs) stabilized by cetyltrimethylammonium bromide (CTAB) were synthesized and an interaction of catecholamines (CAs) with silver ions in the presence of the obtained AuNRs was studied. The reaction results into formation of core-shell Au@Ag nanorods (Au@AgNRs) and leads to a hypsochromic shift of the long-wave surface plasmon resonance (SPR) band in the absorption spectrum of AuNRs. The influence of a CA structure, excess of CTAB, interaction time, pH, concentration of AuNRs, silver ions and CAs on this interaction was studied. Based on correlation of the NRs spectral characteristics with the concentration of CAs, a method for spectrophotometric determination of dobutamine, epinephrine, norepinephrine and dopamine with detection limits 27, 18, 16 and 13 μg L(-1), respectively, has been developed. The method can be applied to the analysis of medicines., (Copyright © 2016 Elsevier B.V. All rights reserved.)
- Published
- 2016
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