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1. Catalyst design for iron-promoted reductions: an iron disilyl-dicarbonyl complex bearing weakly coordinating η2-(H–Si) moieties.

Author

Sunada, Yusuke, Tsutsumi, Hironori, Shigeta, Keisuke, Yoshida, Ryota, Hashimoto, Toru, and Nagashima, Hideo

Subjects
*CATALYSTS, *CHEMICAL synthesis, *CHEMICAL reactions, *HYDROGENATION, *HYDROSILYLATION, *ALKENES, *CARBONYL compounds
Abstract

Iron disilyl dicarbonyl complex 1, in which two H–Si moieties of the 1,2-bis(dimethylsilyl)benzene ligand were coordinated to the iron center in an η2-(H–Si) fashion, was synthesized by the reaction of (η4-C6H8)Fe(CO)3 with 2 equiv. of 1,2-bis(dimethylsilyl)benzene under photo-irradiation. Complex 1 demonstrated high catalytic activity toward the hydrogenation of alkenes, the hydrosilylation of alkenes and the reduction of carbonyl compounds. [ABSTRACT FROM AUTHOR]

Published
2013
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