1. Hydrogenation of Furfural over Ruthenium Catalysts Supported on Porous Aromatic Frameworks.
- Author
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Kulikov, L. A., Makeeva, D. A., Dubiniak, A. M., Terenina, M. V., Kardasheva, Yu. S., Egazar'yants, S. V., Bikbaeva, A. F., Maximov, A. L., and Karakhanov, E. A.
- Subjects
RUTHENIUM catalysts ,HETEROGENEOUS catalysis ,CATALYST supports ,FURFURYL alcohol ,CATALYST testing ,FURFURAL - Abstract
The paper describes an investigation into hydrogenation of furfural over ruthenium catalysts supported on porous aromatic frameworks. The supports were designated as PAF-30-SO
3 H, PAF-30-NH2 , and PAF-30. The synthesized catalysts were tested in furfural hydrogenation carried out in water and in tetrahydrofuran (with a concentration of 10 wt %) at 90–250°C and a hydrogen pressure of 3 MPa. Although the highest furfural conversion (96%) was achieved in the case of its hydrogenation in water at 250°C over Ru-PAF-30, these conditions did not favor product selectivity. The reaction products mainly consisted of furfuryl alcohol, tetrahydrofurfuryl alcohol, and cyclopentanone. The highest yield of cyclopentanone, 71% (with 80% conversion and 89% selectivity) was observed in furfural hydrogenation over Ru-PAF-30 at 200°C, whereas the conditions optimal for selective hydrogenation of furfural into furfuryl alcohol were found to include either tetrahydrofuran as a solvent or water as a solvent and low temperatures (90–150°C). [ABSTRACT FROM AUTHOR]- Published
- 2024
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