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Your search keyword '"Vithalanand R. Kulkarni"' showing total 2 results
Start Over Author "Vithalanand R. Kulkarni" Topic catalysis
2 results on '"Vithalanand R. Kulkarni"'

1. ChemInform Abstract: Phase-Transfer Catalyzed Alkylation of 2-(Diethoxyphosphinyl) cyclohexanone

Author

Suzanne M. Ruder and Vithalanand R. Kulkarni

Subjects
chemistry.chemical_classification, Steric effects, Cyclohexanone, Halide, General Medicine, Alkylation, Medicinal chemistry, Catalysis, Solvent, chemistry.chemical_compound, chemistry, Organic chemistry, Alkyl, Dichloromethane
Abstract

Alkylation of cyclic β-oxophosphonates using the ion pair extractive-phase transfer catalysis method was studied using 2-(diethoxyphosphinyl)cyclohexanone as the model compound. Unlike related phosphonic acid derivatives, the cyclic β-oxophosphonates exhibited ambident character under phase transfer conditions when dichloromethane was used as the solvent. Carbon alkylation was most effective when activated and sterically less demanding alkyl halides were utilized

Published
2010
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2. Phase Transfer Catalyzed Alkylation of 2-(Diethoxyphosphinyl)cyclohexane

Author

Suzanne M. Ruder and Vithalanand R. Kulkarni

Subjects
chemistry.chemical_classification, Ketone, Organic Chemistry, Cyclohexanone, Alkylation, Medicinal chemistry, Catalysis, Solvent, chemistry.chemical_compound, chemistry, Aliphatic compound, Alkyl, Dichloromethane
Abstract

Alkylation of cyclic β-oxophosphonates using the ion pair extractive-phase transfer catalysis method was studied using 2-(diethoxyphosphinyl)cyclohexanone as the model compound. Unlike related phosphonic acid derivatives, the cyclic β-oxophosphonates exhibited ambident character under phase transfer conditions when dichloromethane was used as the solvent. Carbon alkylation was most effective when activated and sterically less demanding alkyl halides were utilized

Published
1993
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