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Start Over Author "Kadota, Joji" Topic catalysis
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1. Ring-Opening Polymerization of L-Lactide Efficiently Triggered by an Amido-Indole. X-ray Structure of a Complex between L-Lactide and the Hydrogen-Bonding Organocatalyst.

Author

Koeller, Sylvain, Kadota, Joji, Deffieux, Alain, Peruch, Frédéric, Massip, Stéphane, Léger, Jean-Michel, Desvergne, Jean-Pierre, and Bibal, Brigitte

Subjects
*RING-opening polymerization, *HYDROGEN bonding, *AMIDES, *CHEMICAL reactions, *CATALYSIS, *ELECTROPHILES, *MONOMERS
Abstract

The article presents a study which analyzes the role of hydrogen (H)-bonding amides in activating the electrophilicity of the lactide that induces the ring opening polymerization (ROP). It uses L-lactide as the monomer in investigating new H-bonding architectures for the ROP of lactide. Results show that through activated amides, organocatalyzed ROP of L-lactide can be achieved. It demonstrates the efficiency of hydrogen-bonding amide 1e as an organocatalyst for the ROP of L-lactide.

Published
2009
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