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Start Over Author "David J. Rawson" Topic catalysis
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3. A highly stereoselective synthesis of axially chiral biaryls. Application to the synthesis of a potential chiral catalysts

Author

David J. Rawson, Albert I. Meyers, and Anton Meier

Subjects
chemistry.chemical_compound, Chemical coupling, Chemistry, Reagent, Aryl, Organic Chemistry, Drug Discovery, Organic chemistry, Stereoselectivity, Biochemistry, Catalysis
Abstract

Excellent diastereoselectivities (⪢98:2) have been obtained in the biaryl coupling of 2′,6′,-disubstituted aryl Grignard reagents 1 with aryl oxazolines 6 , conveniently synthesised from the optically pure amino alcohols L-valinol and (S)-t-leucinol.

Published
1992

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