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Zwei Eisenspezies im Team: Ein NAD(P)H ‐ Modell wird in einer eisenkatalysierten Reduktion mit molekularem Wasserstoff in situ regeneriert. Die anschließende biomimetische Reduktion von α ‐ Keto ‐ und α ‐ Iminoestern liefert in Gegenwart einer Eisen ‐ basierten Lewis ‐ Base (LA) α ‐ Hydroxy ‐ bzw. α ‐ Aminosäureester in guten bis exzellenten Ausbeuten (siehe Schema; NAD(P)+=Nicotinamidadenindinucleotid(phosphat), TM=Übergangsmetall). [ABSTRACT FROM AUTHOR]

A highly selective reduction of N-acylated amino acid derivatives to the corresponding N-alkylated products is developed using PhSiH3 in the presence of a Rh(II)-catalyst. [ABSTRACT FROM AUTHOR]

Aryl, benzyl, and alkylcarboxylic acids endowed with a range of functional groups as well as dicarboxylic acids are efficiently reduced to the corresponding alcohols. [ABSTRACT FROM AUTHOR]

A molecular diagram is presented of Lewis acid induced ruthenium(II)-catalyzed etherifications by carboxylic acids or esters' selective hydrogenation.

An abstract of the article "Relay Iron/Chiral Broensted Acid Catalysis: Enantioselective Hydrogenation of Benzoxazinones" by L.-Q. Lu and colleagues is presented.

The article presents chemical equations related to the article "A General Catalytic Methylation of Amines Using Carbon Dioxide" by Y. Li and colleagues, published in the periodical "Angewandte Chemie International Edition" in 2013.

This method uses dual iron catalysis for the title reaction. [ABSTRACT FROM AUTHOR]