1. Methanol electrooxidation on flexible multi-walled carbon nanotube-modified sponge-based nickel electrode.
- Author
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Cheng, Xiaoli, Ye, Ke, Zhang, Dongming, Cheng, Kui, Li, Yiju, Wang, Bin, Wang, Guiling, and Cao, Dianxue
- Subjects
CARBON nanotubes ,FOMEPIZOLE ,CARBON foams ,CARBON nanofibers ,CARBON nanohorns - Abstract
Flexible and binder-free multi-walled carbon nanotube (MWNT)-modified sponge-based nickel (Ni) is employed as the electrode material for methanol (CHOH) electrooxidation. The nano-spherical Ni is electrodeposited on the surface of the MWNTs which are assembled on the skeleton of a commercial sponge. The as-prepared MWNT-modified sponge-based Ni electrode (MSNi) is characterized by scanning electron microscopy, transmission electron microscope, and X-ray diffractometer. The catalytic activity of the MSNi electrode for CHOH electrooxidation is investigated by means of cyclic voltammetry, chronoamperometry, and electrochemical impedance spectra. The preparation process of the flexible MSNi electrode does not use any binder and it exhibits a unique three-dimensional (3D) network-porous structure. The MSNi exhibits a high electrocatalytic performance of 23 mA (cm mg) in 0.5 mol dm CHOH at 0.5 V. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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