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The lignin-based carbon fibers were prepared by electrospinning followed by stabilization, carbonization, and activation (i.e., steam activation, one-step KOH activation, and metal activation). The effect of carbonization temperature on prepared carbon fibers (CFs) was investigated. As a result, 800 °C is the most suitable carbonization temperature because the prepared carbon fibers possess greater specific surface area and pore volume. With the help of various characterization methods, the structural characteristics of the activated carbon fibers (ACFs) prepared by the three activation methods and the adsorption performance of toluene were compared. It was observed that the activated carbon fibers prepared by KOH one-step activation method (ACFK) exhibited higher specific surface area (1147.16 m 2 /g) and greater toluene adsorption (463 mg/g). Particularly, abundant microporous structures and surface functional groups play a vital role in the adsorption process. Further, the adsorption performance of toluene onto ACFK was further investigated in a gas-phase dynamic adsorption system and the results showed that ACFK has great potential application in adsorption of volatile organic compounds.

The emission of mercury from coal combustion has caused consequential hazards to the ecosystem. The key challenge to abating the mercury emission is to explore highly efficient adsorbents. Herein, sulfur-functionalized carbon (S-C) was synthesized by using a molten-salt pyrolysis strategy and employed for the removal of elemental mercury from coal-combustion flue gas. An ideal pore structure, which was favorable for the internal diffusion of the Hg0 molecule in carbon, was obtained by using a SiO2 hard template and adjusting the HF etching time. The as-prepared S-C with an HF etching time of 10 h possessed a saturation Hg0 adsorption capacity of 89.90 mg·g−1, far exceeding that of the commercial sulfur-loaded activated carbons (S/C). The S-C can be applied at a wide temperature range of 25–125 °C, far exceeding that of commercial S/C. The influence of flue gas components, such as SO2, NO, and H2O, on the Hg0 adsorption performance of S-C was insignificant, indicating a good applicability in real-world applications. The mechanism of the Hg0 removal by S-C was proposed, i.e., the reduced components, including sulfur thiophene, sulfoxide, and C-S, displayed a high affinity toward Hg0, which could guarantee the stable immobilization of Hg0 as HgS in the adsorbent. Thus, the molten-salt pyrolysis strategy has a broad prospect in the application of one-pot carbonization and functionalization sulfur-containing organic precursors as efficient adsorbents for Hg0. [ABSTRACT FROM AUTHOR]

Porous carbons derived from one-pot carbonization and activation of wood sawdust in a molten salt (LiCl-KCl) medium were employed for Hg0 removal. The carbons derived from molten salt carbonization (MSC) displayed much superior Hg0 removal performance comparing with the carbons derived from N 2 pyrolysis method (NC). The best molar ratio of LiCl-KCl was 59:41, the optimal molten salt temperature was 700 °C, and the best mass ratio of wood sawdust to molten salt was 1:10. The MSC displayed good applicability at 50–125 °C. The saturation Hg0 adsorption capacity of MSC was about 7828.39 μg·g−1, far exceeding those for carbonaceous adsorbents reported in literatures. A Hg0 removal mechanism over MSC was proposed, i.e., the hierarchical porous structure accelerated mass transfer of Hg0, and the C O groups served as electron acceptors from Hg0 atoms to form organic matter bonded mercury (Hg-OM). The molten salt could be easily separated from the mixture of MSC for recycling multiple times. Thus, molten salt carbonization method appears to be promising in one-pot carbonization and activation of biomass as efficient adsorbents for gaseous Hg0. [Display omitted] • Porous carbon was prepared by one-pot carbonization and activation of biomass in molten salt. • The Hg0 adsorption capacity of porous carbon reached about 7828.39 µg·g−1. • The porous carbon can be adopted in a wide temperature range of 50–125 °C. • The spent molten salt can be effectively seperated with carbon for reusing. [ABSTRACT FROM AUTHOR]