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In the present study, adsorption of three metal ions Pb(II), Hg(II) and Cd(II) on carbon aerogel a new form of activated carbon has been investigated in mono- and multi-component (binary and tertiary) system. Batch experiments were also carried out for mono- and multi-component systems with varying metal ion concentration (mg/l) to investigate the competitive adsorption characteristics. Many adsorbents have been studied for their adsorption properties pertaining to mono-component solutions of metal ions. However, to treat wastewater with new materials, their performance needs to be ascertained in multi-component system. The scanning electron micrographs (SEM) and EDAX spectrum of carbon aerogel surfaces before and after the adsorbent was equilibrated with the metal ion solution clearly establishes the presence of the metal ions and some surface modifications can be observed on the carbon aerogel particles adsorption with (i) surface chemistry of the pellets on the surface of carbon aerogel and (ii) inside layers of the carbon aerogel. Applicability of the isotherm models namely Freundlich and Langmuir to predict the equilibrium uptake of Pb(II), Hg(II) and Cd(II) in mono-component, binary and tertiary system has also been tested. Langmuir and Freundlich models are found to generally represent the experimental though but not consistently.

Wastewaters discharged from the defence serviceable industries pose a serious environmental hazard due to their heavy metal load. The present study focused on optimizing the operational variables viz, hydraulic loading rate, bed height and feed concentration through bench scale study and using that for assessing the efficiency of pilot scale system with sulphur loaded carbon (AC-S) as the adsorbent in the removal of Pb (II). Static mode adsorption studies were also carried out for Pb (II) removal using treated (AC-S) and untreated carbon (AC). AC-S shows about 35 percent increase in maximum adsorption capacity over that on AC. The maximum adsorption capacity in the column mode for Pb (II) at the optimized conditions: bed height of 0.4 m, hydraulic loading rate of 7.5 m3h(-1)m(-2) and the feed concentration of 6 mg l(-1) for achieving 50% breakthrough concentration was found to be 2.89 mg g(-1). Adsorption mechanism involved during Pb (1) in the column has also been explored. Bohart-Adams model was used for modeling the bench scale data and predicting the adsorption behavior at pilot scale level.