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1. Chromic triboluminescence of self-assembled platinum(II) complexes.

Author

Sasaki, Kono, Saito, Daisuke, Yoshida, Masaki, Tanaka, Fuka, Kobayashi, Atsushi, Sada, Kazuki, and Kato, Masako

Subjects
PLATINUM, PHOTOLUMINESCENCE, CARBENES, VAPORS
Abstract

A series of Pt(II) complexes bearing N-heterocyclic carbenes, [Pt(CN)2(Rim-Mepy)] (Rim-MepyH+ = 3-alkyl-1-(4-methyl-(2-pyridinyl))-1H-imidazolium, R = Me, Et, iPr, or tBu), exhibits triboluminescence in the visible range from blue to red, as well as the corresponding intense photoluminescence. Remarkably, among the complexes, the iPr-substituted one exhibits chromic triboluminescence behaviour during the process of rubbing and also vapour exposure. [ABSTRACT FROM AUTHOR]

Published
2023
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