1. Thermodynamics of crystalline dimer of fullerene C60 in the range from T → 0 to 340 K at standard pressure
- Author
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B. V. Lebedev, L. S. Kashevarova, A. V. Markin, V. A. Davydov, and A. V. Rakhmanina
- Subjects
Standard enthalpy of reaction ,Standard molar entropy ,Dimer ,Enthalpy ,Thermodynamics ,Calorimetry ,Condensed Matter Physics ,Heat capacity ,Gibbs free energy ,chemistry.chemical_compound ,symbols.namesake ,chemistry ,Physics::Atomic and Molecular Clusters ,symbols ,Physical chemistry ,Physical and Theoretical Chemistry ,Thermal analysis ,Instrumentation - Abstract
By adiabatic vacuum calorimetry the temperature dependence of heat capacity for crystalline dimer of fullerene C 60 has been determined in the range 6–340 K at standard pressure. Between 46 and 56 K, a glass-like transition of the dimer, the nature of which is, probably, similar to that described for C 60 , has been found. The results were used to calculate the thermodynamic functions of the dimer: the heat capacity C p ∘ ( T ), enthalpy H ° ( T )− H ° (0), entropy S ° ( T )− S ° (0) and Gibbs function G ° ( T )− H ° (0) over the range from T →0 to 340 K. For T D in the heat capacity function of the multifractal variant of the Debye’s theory of heat capacity was estimated and in the 20–45 K range D was found to be 1. That indicates a chain structure of the dimer. The heat capacities of the dimer have been compared to those of the initial fullerite C 60 . The standard entropy of formation of the crystalline dimer from graphite, at T =298.15 K and at standard pressure, and the entropies of transition of the initial fullerite C 60 to the crystalline dimer have been calculated.
- Published
- 2003