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Molecular or supramolecular level photoluminescence (PL) modulation combining chemical and photonic input/output signals together in an integrated system can provide potential high-density data memorizing and process functions intended for miniaturized devices and machines. Herein, a PL-responsive supramolecular coordination cage has been demonstrated for complex interactions with redox-active guests. PL signals of the cage can be switched and modulated by adding or retracting Fc derivatives or converting TTF into different oxidation states through chemical or photochemical pathways. As a result, reversible or stepwise PL responses are displayed by these host-guest systems because of the occurrence of photoinduced electron-transfer (PET) or fluorescence resonance energy transfer (FREnT) processes, providing unique nanodevice models bearing off/on logic gates or memristor-like sequential memory and Boolean operation functions.

A Co-MOF, [Co3(HL)2·4DMF·4H2O] was simply synthesized through a one-pot solvothermal method. With the semiconductor nature, its band gap was determined to be 2.95 eV by the Kubelka–Munk method. It is the first trinuclear Co-MOF employed for photocatalytic hydrogen evolution and CO2 reduction with cobalt–oxygen clusters as catalytic nodes. Hydrogen evolution experiments indicated the activity was related to the photosensitizer, TEOA, solvents, and size of catalyst. After optimization, the best activity of H2 production was 1102 μmol/(g h) when catalyst was ground and then soaked in photosensitizer solution before photoreaction. To display the integrated design of Co-MOF, we used no additional photosensitizer and cocatalyst in the CO2 reduction system. When −NH2 was used for light absorption and a Co–O cluster was used as catalyst, Co-MOF exhibited an activity of 456.0 μmol/(g h). The photocatalytic mechanisms for hydrogen evolution and CO2 reduction were also proposed.

In this paper, a generalized conforming thick/thin plate element based on the quadrilateral area coordinate system called AATF-PQ4 is developed. Based on the governing equations of Mindlin-Reissner plate theory, the fundamental analytical solutions are first derived, then using this trial functions to formulate element AATF-PQ4. In the case of thin plate, this thick/thin plate element is degraded into corresponding thin plate element automatically and is free from shear locking. Numerical examples show that the proposed element, AATF-PQ4, has a good precision for thick and thin plate.

GA-Bp network model was proposed. GA was used to optimize the initial real values population of Bp network, and optimizing crossover fraction was fulfilled. In addition, the modified GA-Bp was applied to predict the deformation of the surrounding rock around tunnels.

To better understand the distributed characteristics of key minerals of China, a systematic analysis regarding the mining rights and prospecting rights for coal, iron, copper, aluminum, and other key minerals was done all over the country. The characteristics of the national mining rights of key minerals shows as followings: too much underground mining rights, less prospecting rights, the scale of mining rights is relative small and the geological distribution is unbalance. The analysis result can provide an important reference to mining rights management and mineral resource deployment.

A finite element method was developed to reveal the thermal characteristics of concrete with a cooling pipe, and the influence of cooling pipe on thermal field was calculated by the coupled fluid flow and solid heat transfer method. Temperature distribution along the pipeline was calculated and the mean Nusselt numbers on each section in the cooling pipe also were obtained. Numerical results show that the flow field and the temperature distribution were very complexly and the heat transfer was severely attenuated in the bend position, the outboard temperature of pipe was higher than the inboard temperature. In addition, in order to study the effect of the cooling pipe on thermal distribution, the temperature of different positions at the hydration time were compared with the no cooling results. The present results could be helpful to predict the temperature cracks in structure engineering.

The Equivalent Linear Method is a common way used in earthquake engineering to analyze nonlinear site seismic response, but the response under strong motion is underestimated by the way. For analyzing nonlinear response more veritably, in the study, a time-domain nonlinear analysis method was proposed and used in a case for 1D seismic response analysis of soil layers under strong motion. The results obviously showed that, comparing with true nonlinear method, the Equivalent Linear Method underestimated in the case in natural period range of common civil engineering structures. The true nonlinear method adopted in the study is more fitful for nonlinear response of soil layers under strong motion.