1. Overcoming diffusion limitations in supercapacitors using layered electrodes
- Author
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Ross Drummond, Stephen R. Duncan, Patrick S. Grant, and Chun Huang
- Subjects
Materials science ,Energy Engineering and Power Technology ,02 engineering and technology ,Carbon nanotube ,010402 general chemistry ,Electrochemistry ,01 natural sciences ,Capacitance ,Electric double layer structured electrodes ,law.invention ,Ion ,law ,Supercapacitors ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,Diffusion (business) ,Double layer (biology) ,Supercapacitor ,Renewable Energy, Sustainability and the Environment ,business.industry ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Electrode ,Optoelectronics ,Electrochemical modelling ,0210 nano-technology ,business - Abstract
The impact of multi-layered electrode microstructures on the dynamic capacitance of electrochemical double layer supercapacitors is investigated. An electrochemical model that describes ion diffusion and double layer dynamics across the layered electrodes is first developed and then matched to experimental data. With TiO2 particulate and carbon nanotube layered electrodes, two knee frequencies were observed in the real and imaginary capacitance plots in both experiment and model simulations. These two knee frequencies resulted in an increase in real capacitance at high frequencies (ω ≈ 100 − 102 rad s−1) but a reduction at lower frequencies (ω ≈ 10−2 rad s−1), with the response being largely insensitive to the relative layer thicknesses. The increased capacity at high frequencies was due to increased ion mobility across the electrodes caused by the layering, allowing diffusion limitations of identical homogeneous electrodes to be overcome. These results imply the suitability of layered electrodes for applications with highly dynamic charge profiles and/or relatively thick electrodes.
- Published
- 2019
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