1. Nanoplasmonic for Solar Energy Conversion Devices
- Author
-
J. Asad, H. Musleh, Ahmed Issa, Amal Al-Kahlout, Samy K. Shaat, N. Al-Dahoudi, and Nabil Kh. Shurrab
- Subjects
lifetime ,Engineering ,business.industry ,solar energy ,eosin Y ,Solar energy ,Engineering physics ,Electron recombination ,combustion synthesis ,renewable energy ,nanoplasmonic ,Renewable energy ,Joint research ,Solar energy conversion ,electron recombination ,business ,conversion device ,defects - Abstract
The effect of nanoplasmonic (Ag) on the performance of DSSCs has been studied in doped and undoped ZnO (DZ and UZ) NPs, which were prepared by the urea-assisted combustion route. Different techniques were conducted to characterize DZ and UZ NPs. XRD patterns were indexed to the hexagonal wurtzite structure of ZnO NPs (ICSD-52362). The values of average crystalline size of UZ and DZ(1.0 mol% Ag) NPs were 20.45 and 22.30 nm, respectively. HR-TEM micrograph revealed good crystallization with an intermediate or poor agglomeration with distribution of semispherical morphologies of ZnO NPs. The energy bandgap of UZ and DZ NPs was changed from 3.21 to 3.31 eV. The deconvolution of the PL spectra recognized eight peaks into near ultraviolet (NUV) and visible regions. The PL emission of visible region overshadowed NUV transition. The photovoltaic cell with the doped photoanode DZ:1.0 mol% Ag exhibited the best performance parameters:Voc = 0.46 V, Jsc = 7.81 mA.cm-2, Pm = 1.91, FF = 51%, and η= 1.91%. A double exponential function was used as a powerful fitting function for the TOCVD data.The results revealed that τn in the UZ NPs photoanode was longer than that in theDZ:1.0 mol% Ag NPs photoanode. The authors would like to thank the Palestinian German Joint Research Project PALGER2015-34-012 and the PHC Al Maqdisi grant No. 37038WF for their partially financial support of this research. The authors would, also, like to thank Mr. Ahmad Ashour for his technical assistant The effect of nanoplasmonic (Ag) on the performance of DSSCs has been studied in doped and undoped ZnO (DZ and UZ) NPs, which were prepared by the urea-assisted combustion route. Different techniques were conducted to characterize DZ and UZ NPs. XRD patterns were indexed to the hexagonal wurtzite structure of ZnO NPs (ICSD-52362). The values of average crystalline size of UZ and DZ(1.0 mol% Ag) NPs were 20.45 and 22.30 nm, respectively. HR-TEM micrograph revealed good crystallization with an intermediate or poor agglomeration with distribution of semispherical morphologies of ZnO NPs. The energy bandgap of UZ and DZ NPs was changed from 3.21 to 3.31 eV. The deconvolution of the PL spectra recognized eight peaks into near ultraviolet (NUV) and visible regions. The PL emission of visible region overshadowed NUV transition. The photovoltaic cell with the doped photoanode DZ:1.0 mol% Ag exhibited the best performance parameters:Voc = 0.46 V, Jsc = 7.81 mA.cm-2, Pm = 1.91, FF = 51%, and η= 1.91%. A double exponential function was used as a powerful fitting function for the TOCVD data.The results revealed that τn in the UZ NPs photoanode was longer than that in theDZ:1.0 mol% Ag NPs photoanode.
- Published
- 2019