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Centrifugal fans are suitable for the air supply of fuel cells because of their relatively high efficiency and low power consumption. Fuel cells are operated over a broad range of current densities, which is proportional to the air mass flow rate, i.e., the air supply system needs to provide high efficiencies over a wide range of mass flow. To achieve this target, a centrifugal fan equipped with a diffuser and volute with variable cross-sectional area is developed based on numerical simulations (CFD), laser-optical flow measurements (PIV) and performance measurements of the centrifugal fan. The geometrical variability is achieved by a movable backplate of the diffuser and the volute. The variable cross-sectional area of the diffuser and volute allows maintaining high efficiencies and pressure ratios for operating points at off-design. A small diffuser width is suitable for low mass flow rates, and a large diffuser width for high mass flow rates. Thus, efficiency of the centrifugal fan can be increased at part-load operation by up to 7.1% points by appropriately adjusting the diffuser width. As a result the parasitic power consumption of the air supply system is reduced and hence the overall efficiency of the fuel cell system increases.

The integration of cross-sectoral energy hubs into large-scale wind farms opens up existing structures to new applications and contributes to achieving renewable energy systems and climate protection targets. The offshore energy hub concept consists in establishing an artificially constructed energy conversion and distribution hub that addresses two energy-related markets by power supply to public grids and by potentially enabling the conversion of renewable electricity into hydrogen or ammonia and supplying it ashore. Hence, the energy hub concept enables smart integration of offshore wind power into gas grids. Power generation on demand from stored green gas is able to cover residual power loads at low carbon intensity. Electrofuel production provides also the opportunity to export renewable fuels for sectors with traditionally high greenhouse gas emissions, e.g., agriculture or transportation. In this contribution an energy hub system in the North Sea is modeled and simulated to determine production quantities and efficiencies of electricity, hydrogen and ammonia. When comparing the efficiencies of production, storage, and transport values of 45.1–65% for hydrogen and values of 52–52.3% for ammonia were determined. Re-conversion to electricity with fuel cells of both hydrogen and ammonia is less efficient and cost worthly than their use in electrofuel applications. Because of emerging and potential cost reductions a sensitivity analysis is performed where lower capital costs (50%) lead to cost reductions in hydrogen (42–45%) and ammonia production (40–42%). Results show that energy hubs can become sustainable pillars in future energy systems through improving cost-competitiveness of wind power.

A novel reactor of a natural gas (NG) fueled, 1 kW net power solid oxide fuel cell (SOFC) system with anode off-gas recirculation (AOGR) is experimentally investigated. The reactor operates as pre-reformer, is of the type radial reactor with centrifugal z-flow, has the shape of a hollow cylinder with a volume of approximately 1 L and is equipped with two different precious metal wire-mesh catalyst packages as well as with an internal electric heater. Reforming investigations of the reactor are done stand-alone but as if the reactor would operate within the total SOFC system with AOGR. For the tests presented here it is assumed that the SOFC system runs on pure CH 4 instead of NG. The manuscript focuses on the various phases of reactor operation during the startup process of the SOFC system. Startup process reforming experiments cover reactor operation points at which it runs on an oxygen to carbon ratio at the reactor inlet ( ϕ RI ) of 1.2 with air supplied, up to a ϕ RI of 2.4 without air supplied. As confirmed by a Monte Carlo simulation, most of the measured outlet gas concentrations are in or close to equilibrium.

The continuous expansion of renewable energy sources leads to changes in supply systems. More flexibility is necessary since the degree of dependency on volatile renewables increases. This new paradigm affects the runtime of conventional plants and a characteristic change of the residual load, which must be covered by controllable systems. State-of-the-art studies resolve the future flexibility challenge non-congruent because of their given viewing point. The contribution of this paper is an analysis on the sense of cogeneration plants as flexible supply option in Germany's urban energy systems. Results show that cogeneration operation is eligible to cover major fluctuations of the residual load and to avoid many issues, which arise from increasing decentral renewable power generation and relate to all sectors electricity, heat, gas, and mobility.

It is known that traffic related air contaminants cause power loss, decreasing lifetime or a complete failure of proton exchange membrane fuel cell (PEMFC). Therefore, the present study aims for a better understanding and the development of a data basis for further decisions in dealing with air contaminants for automobile applications. The first section provides an overview of scientific literature about the influence of important air contaminants on proton exchange membrane fuel cells (PEMFC). The second section describes an extensive study of air contaminants at possible automotive operating conditions using a full factorial matrix test. The specific variation of temperature, cell potential and harmful gas concentration resulted in 27 operating points for each used air contaminant. The gases NO, NO2, SO2, NH3, toluene and ethane were used. The results indicate significant degradation but as well the possibility of regeneration. The degradation caused by different harmful gases is both, dependent on temperature and potential. Furthermore, a clear difference of the influence of NO and NO2 at low concentrations could be shown. The experiments give an overview of the cathode harming potential of relevant air contaminants. Hence, the work provides a basis for the development of cathode air filter and regeneration techniques for automotive applications.

In this paper, the optimization of a power management strategy of a fuel cell/battery/supercapacitor hybrid vehicular system is investigated, both offline and in real time. Two offline optimization algorithms, namely, dynamic programming and Pontryagin's minimum principle, are first compared. The offline optimum is used as a benchmark when designing a real-time strategy, which is an inevitable step since the offline optimum is not real-time capable and is oriented only toward minimizing hydrogen consumption, which may result in the unnecessary overloading of the battery. The design and optimization of the real-time strategy makes use of a multiobjective genetic algorithm while taking into account, apart from hydrogen consumption, other important factors, such as the slow dynamics of the fuel cell system and minimizing the battery power burden. As a result, the real-time strategy is found to consume slightly more hydrogen than the offline optimum; however, it dramatically improves system durability.

The versatility of fuel cells enables a wide range of applications. Usually fuel cells are combined to stacks such that the reactant supply of the single cells is achieved via a pipe branching system, the manifold. The overall performance significantly depends on cell flow rates which are related to the fluidic interaction of the manifold and the cells. Computational Fluid Dynamics (CFD) simulations, which are often used to find a suitable design, lack experimental flow data for validation of the numerical results. To enable flow measurements within the small geometries of the manifold and to provide reliable velocity information inside a real fuel cell stack, a low-coherence Laser Doppler Anemometer (LDA) is applied, which uses multi-mode laser light to achieve a spatial resolution of

The possibility to use fuel cells as an electrical power source makes them interesting for a wide range of applications. In this work, computational fluid dynamics (CFD) simulations and optical measurements are performed to predict the flow distribution in a flow setup resembling the parallel flow circuits in fuel cell stacks. For the first time it is shown that by an adaptation of the port sizes in the inlet manifold to the individual fuel cells, the average global deviation between the flow rates can be reduced from 10.1% to 4.0% by means of a model experiment. The measurements are performed with a high resolution laser Doppler velocity profile sensor (LD-PS) specifically developed for measurements in small-scale channels, in this work 4 × 1 mm 2 , allowing for a spatial resolution below 2 μ m and relative velocity uncertainties below 0.1%, helping to resolve installation effects possibly occurring in fuel cells to improve their efficiency. The presented results can be used by manufacturers to increase the efficiency of their fuel cell stacks.

A simulation and control model for a two-step thermo-chemical water splitting cycle using metal oxids for the generation of hydrogen with a solar tower system as heat source has been developed. The simulation and control model consists of three main parts, the simulation of the solar flux distribution on the receiver, of the temperatures in the driven reactor modules and the produced hydrogen in the metal oxide. The results of the three parts of the simulation model have been evaluated by comparing and validating them with experimental data from the Hydrosol 100 kW th pilot plant at the Plataforma Solar de Almeria (PSA) in Spain. With the overall model of the hydrogen production plant that was created, an evaluation of the two-step thermochemical cycle process in combination with a solar tower system was performed. The model was used to perform parametric studies for the development of the plant and the operation strategies. For this purpose, a provision in the overall model was integrated. The simulation helps to reduce the frequency of using the flux measurement system and can be used for the heliostat field control, in particular for the temperature control in the solar chemical reactor modules. Because of these promising results the overall system model is being extended to enable a use as a control model with controller for the temperature control of the two core reactions in the process. The central control variable of the process control was the operating temperatures for the hydrogen production and the regeneration of the two modules. The process control with its PI controller turned out suitable to compensate diurnal changes of solar input power as well as certain statistical fluctuation due to cloud passage. At the same time the limits of the operability and controllability of the process became clear in terms of the minimum of solar power needed and maximum acceptable gradients. With this experience an operating strategy, the basic parameters of the system in operation, especially the starting up and shutdown procedures, regular operation and the response to disturbances were selected and optimized. With this operation/control strategy such a complex system can be operated in the future on a commercial scale automatically. The obtained results can also be adapted for other solar chemical processes.

In this paper, an experimental fuel cell/battery/supercapacitor hybrid system is investigated in terms of modeling and power management design and optimization. The power management strategy is designed based on the role that should be played by each component of the hybrid power source. The supercapacitor is responsible for the peak power demands. The battery assists the supercapacitor in fulfilling the transient power demand by controlling its state-of-energy, whereas the fuel cell system, with its slow dynamics, controls the state-of-charge of the battery. The parameters of the power management strategy are optimized by a genetic algorithm and Pareto front analysis in a framework of multi-objective optimization, taking into account the hydrogen consumption, the battery loading and the acceleration performance. The optimization results are validated on a test bench composed of a fuel cell system (1.2 kW, 26 V), lithium polymer battery (30 Ah, 37 V), and a supercapacitor (167 F, 48 V). OA gold

This work describes the development of a compact ethanol fuel processor for small scale high temperature polymer electrolyte membrane fuel cell (HT-PEMFC) systems with 200–500 W electrical power output. Promising markets for reformer fuel cell systems based on ethanol are mobile or portable leisure and security power supply applications as well as small scale stationary off grid power supply and backup power. Main components of the fuel processor to be developed were the reformer reactor, the shift converter, a catalytic burner and heat exchangers. Development focused in particular on the homogeneous evaporation of the liquid reactants ethanol and water for the reformer and burner and on the development of an efficient and autarkic start-up method, respectively. Theoretical as well as experimental work has been carried out for all main components separately including for example catalyst screening and evaporator performance tests in a first project period. Afterwards all components have been assembled to a complete fuel processor which has been qualified with various operation parameter set-ups. A theoretically defined basic operation point could practically be confirmed. The overall start-up time to receive reformate gas with appropriate quality to feed an HT-PEMFC (xCO

The current energy system is subject to a fundamental transformation: A system that is oriented towards a constant energy supply by means of fossil fuels is now expected to integrate increasing amounts of renewable energy to achieve overall a more sustainable energy supply. The challenges arising from this paradigm shift are currently most obvious in the area of electric power supply. However, it affects all areas of the energy system, albeit with different results. Within the energy system, various independent grids fulfill the function of transporting and spatially distributing energy or energy carriers, and the demand-oriented supply ensures that energy demands are met at all times. However, renewable energy sources generally supply their energy independently from any specific energy demand. Their contribution to the overall energy system is expected to increase significantly. Energy storage technologies are one option for temporal matching of energy supply and demand. Energy storage systems have the ability to take up a certain amount of energy, store it in a storage medium for a suitable period of time, and release it in a controlled manner after a certain time delay. Energy storage systems can also be constructed as process chains by combining unit operations, each of which cover different aspects of these functions. Large-scale mechanical storage of electric power is currently almost exclusively achieved by pumped-storage hydroelectric power stations. These systems may be supplemented in the future by compressed-air energy storage and possibly air separation plants. In the area of electrochemical storage, various technologies are currently in various stages of research, development, and demonstration of their suitability for large-scale electrical energy storage. Thermal energy storage technologies are based on the storage of sensible heat, exploitation of phase transitions, adsorption/desorption processes, and chemical reactions. The latter offer the possibility of permanent and loss-free storage of heat. The storage of energy in chemical bonds involves compounds that can act as energy carriers or as chemical feedstocks. Thus, they are in direct economic competition with established (fossil fuel) supply routes. The key technology here – now and for the foreseeable future – is the electrolysis of water to produce hydrogen and oxygen. Hydrogen can be transformed by various processes into other energy carriers, which can be exploited in different sectors of the energy system and/or as raw materials for energy-intensive industrial processes. Some functions of energy storage systems can be taken over by industrial processes. Within the overall energy system, chemical energy storage technologies open up opportunities to link and interweave the various energy streams and sectors. Chemical energy storage not only offers means for greater integration of renewable energy outside the electric power sector, it also creates new opportunities for increased flexibility, novel synergies, and additional optimization. Several examples of specific energy utilization are discussed and evaluated with respect to energy storage applications. The article describes various technologies for energy storage and their potential applications in the context of Germany’s Energiewende, i.e. the transition towards a more sustainable energy system. Therefore, the existing legal framework defines some of the discussions and findings within the article, specifically the compensation for renewable electricity providers defined by the German Renewable Energy Sources Act, which is under constant reformation. While the article is written from a German perspective, the authors hope this article will be of general interest for anyone working in the areas of energy systems or energy technology.

Online state classification of PEM fuel cell systems is a challenging task. While electrochemical impedance spectroscopy (EIS), the measurement of the 1kHz impedance, cyclic voltammetry, and the polarisation curve are the state-of-the-art in laboratory testing, it is hardly possible to install these analytic methods in application-oriented fuel cell systems. The necessary technical equipment is expensive, and hybridisation would be essential to create artificial operating conditions necessary during the measurement. A more economic solution for online state classification is the integration of a real-time model-based state classifier. A model, operating in parallel to the fuel cell, is able to provide extra information about the fuel cell such as the humidity of the membrane, which is not measurable in situ. On the other hand, online comparison of measurement data with the theoretical calculation allows us to detect malfunction of components. Based on a detailed model and a complex classification database, including error states of the system, it is possible to classify the state of a fuel cell or detect system errors. The voltage drift between classical physical models and a real fuel cell caused by irreversible degradation (platinum diversion, membrane thinning, carbon corrosion) and reversible degradation (contamination) is not yet completely understood, and therefore modelling so far remains imprecise. To avoid the misinterpretation caused by these constantly growing differences between the model and the reality, the described modelling approach has been focused on dynamic fuel cell reactions. Dynamic step responses of the fuel cell for abruptly changing operation conditions are being simulated in real time. The changing operation conditions may result from a real load cycle or, as for theses analyses, by forced stoichiometric steps. The comparison of the real and the simulated step responses is the basis for the state classifier and the controller to react. A conclusion of the series of measurement is shown, the model and its parameters are presented, and the opportunities of the state classifier and controller are discussed in this paper.

An attractive path to the production of hydrogen from water is a two-step thermo chemical cycle powered by concentrated sunlight from a solar tower system. In the first process step the redox system, a ferrite coated on a monolithic honeycomb absorber, is present in its reduced form while the concentrated solar energy hits the ceramic absorber. When water vapour is fed to the honeycomb at 800 °C, oxygen is abstracted from the water molecules, bond in the redox system and hydrogen is produced. When the metal oxide system is completely oxidised it is heated up for regeneration at 1100–1200 °C in an oxygen-lean atmosphere. Under those conditions and in the second process step, oxygen is set free from the redox system, so the metal oxide is being reduced and after completion of the reaction again capable for water splitting. Since the overall process consists of two core reaction steps, which need to be carried out sequentially in a reactor unit at two different temperature steps, a special process and plant concept had to be developed enabling the continuous supply of product regardless of the alternating nature of the solar reactor operation. The challenge of the process control is to keep the two core reaction temperatures constant and to ensure regular temperature switches after completion of the individual process steps, independent of the weather conditions, like DNI fluctuation, clouds and wind speed. Also start-up, the fast switching after completion of half-cycles and the shutdown must be controlled. State of the art is the manual switching of heliostats to fulfil those control tasks. This paper describes the development and use of a system model of this process. The model consists of three main parts: the simulation of the solar flux distribution at the receiver aperture, the simulation of the temperatures in the reactor modules and the simulation of the hydrogen generation. It can be used for the analysis of the operational behaviour. The model is intended to be used in the future for the control of the whole process.

The cogeneration of heat and power by means of a fuel cell based CHP unit is a promising option for efficient residential power supply. For most applications natural gas is used as fuel. One main component of such a CHP unit is a fuel processor in order to generate hydrogen from the natural gas with hydrogen thermal power output of about 6 kW. Usually the steam reforming process is used for hydrogen production. In order to meet the heat demand of the endothermic steam reforming process the fuel processor is equipped with a burner, which has to work with natural gas during start up phase and mainly with the low calorific anodic off gas of the fuel cell stack during normal operation. The presented work is focused on aspects of the main pollutant emissions (carbon monoxide and nitrogen oxide) of burners integrated into the reformer. Experimental investigations of two different burners, which were developed and adapted to the steam reformer requirements, in a real fuel processor environment show, that it is possible to operate both burner concepts with high and low calorific gases with very low pollutant emissions in order to compete with emissions of current heating boilers, which are in the range of 15 mg kWh−1 for CO and of 20 mg kWh−1 for NOx by adjusting suitable excess air ratios in the range of 1.2–1.4. But it is also demonstrated, that the efficiency of the fuel processor is influenced by the excess air ratio. An increase of the air ratio from 1.05 to 1.45 leads to an decrease of the efficiency from 80% to 76%. This results in a conflict of objectives between low pollutant emissions and high system efficiencies. The choice of a suitable burner concept and the definition of a suitable operation strategy can be based on the presented results. Additionally, aspects like fuel processor geometry, flame monitoring, pressure drop in the burner feed gas line as well as in the flue gas duct, investment costs and safety items have also to be considered for the burner selection.

Portable fuel cells are under development at present for remote off-grid applications, the first niche markets having notable numbers of pieces are military and leisure applications of the direct methanol fuel cell DMFC in the power range up to several hundreds of watts. Hydrogen-fuelled cells are not applicable yet due to missing refueling infrastructure. Different storage options are evaluated at present. Specially developed micro-fuel cells are an interesting alternative to batteries, particularly if extreme long and autarkic operation is required, but in fact the breakthrough of a marketable product has not yet been achieved.

With focus on mobile applications a fuel cell auxiliary power unit (APU) using liquefied petroleum gas (LPG) is currently being developed at the Centre for Fuel Cell Technology (Zentrum fur BrennstoffzellenTechnik, ZBT gGmbH). The system is consisting of an integrated compact and lightweight fuel processor and a low temperature PEM fuel cell for an electric power output of 300 W. This article is presenting the current status of development of the fuel processor which is designed for a nominal hydrogen output of 1 k W th , H 2 within a load range from 50 to 120%. A modular setup was chosen defining a reformer/burner module and a CO-purification module. Based on the performance specifications, thermodynamic simulations, benchmarking and selection of catalysts the modules have been developed and characterised simultaneously and then assembled to the complete fuel processor. Automated operation results in a cold startup time of about 25 min for nominal load and carbon monoxide output concentrations below 50 ppm for steady state and dynamic operation. Also fast transient response of the fuel processor at load changes with low fluctuations of the reformate gas composition have been achieved. Beside the development of the main reactors the transfer of the fuel processor to an autonomous system is of major concern. Hence, concepts for packaging have been developed resulting in a volume of 7 l and a weight of 3 kg. Further a selection of peripheral components has been tested and evaluated regarding to the substitution of the laboratory equipment.

At the Centre for Fuel Cell Technology (Zentrum fur BrennstoffzellenTechnik/ZBT GmbH) in Duisburg/Germany a 300 W fuel cell system of liquid gas-powered operation is currently being developed with focus on leisure boats. An excellent infrastructure in the domain of recreational activities is available for this fuel and users are familiar with the safe handling of liquid gas. On sailing yachts the consumption of electrical power is very restricted during long cruises because of low battery capacities. In this case an additional power supply based on the noiseless fuel cell technology promises an essential comfort increase without disturbing emissions. ZBT's engineers combined their experience in system simulation, reactor design for the gas process and fuel cell technology with the aim of developing a user friendly fuel cell product.

The University of Duisburg-Essen and the Center for Fuel Cell Technology (ZBT Duisburg GmbH) have developed a compact multi-fuel steam reformer suitable for natural gas, propane and butane. Fuel processor prototypes based on this concept were built up in the power range from 2.5 to 12.5 kW thermal hydrogen power for different applications and different industrial partners. The fuel processor concept contains all the necessary elements, a prereformer step, a primary reformer, water gas shift reactors, a steam generator, internal heat exchangers, in order to achieve an optimised heat integration and an external burner for heat supply as well as a preferential oxidation step (PrOx) as CO purification. One of the built fuel processors is designed to deliver a thermal hydrogen power output of 2.5 kW according to a PEM fuel cell stack providing about 1 kW electrical power and achieves a thermal efficiency of about 75% (LHV basis after PrOx), while the CO content of the product gas is below 20 ppm. This steam reformer has been combined with a 1 kW PEM fuel cell. Recirculating the anodic offgas results in a significant efficiency increase for the fuel processor. The gross efficiency of the combined system was already clearly above 30% during the first tests. Further improvements are currently investigated and developed at the ZBT.

The University of Duisburg–Essen has developed a compact multi-fuel steam reformer suitable for natural gas, propane and butane. This steam reformer was combined with a polymer electrolyte membrane fuel cell (PEM FC) and a system test of the process chain was performed. The fuel processor comprises a prereformer step, a primary reformer, water gas shift reactors, a steam generator, internal heat exchangers in order to achieve an optimised heat integration and an external burner for heat supply as well as a preferential oxidation step (PROX) as CO purification. The fuel processor is designed to deliver a thermal hydrogen power output from 500 W to 2.5 kW. The PEM fuel cell stack provides about 1 kW electrical power. In the following paper experimental results of measurements of the single components PEM fuel cell and fuel processor as well as results of the coupling of both to form a process chain are presented.

Fuel cells are under discussion for a large variety of applications as efficient and clean power generators today. In general, fuel cells are easily scalable due to their modular design and furthermore, the storage capacity and the output power can be combined independently. This enables the integration into portable devices or even in micro systems, which is favourable in those cases when batteries do not meet the respective demands. In particular, fuel cells offer advantages like variable geometry, high storage capacity, no self discharge and the potential for low production costs which make them interesting candidates for an environmentally friendly energy source [1].

The reforming of natural gas to produce hydrogen for fuel cells is described, including the basic concepts (steam reforming or autothermal reforming) and the mechanisms of the chemical reactions. Experimental work has been done with a compact steam reformer, and a prototype of an experimental reactor for autothermal reforming was tested, both containing a Pt-catalyst on metallic substrate. Experimental results on the steam reforming system and a comparison of the steam reforming process with the autothermal process are given.

Oil and gas are raw materials—the availability of which is prognosticated to run short in the near future. The peak oil discussion is an example generally perceived as proof of this development to come.

Fuel cell hybrid vehicles offer a high-efficiency and low-emission substitute for their internal combustion engine counterparts. The hybridization significantly improves the fuel economy of the vehicle; however, exploiting the hybridization requires a well-designed power management strategy that optimally shares the power demand between the power sources. This paper deals with the optimization of power management strategy of a fuel cell/battery hybrid vehicle, both off-line and in real-time. A new formulation of the optimization problem for the real-time strategy is presented. The new approach allows the optimization of the controller over a set of driving cycles at once, which improves the robustness of the designed strategy. The real-time optimization is applied to two forms of real-time controllers: a PI controller based on Pontryagin's Minimum Principle with three parameters and a fuzzy controller with ten parameters. The results show that the PI controller can outperform the fuzzy controller, even though it has fewer parameters. The real-time controllers are designed by simulation and then validated by experiment.

During the past decade several important development steps, such as the 700 bar hydrogen storage or the freeze start capability, have brought fuel cell electric vehicles close to market introduction. Further drive system cost reduction by e.g. simplification of the fuel cell system architecture are intended for future fuel cell vehicle generations. Removing the anode recirculation loop and operating the fuel cell stack in the so-called near-dead-ended1 mode is one promising concept. Key experiments focussed on the fuel cell stack's anode side under vehicular load conditions and temperature levels have been performed successfully while maintaining fuel consumption constraints. The impact of cathode operating conditions on the liquid water accumulation and hydrogen concentration on the anode side has been investigated by simulation in order to optimize the operation of this lean anode concept.

Significant advances have been reported in building and testing of high-temperature polymer electrolyte membrane (HTPEM) fuel cells and stacks during recent years. Quantity distribution measurement techniques (e.g. current density, temperature and electrochemical impedance spectroscopy (EIS)) using segmented cells are commonly used to characterise low-temperature PEM (LTPEM) fuel cells. Performing these measurements at higher temperatures is more difficult and a relatively new process. For this study, a fully operational segmented HTPEM fuel cell using a straight flow-field configuration was designed, constructed and tested. The cathode side bipolar half-plate consisted of 36 exchangeable segments, whereas, the anode side bipolar half-plate was not segmented. The cell was operated at various operating temperatures with various anode gas compositions and air (no backpressure). In addition to the experimental results, a simple computational fluid dynamics model based on COMSOL Multiphysics® 3.5a was used to support the observed behaviour during segmented measurements. The computational domain consisted of the cathode side gas channels and the porous media. All of the boundary conditions and gas properties were defined in a manner similar to the experimental investigations. Some of the theoretical results were compared to the experimental results and conclusions were drawn.

In the current work, three types of flow field structures were analysed: i) Fluid flow patterns such as uniformity in gas distribution in various channels of these flow fields were studied using particle image velocimetry (PIV) technique, ii) Pressure drop across each flow field structure was measured using standard anemometers, iii) Impedance of 3 single cells built with these three types of flow fields, each with a commercially available Celtec-P 1000 based membrane electrode assembly (MEA) was examined, to ensure, adequate contact between various cell components using electrochemical impedance spectroscopy (EIS) technique, iv) 3Dcomputational fluid dynamics (CFD) simulations were performed using a commercially available software to ascertain oxidant distribution in these flow fields. Finally, v) Experiments were performed in a test stand with these three types of single cells, (with hydrogen and air as reactant gases) to gauge each cell's overall performance. The active area of each cell was 27.6 cm². High temperature stable graphite compound based bipolar plates (FU 4369) from Schunk Kohlenstofftechnik GmbH, Germany were used in each cell.

High temperature polymer electrolyte membrane fuel cells (HT PEMFCs) offer tremendous flexibility when used as energy converters in stationary as well as mobile power devices. Coupling HT PEMFC stacks with fuel processors that use liquid as well as gaseous fuels to generate hydrogen rich gas is a promising prospect, which paves the way for a possible hydrogen economy. The current paper deals with the performance aspects of a 150 Wel HT PEMFC stack, which potentially could be coupled to (i) a natural gas reformer, (ii) a propane reformer, or (iii) a methanol reformer. A 12 cell HT PEMFC stack with a total active area of about 600 cm2 was operated in a test rack, and the results show that HT PEMFCs are principally suited for operation with reformates.

A review of the state-of-the-art of solid polymer fuel cell (SPFC) development is given. The international activities focus on cell performance and stack design, materials research and gas processing, depending on the application. The fastest progress is being made with respect to fuel cell development for transportation, but the specific advantages of SPFC make the system interesting for residential power supply systems, for on-site power production and also for small, portable power supplies.

Recent research concerning hydrogen technology focusses on membrane technology. Small electrolysers and fuel cells with high power density are attractive for many different applications such as transportation and energy storage for solar systems or other renewable energy sources. In order to lay the foundations of widespread applicatication, cost reduction must be achieved and a simple and reliable system must be designed. Various membrane/electrode units have been prepared and the results of electrolysis and fuel cell operation experiments are presented.

Results are reported on the flat band potential Vfb of the contact TiO2/CH3CN. The informations were taken from capacitance/voltage and photocurrent/voltage measurements. As electrolyte either pre-dried CH3CN or various mixtures of dried CH3CN with H2O were used. It was found that both the addition of H2O and illumination with band gap light affect Vfb considerably. – It could be shown that Vfb-values determined from photocurrent/potential measurements differ up to 2 V from values evaluated from capacitance/potential measurements taken on unilluminated electrodes. However, Vfb-values obtained from capacitance measurements on pre-illuminated electrodes agree well with data from photocurrent measurements. The results are discussed in terms of alterations of the inner Helmholtz plane. Finally, consequences of the observed Vfb shifts on the charge transfer process are outlined.