1. Data-driven parameter optimization for the synthesis of high-quality zeolitic imidazolate frameworks via a microdroplet route
- Author
-
Shane Albin, Jianping Chen, Wei-Ning Wang, Xiang He, and Zan Zhu
- Subjects
Materials science ,business.industry ,General Chemical Engineering ,media_common.quotation_subject ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Spray method ,0104 chemical sciences ,Data-driven ,Mechanics of Materials ,Mass transfer ,Quality (business) ,Computational analysis ,0210 nano-technology ,Process engineering ,business ,Zeolitic imidazolate framework ,media_common - Abstract
As an emerging strategy for the synthesis of metal-organic frameworks (MOFs), a microdroplet-based spray method holds merits of improved heat and mass transfer rates, which allows the formation of MOF crystals in a much faster manner. To optimize the spray route for the MOF synthesis, further exploration is needed to understand the dominant variables controlling the quality of the products. With a series of experiments and advanced computational analysis, we present here general guidance for the synthesis of representative zeolitic imidazolate frameworks (i.e., ZIF-8 and ZIF-67) using the spray route.
- Published
- 2021