1. Highly efficient solar-thermal storage coating based on phosphorene encapsulated phase change materials
- Author
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Waseem Aftab, Ali Usman, Xinyu Huang, Muhammad Khurram, Ruimin Yao, Ruqiang Zou, Zibin Liang, Wenhao Wu, Wenhan Guo, Qingfeng Yan, Shi Jinming, and Hassina Tabassum
- Subjects
Materials science ,Dopant ,Renewable Energy, Sustainability and the Environment ,business.industry ,Energy Engineering and Power Technology ,02 engineering and technology ,engineering.material ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Thermal energy storage ,01 natural sciences ,Energy storage ,0104 chemical sciences ,Renewable energy ,Phosphorene ,chemistry.chemical_compound ,Coating ,chemistry ,Latent heat ,Thermal ,engineering ,Optoelectronics ,General Materials Science ,0210 nano-technology ,business - Abstract
Solar-thermal energy storage using latent heat of phase change materials (PCMs) offers renewable penetration in wide range of smart applications. The limiting solar energy harvesting efficiency of existing photo-thermal dopant materials and their negative impact on thermal storage capacity have remained fundamental impediment to further advancement. Herein, we explore a phosphorene based bandgap engineered broadband photonic nanoheater for efficient thermal charging of solid-solid PCMs. In our devised composite system, we benefitted from the synergistic effect of highly efficient photonic energy harvesting characteristic of exfoliated phosphorene nanoflakes (PNF) and latent heat storage capability as well as encapsulating feature of PCM matrix. The solar-thermal energy storage efficiency of our developed materials exceeds 95 % even at lower phosphorene doping level (1 wt. %) and under full solar spectrum with improved latent heat storage capacity (150 J g−1). The achieved efficiency is highest among all photo-thermal storage materials and attributed to the intense and broadband solar absorbance of PNF featured by wide thickness distribution. Further, coating of developed solar heat storage material on fabric substrate has shown promising results toward real world applications.
- Published
- 2020