1. Strong adhesion and high optoelectronic performance hybrid graphene/carbon nanotubes transparent conductive films for green-light OLED devices
- Author
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Ze-Long Bao, Li-Chao Jing, Wenming Geng, Wen-Hao Geng, Lvyun Chen, Anita Sagadevan Ethiraj, Hong-Zhang Geng, Tao Wang, Qingxia Zhu, and Peng-Fei Qian
- Subjects
Materials science ,business.industry ,Graphene ,General Physics and Astronomy ,02 engineering and technology ,Surfaces and Interfaces ,General Chemistry ,Carbon nanotube ,Adhesion ,Green-light ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Exfoliation joint ,0104 chemical sciences ,Surfaces, Coatings and Films ,law.invention ,Anode ,law ,OLED ,Optoelectronics ,0210 nano-technology ,business ,Electrical conductor - Abstract
Carbon nanotubes (CNTs) and graphene (Gr) are promising materials for flexible transparent conductive films (TCFs) in optoelectronic application because of their exceptional electrical, optical, and mechanical properties. Here, high-quality graphene nanosheets were synthesized by the one-step green method which using natural polyphenols-gallic acid (GA) as the exfoliation medium through high-pressure homogenization; besides, GA molecules can also be used as a non-covalent modifier to obtain GA modified CNTs (GCNTs). Then, the Au decorated Gr/GCNT-PET (Au-Gr/GCNT-PET) TCFs were obtained by a simple spray-coating process. The TCFs exhibited an excellent optoelectronic performance (Rs = 45.6 Ω/sq., T = ca. 80% at 550 nm), relatively flat surface (roughness = 12.43 nm), good bending resistance (the ΔR Au-Gr/GCNT-PET TCF/R0 was 0.07 after 1000 times bending tests) and strong adhesion (the fT of all Au-Gr/GCNT PET films was higher than 0.8). Finally, the Au-Gr/GCNT-PET films were used as an anode to prepare flexible green-light OLED devices; the maximum luminance of the Au-Gr/GCNT-PET device was 6554.1 cd/m2 at 15V, and the maximum current efficiency was 4.03 cd/A. It confirmed that this type of TCFs has considerable potential application in photovoltaic devices.
- Published
- 2021