1. Highly luminescent CsPbX3 (X=Cl, Br, I) perovskite nanocrystals with tunable photoluminescence properties
- Author
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Haitao Chen, Anqi Guo, Xieyang Gu, and Min Feng
- Subjects
Nanostructure ,Materials science ,Photoluminescence ,business.industry ,Band gap ,Mechanical Engineering ,Metals and Alloys ,Quantum yield ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Full width at half maximum ,Nanocrystal ,Mechanics of Materials ,Materials Chemistry ,Optoelectronics ,0210 nano-technology ,Luminescence ,business ,Perovskite (structure) - Abstract
All-inorganic cesium lead halide perovskite nanostructures have become an outstanding luminous optoelectronic material for illumination and display. In this paper, we synthesized monodispersed colloidal single- and mixed-halide CsPbX3 (X = Cl, Br, I) nanocrystals with various morphologies and brightly luminescent properties. By varying the amount of PbX2 (X = Cl, Br, I), the prepared CsPbX3 nanocrystals possess high photoluminescence quantum yield (PLQY, about 70%), narrow full width at half-maximum (FWHM) (4–17 nm), tunable band gap (407–680 nm), and highly strong photostability. In addition, it is found that the PL decay lifetime of CsPbX3 nanocrystals ranged from 1 to 6 ns, and their PL mechanism was studied thoroughly. These corresponding results demonstrate that all-inorganic colloidal CsPbX3 perovskite nanocrystals are expected to have a promising application in the field of optoelectronic material.
- Published
- 2019
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