1. Identification by inelastic X-ray scattering of bulk alteration of solid dynamics due to liquid wetting.
- Author
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Warburton, M., Ablett, J.M., Rueff, J.-P., Baroni, P., Paolasini, L., and Noirez, L.
- Subjects
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BULK solids , *INELASTIC scattering , *ACOUSTIC phonons , *X-ray scattering , *INELASTIC neutron scattering , *WETTING , *LIQUIDS - Abstract
• An impact of the hydrophilic wetting on solid phonon dynamics is revealed by IXS. • Twofold impact: a depth-dependent hardening of acoustic phonons and an internal stress relaxation. • Therefore, a dynamic liquid/solid coupling is revealed, echoing mesoscopic liquid shear elasticity. We examine the influence at room temperature of the deposit of a water layer on the phonon dynamics of a solid. It is shown that the water wetting at the surface of an Alumina monocrystal has deep effects on acoustic phonons, propagating over several hundred µm distance and taking place on a relatively long time scale. The effect of the wetting at the boundary is two-fold: a hardening of both transverse and longitudinal acoustic phonons is observed as well as a relaxation of internal stresses. These acoustic phonon energy changes were observed by inelastic X-ray scattering up to 40 meV energy loss, allowing us to probe the solid at different depths from the surface. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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