13 results on '"Sokolov, Alexei P."'
Search Results
2. Tuning proton conductivity and energy barriers for proton transfer.
- Author
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Young-Gonzales, Amanda R., Paddison, Stephen J., and Sokolov, Alexei P.
- Subjects
ACTIVATION energy ,BROADBAND dielectric spectroscopy ,PROTONS ,PROTON-proton interactions ,GLASS transition temperature ,VISCOSITY ,PROTON conductivity - Abstract
Proton transport is critical for many technologies and for a variety of biochemical and biophysical processes. Proton transfer between molecules (via structural diffusion) is considered to be an efficient mechanism in highly proton conducting materials. Yet, the mechanism and what controls energy barriers for this process remain poorly understood. It was shown that mixing phosphoric acid (PA) with lidocaine leads to an increase in proton conductivity at the same liquid viscosity. However, recent simulations of mixtures of PA with various bases, including lidocaine, suggested no decrease in the proton transfer energy barrier. To elucidate this surprising result, we have performed broadband dielectric spectroscopy to verify the predictions of the simulations for mixtures of PA with several bases. Our results reveal that adding bases to PA increases the energy barriers for proton transfer, and the observed increase in proton conductivity at a similar viscosity appears to be related to the increase in the glass transition temperature (T
g ) of the mixture. Moreover, the energy barrier seems to increase with Tg of the mixtures, emphasizing the importance of molecular mobility or interactions in the proton transfer mechanism. [ABSTRACT FROM AUTHOR]- Published
- 2021
- Full Text
- View/download PDF
3. Correlation between the temperature evolution of the interfacial region and the growing dynamic cooperativity length scale.
- Author
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Cheng, Shiwang and Sokolov, Alexei P.
- Subjects
- *
BROADBAND dielectric spectroscopy , *GLASS transition temperature , *DIELECTRIC measurements , *SUPERCOOLED liquids , *TEMPERATURE , *HIGH temperatures - Abstract
We study experimentally the temperature evolution of the thickness of the interfacial layer, Lint(T), between bulk matrices and the surface of nanoparticles in nanocomposites through broadband dielectric spectroscopy. Analyses revealed a power-law dependence between the logarithm of structural relaxation time in the interfacial layer, τint(T), and the Lint(T): ln τ i n t (T) / τ 0 ∝ L i n t β (T) / T , with τ0 ∼ 10−12 s, and β index ∼0.67 at high temperatures and ∼1.7 at temperatures close to the glass transition temperature. In addition, our analysis revealed that the Lint(T) is comparable to the length scale of dynamic heterogeneity estimated from previous nonlinear dielectric measurements and the four-point NMR [ξNMR(T)], with Lint(T) ∼ ξNMR(T). These observations may suggest a direct correlation between the Lint(T) and the size of the cooperatively rearranging regions and have strong implications for understanding the dynamic heterogeneity and cooperativity in supercool liquids and their role in interfacial dynamics. [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF
4. Search for a Grotthuss mechanism through the observation of proton transfer.
- Author
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Popov, Ivan, Zhu, Zhenghao, Young-Gonzales, Amanda R., Sacci, Robert L., Mamontov, Eugene, Gainaru, Catalin, Paddison, Stephen J., and Sokolov, Alexei P.
- Subjects
PROTONS ,MOLECULAR dynamics ,LIGHT scattering ,NEUTRON scattering ,BROADBAND dielectric spectroscopy ,INTRAMOLECULAR proton transfer reactions ,PROTON transfer reactions ,HYDROGEN bonding ,PHOSPHORIC acid - Abstract
The transport of protons is critical in a variety of bio- and electro-chemical processes and technologies. The Grotthuss mechanism is considered to be the most efficient proton transport mechanism, generally implying a transfer of protons between 'chains' of host molecules via elementary reactions within the hydrogen bonds. Although Grotthuss proposed this concept more than 200 years ago, only indirect experimental evidence of the mechanism has been observed. Here we report the first experimental observation of proton transfer between the molecules in pure and 85% aqueous phosphoric acid. Employing dielectric spectroscopy, quasielastic neutron, and light scattering, and ab initio molecular dynamic simulations we determined that protons move by surprisingly short jumps of only ~0.5–0.7 Å, much smaller than the typical ion jump length in ionic liquids. Our analysis confirms the existence of correlations in these proton jumps. However, these correlations actually reduce the conductivity, in contrast to a desirable enhancement, as is usually assumed by a Grotthuss mechanism. Furthermore, our analysis suggests that the expected Grotthuss-like enhancement of conductivity cannot be realized in bulk liquids where ionic correlations always decrease conductivity. Although the Grotthuss mechanism of proton transfer is generally considered to be the most efficient means of proton transport, the search for experimental evidence of the mechanism has remained elusive and in certain cases confusing. Here, dielectric spectroscopy, quasieleastic neutron and light scattering, along with ab initio molecular dynamics simulations have been utilized to elucidate the mechanism of proton transfer in pure and 85% aqueous phosphoric acid. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
5. Influence of the Graft Length on Nanocomposite Structure and Interfacial Dynamics.
- Author
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Genix, Anne-Caroline, Bocharova, Vera, Carroll, Bobby, Dieudonné-George, Philippe, Chauveau, Edouard, Sokolov, Alexei P., and Oberdisse, Julian
- Subjects
BROADBAND dielectric spectroscopy ,INTERFACE dynamics ,SMALL-angle X-ray scattering ,MONTE Carlo method ,POLYMERIC nanocomposites ,SURFACE dynamics ,NANOCOMPOSITE materials - Abstract
Both the dispersion state of nanoparticles (NPs) within polymer nanocomposites (PNCs) and the dynamical state of the polymer altered by the presence of the NP/polymer interfaces have a strong impact on the macroscopic properties of PNCs. In particular, mechanical properties are strongly affected by percolation of hard phases, which may be NP networks, dynamically modified polymer regions, or combinations of both. In this article, the impact on dispersion and dynamics of surface modification of the NPs by short monomethoxysilanes with eight carbons in the alkyl part (C
8 ) is studied. As a function of grafting density and particle content, polymer dynamics is followed by broadband dielectric spectroscopy and analyzed by an interfacial layer model, whereas the particle dispersion is investigated by small-angle X-ray scattering and analyzed by reverse Monte Carlo simulations. NP dispersions are found to be destabilized only at the highest grafting. The interfacial layer formalism allows the clear identification of the volume fraction of interfacial polymer, with its characteristic time. The strongest dynamical slow-down in the polymer is found for unmodified NPs, while grafting weakens this effect progressively. The combination of all three techniques enables a unique measurement of the true thickness of the interfacial layer, which is ca. 5 nm. Finally, the comparison between longer (C18 ) and shorter (C8 ) grafts provides unprecedented insight into the efficacy and tunability of surface modification. It is shown that C8 -grafting allows for a more progressive tuning, which goes beyond a pure mass effect. [ABSTRACT FROM AUTHOR]- Published
- 2023
- Full Text
- View/download PDF
6. Revealing spatially heterogeneous relaxation in a model nanocomposite.
- Author
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Shiwang Cheng, Mirigian, Stephen, Carrillo, Jan-Michael Y., Bocharova, Vera, Sumpter, Bobby G., Schweizer, Kenneth S., and Sokolov, Alexei P.
- Subjects
NANOCOMPOSITE materials ,BROADBAND dielectric spectroscopy ,ATOMISM ,SIMULATION methods & models ,NANOPARTICLES - Abstract
The detailed nature of spatially heterogeneous dynamics of glycerol-silica nanocomposites is unraveled by combining dielectric spectroscopy with atomistic simulation and statistical mechanical theory. Analysis of the spatial mobility gradient shows no "glassy" layer, but the ɑ-relaxation time near the nanoparticle grows with cooling faster than the ɑ-relaxation time in the bulk and is ~20 times longer at low temperatures. The interfacial layer thickness increases from ~1.8 nm at higher temperatures to ~3.5 nm upon cooling to near bulk Tg. A real space microscopic description of the mobility gradient is constructed by synergistically combining high temperature atomistic simulation with theory. Our analysis suggests that the interfacial slowing down arises mainly due to an increase of the local cage scale barrier for activated hopping induced by enhanced packing and densification near the nanoparticle surface. The theory is employed to predict how local surface densification can be manipulated to control layer dynamics and shear rigidity over a wide temperature range. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
7. Ion transport and structural dynamics in homologous ammonium and phosphonium-based room temperature ionic liquids.
- Author
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Griffin, Philip J., Holt, Adam P., Katsuhiko Tsunashima, Sangoro, Joshua R., Kremer, Friedrich, and Sokolov, Alexei P.
- Subjects
STRUCTURAL dynamics ,IONIC liquids ,AMMONIUM ,PHOSPHONIUM compounds ,GLASS transition temperature ,BROADBAND dielectric spectroscopy ,QUASIELASTIC light scattering - Abstract
Charge transport and structural dynamics in a homologous pair of ammonium and phosphonium based room temperature ionic liquids (ILs) have been characterized over a wide temperature range using broadband dielectric spectroscopy and quasi-elastic light scattering spectroscopy. We have found that the ionic conductivity of the phosphonium based IL is significantly enhanced relative to the ammonium homolog, and this increase is primarily a result of a lower glass transition temperature and higher ion mobility. Additionally, these ILs exhibit pronounced secondary relaxations which are strongly influenced by the atomic identity of the cation charge center. While the secondary relaxation in the phosphonium IL has the expected Arrhenius temperature dependence characteristic of local beta relaxations, the corresponding relaxation process in the ammonium IL was found to exhibit a mildly non-Arrhenius temperature dependence in the measured temperature range--indicative of molecular cooperativity. These differences in both local and long-range molecular dynamics are a direct reflection of the subtly different inter-ionic interactions and mesoscale structures found in these homologous ILs. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
8. No fragile-to-strong crossover in LiCl-H2O solution.
- Author
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Nakanishi, Masahiro, Griffin, Philip, Mamontov, Eugene, and Sokolov, Alexei P.
- Subjects
AQUEOUS solutions ,LITHIUM chloride ,TEMPERATURE effect ,BROADBAND dielectric spectroscopy ,LIGHT scattering ,RELAXATION phenomena - Abstract
Dynamics of water, especially in the temperature range of the 'no man's land', remain a mystery. We present detailed study of dynamics in aqueous LiCl solution that is often considered as a model for bulk water. We employ broadband dielectric and light scattering spectroscopy in a broad frequency and temperature range. Our analysis reveals no sign of the fragile-to-strong crossover (FSC) neither in structural relaxation nor in translational motions. Our experimental results combined with a large selection of literature data lead to the clear conclusion-there is no FSC in dynamics of aqueous solutions at T ∼ 200-230 K. Instead, our analysis reveals appearance of the so-called excess wing at the high frequency tail of the structural relaxation peak. We discuss the localized nature of the relaxation process that contributes to the excess wing. [ABSTRACT FROM AUTHOR]
- Published
- 2012
- Full Text
- View/download PDF
9. Impact of hydration and temperature history on the structure and dynamics of lignin.
- Author
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Vural, Derya, Gainaru, Catalin, O'Neill, Hugh, Pu, Yunquiao, Smith, Micholas Dean, Parks, Jerry M., Pingali, Sai Venkatesh, Mamontov, Eugene, Davison, Brian H., Sokolov, Alexei P., Ragauskas, Arthur J., Smith, Jeremy C., and Petridis, Loukas
- Subjects
LIGNINS ,BROADBAND dielectric spectroscopy - Abstract
The full utilization of plant biomass for the production of energy and novel materials often involves high temperature treatment. Examples include melt spinning of lignin for manufacturing low-cost carbon fiber and the relocalization of lignin to increase the accessibility of cellulose for production of biofuels. These temperature-induced effects arise from poorly understood changes in lignin flexibility. Here, we combine molecular dynamics simulations with neutron scattering and dielectric spectroscopy experiments to probe the dependence of lignin dynamics on hydration and thermal history. We find a dynamical and structural hysteresis: at a given temperature, the lignin molecules are more expanded and their dynamics faster when the lignin is cooled than when heated. The structural hysteresis is more pronounced for dry lignin. The difference in dynamics, however, follows a different trend, it is found to be more significant at high temperatures and high hydration levels. The simulations also reveal syringyl units to be more dynamic than guiacyl. The results provide an atomic-detailed description of lignin dynamics, important for understanding lignin role in plant cell wall mechanics and for rationally improving lignin processing. The lignin glass transition, at which the polymer softens, is lower when lignin is cooled than when heated; therefore extending the cooling phase of processing and shortening the heating phase may offer ways to lower processing costs. [ABSTRACT FROM AUTHOR]
- Published
- 2018
- Full Text
- View/download PDF
10. Protein dynamics in a broad frequency range: Dielectric spectroscopy studies.
- Author
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Nakanishi, Masahiro and Sokolov, Alexei P.
- Subjects
- *
PROTEINS , *HYDRATION , *LYSOZYMES , *MYOGLOBIN , *SERUM albumin , *BROADBAND dielectric spectroscopy - Abstract
We present detailed dielectric spectroscopy studies of dynamics in two hydrated proteins, lysozyme and myoglobin. We emphasize the importance of explicit account for possible Maxwell–Wagner (MW) polarization effects in protein powder samples. Combining our data with earlier literature results, we demonstrate the existence of three major relaxation processes in globular proteins. To understand the mechanisms of these relaxations we involve literature data on neutron scattering, simulations and NMR studies. The faster process is ascribed to coupled protein–hydration water motions and has relaxation time ~ 10–50 ps at room temperature. The intermediate process is ~ 10 2 –10 3 times slower than the faster process and might be strongly affected by MW polarizations. Based on the analysis of data obtained by different experimental techniques and simulations, we ascribe this process to large scale domain-like motions of proteins. The slowest observed process is ~ 10 6 –10 7 times slower than the faster process and has anomalously large dielectric amplitude Δ ε ~ 10 2 –10 4 . The microscopic nature of this process is not clear, but it seems to be related to the glass transition of hydrated proteins. The presented results suggest a general classification of the relaxation processes in hydrated proteins. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
11. Decoupling charge transport from the structural dynamics in room temperature ionic liquids.
- Author
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Griffin, Philip, Agapov, Alexander L., Kisliuk, Alexander, Sun, Xiao-Guang, Dai, Sheng, Novikov, Vladimir N., and Sokolov, Alexei P.
- Subjects
CHARGE transfer ,STRUCTURAL dynamics ,IONIC liquids ,RELAXATION (Nuclear physics) ,BROADBAND dielectric spectroscopy ,LIGHT scattering ,THERMAL conductivity ,MODE-coupling theory (Phase transformations) ,DIFFUSION - Abstract
Light scattering and dielectric spectroscopy measurements were performed on the room temperature ionic liquid (RTIL) [C4mim][NTf2] in a broad temperature and frequency range. Ionic conductivity was used to estimate self-diffusion of ions, while light scattering was used to study structural relaxation. We demonstrate that the ionic diffusion decouples from the structural relaxation process as the temperature of the sample decreases toward Tg. The strength of the decoupling appears to be significantly lower than that expected for a supercooled liquid of similar fragility. The structural relaxation process in the RTIL follows well the high-temperature mode coupling theory (MCT) scenario. Using the MCT analysis we estimated the dynamic crossover temperature in [C4mim][NTf2] to be Tc ∼ 225 ± 5 K. However, our analysis reveals no sign of the dynamic crossover in the ionic diffusion process. [ABSTRACT FROM AUTHOR]
- Published
- 2011
- Full Text
- View/download PDF
12. Translation-rotation decoupling and nonexponentiality in room temperature ionic liquids.
- Author
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Griffin, Philip J., Agapov, Alexander L., and Sokolov, Alexei P.
- Subjects
- *
IONIC liquids , *PHASE transitions , *ROTATIONAL motion , *LIGHT scattering , *BROADBAND dielectric spectroscopy , *DIFFUSION , *IMIDAZOLES , *INTERMOLECULAR interactions - Abstract
Using a combination of light scattering techniques and broadband dielectric spectroscopy, we have measured the temperature dependence of structural relaxation time and self diffusion in three imidazolium-based room temperature ionic liquids: [bmim][NTf2], [bmim||PF6], and [bmim][TFA]. A detailed analysis of the results demonstrates that self diffusion decouples from structural relaxation in these systems as the temperature is decreased toward Tg. The degree to which the dynamics are decoupled, however, is shown to be surprisingly weak when compared to other supercooled liquids of similar fragility. In addition to the weak decoupling, we demonstrate that the temperature dependence of the structural relaxation time in all three liquids can be well described by a single Vogel-Fulcher-Tamann function over 13 decades in time from 10-11 s up to 102 s. Furthermore, the stretching of the structural relaxation is shown to be temperature independent over the same range of time scales, i.e., time temperature superposition is valid for these ionic liquids from far above the melting point down to the glass transition temperature. We suggest that these phenomena are interconnected and all result from the same underlying mechanism--strong and directional intermolecular interactions. [ABSTRACT FROM AUTHOR]
- Published
- 2012
- Full Text
- View/download PDF
13. Dynamics at the Polymer/Nanoparticle Interface inPoly(2-vinylpyridine)/Silica Nanocomposites.
- Author
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Holt, Adam P., Griffin, Philip J., Bocharova, Vera, Agapov, Alexander L., Imel, Adam E., Dadmun, Mark D., Sangoro, Joshua R., and Sokolov, Alexei P.
- Subjects
- *
VINYLPYRIDINE , *SILICA nanoparticles , *POLYMERIC nanocomposites , *DIFFERENTIAL scanning calorimetry , *BROADBAND dielectric spectroscopy , *TRANSMISSION electron microscopy - Abstract
The static and dynamic propertiesof poly(2-vinylpyridine)/silicananocomposites are investigated by temperature modulated differentialscanning calorimetry, broadband dielectric spectroscopy (BDS), small-angleX-ray scattering (SAXS), and transmission electron microscopy. BothBDS and SAXS detect the existence of an interfacial polymer layeron the surface of nanoparticles. The results show that whereas thecalorimetric glass transition temperature varies only weakly withnanoparticle loading, the segmental mobility of the polymer interfaciallayer is slower than the bulk polymer by 2 orders of magnitude. Detailedanalysis of BDS and SAXS data reveal that the interfacial layer hasa thickness of 4–6 nm irrespective of the nanoparticle concentration.These results demonstrate that in contrast to some recent articleson polymer nanocomposites, the interfacial polymer layer is by nomeans a “dead layer”. However, its existence might providesome explanation for controversies surrounding the dynamics of polymernanocomposites. [ABSTRACT FROM AUTHOR]
- Published
- 2014
- Full Text
- View/download PDF
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