1. Unveiling 79‐Year‐Old Ixene and Its BN‐Doped Derivative.
- Author
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Pati, Palas Baran, Jin, Eunji, Kim, Yohan, Kim, Yongchul, Mun, Jinhong, Kim, So Jung, Kang, Seok Ju, Choe, Wonyoung, Lee, Geunsik, Shin, Hyung‐Joon, and Park, Young S.
- Subjects
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SCANNING tunneling microscopy , *ORGANIC electronics , *BAND gaps , *ELECTRONIC structure , *POLYCYCLIC aromatic hydrocarbons , *BORON nitride - Abstract
Polycyclic aromatic hydrocarbons (PAHs) are key components of organic electronics. The electronic properties of these carbon‐rich materials can be controlled through doping with heteroatoms such as B and N, however, few convenient syntheses of BN‐doped PAHs have been reported. Described herein is the rationally designed, two‐step syntheses of previously unknown ixene and BN‐doped ixene (B2N2‐ixene), and their characterizations. Compared to ixene, B2N2‐ixene absorbs longer‐wavelength light and has a smaller electrochemical energy gap. In addition to its single‐crystal structure, scanning tunneling microscopy revealed that B2N2‐ixene adopts a nonplanar geometry on a Au(111) surface. The experimentally obtained electronic structure of B2N2‐ixene and the effect of BN‐doping were confirmed by DFT calculations. This synthesis enables the efficient and convenient construction of BN‐doped systems with extended π‐conjugation that can be used in versatile organic electronics applications. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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