1. Utilization of steel, pulp and paper industry solid residues in forest soil amendment: relevant physicochemical properties and heavy metal availability
- Author
-
Olli Dahl, Mikko Mäkelä, Gary Watkins, Hannu Nurmesniemi, and Risto Pöykiö
- Subjects
Paper ,Blast furnace ,Environmental Engineering ,Health, Toxicology and Mutagenesis ,Amendment ,Biological Availability ,Industrial Waste ,Industrial waste ,Trees ,Metal ,Nutrient ,Metals, Heavy ,Environmental Chemistry ,Soil Pollutants ,ta216 ,Waste Management and Disposal ,ta215 ,Environmental Restoration and Remediation ,Chemistry ,Slag ,Heavy metals ,Plants ,Pulp and paper industry ,Pollution ,Bioavailability ,Steel ,visual_art ,visual_art.visual_art_medium - Abstract
Industrial residue application to soil was investigated by integrating granulated blast furnace or converter steel slag with residues from the pulp and paper industry in various formulations. Specimen analysis included relevant physicochemical properties, total element concentrations (HCl+HNO3 digestion, USEPA 3051) and chemical speciation of chosen heavy metals (CH3COOH, NH2OH·HCl and H2O2+H2O2+CH3COONH4, the BCR method). Produced matrices showed liming effects comparable to commercial ground limestone and included significant quantities of soluble vital nutrients. The use of converter steel slag, however, led to significant increases in the total concentrations of Cr and V. Subsequently, total Cr was attested to occur as Cr(III) by Na2CO3+NaOH digestion followed by IC UV/VIS-PCR (USEPA 3060A). Additionally, 80.6% of the total concentration of Cr (370 mg kg(-1), d.w.) occurred in the residual fraction. However, 46.0% of the total concentration of V (2470 mg kg(-1), d.w.) occurred in the easily reduced fraction indicating potential bioavailability.
- Published
- 2010