Search

[Display omitted] • Ester-cleavage strategy was first applied to improve the TE performance. • Chemical doping and ester cleavage were realized synchronously. • Elevated crystalline domains were formed along with ester cleavage. • Power factor is enhanced about 15-fold by FeCl 3 -promoted ester-cleavage. Side-chain cleavage is an effective strategy to reconstruct the arrangement of polymer main chains, thus improving their electrical properties and corrosion stability. However, simultaneously realizing side-chain cleavage and chemical doping of polymer semiconductors have not been reported. Herein, a series of p-type polymer semiconductors with the incorporation of ester-cleavage groups (PBDTTT-TET x , X is the molar ratio of the cleavage ester groups and nondegradable alkyl groups) were designed and synthesized. The introduced functional ester side-chains on PBDTTT-TET 0.5 can be degraded by a commonly used p-type dopant FeCl 3 readily, resulting in the maximum 120-fold enhancement in electrical conductivity and 15-fold increase in power factor at the FeCl 3 concentration of 30 mM, compared to the reference one (PBDTTT-PET 0.5 with the nondegradable ester side-chains). Scanning electron microscopy, atomic force microscopy measurements and X-ray diffraction reveal that the increase of crystalline domains along with the side-chain cleavage contributes to the formation of (bi)polaron network. The improved doping efficiency can be reflected by their ultraviolet photoelectron spectroscopy and UV–vis-NIR spectroscopy results. Moreover, a further optimized power factor can be achieved for PBDTTT-TET 0.05 , which is 5.8 times higher than that of PBDTTT-TET. Therefore, molecule design strategy by incorporating FeCl 3 -cleavage ester groups into the π-conjugated backbones provided an effective approach to establish advanced TE materials. [ABSTRACT FROM AUTHOR]