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Abstract: The Early Jurassic was characterized by a global disturbance of the carbon cycle known as the Toarcian Oceanic Anoxic Event (T-OAE). This event is recorded worldwide by a negative excursion in marine and terrestrial carbon-isotope ratios, typically interrupting an overarching positive trend attributed to large-scale burial of marine organic matter under oxygen-depleted conditions. The negative excursion is attributed to introduction of isotopically light carbon into the ocean–atmosphere system. Three sections from the Ionian Zone in Greece have been analysed in terms of biostratigraphy, Total Organic Carbon (TOC), CaCO3, δ13Ccarb, δ18Ocarb and δ13Corg. On the basis of bio- and chemostratigraphy, the age of Pliensbachian–Toarcian formations from the Ionian Zone in Greece has been refined and the geochemical signature of the T-OAE recognized. All sections illustrate the characteristic negative excursion in carbon isotopes from both carbonates and organic matter and, in only one locality, a positive excursion has also been recorded. The recognition of the T-OAE in this part of the Tethyan continental margin offers additional information on the global impact and amplitude of this important Jurassic palaeoceanographic event. [Copyright &y& Elsevier]

The Early Toarcian (Early Jurassic, c. 183 Ma) was characterized by an Oceanic Anoxic Event (T-OAE), primarily identified by the presence of globally distributed approximately coeval black organic-rich shales. This event corresponded with relatively high marine temperatures, mass extinction, and both positive and negative carbon-isotope excursions. Because most studies of the T-OAE have taken place in northern European and Tethyan palaeogeographic domains, there is considerable controversy as to the regional or global character of this event. Here, we present the first high-resolution integrated chemostratigraphic (carbonate, organic carbon, δ13Ccarb, δ13Corg) and biostratigraphic (calcareous nannofossil) records from the Kastelli Pelites cropping out in the Pindos Zone, western Greece. During the Mesozoic, the Pindos Zone was a deep-sea ocean-margin basin, which formed in mid-Triassic times along the northeast passive margin of Apulia. In two sections through the Kastelli Pelites, the chemostratigraphic and biostratigraphic (nannofossil) signatures of the most organic-rich facies are identified as correlative with the Lower Toarcian, tenuicostatum/polymorphum–falciferum/serpentinum/levisoni ammonite zones, indicating that these sediments record the T-OAE. Both sections also display the characteristic negative carbon-isotope excursion in organic matter and carbonate. This occurrence reinforces the global significance of the Early Toarcian Oceanic Anoxic Event. [ABSTRACT FROM AUTHOR]