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Small-scale, distributed and low cost biomass power generation technologies are highly required in the modern society. The biomass pretreatment process, that is, a combination of carbonization and pelletization processes of cedar wood were explored in this study. For the carbonization process, a novel carbonizer composed of one carbonization chamber and one combustion chamber was tested, and the mass and energy balances during cedar wood carbonization at 400–500 °C were analyzed, respectively. During the initial heating stage, about 22 kg of wood with dry basis should be supplied into the combustion chamber through several batches. When the temperature in the carbonization chamber reached to the range of 200–220 °C, the combustion chamber could be self-heated by burning the pyrolysis gas (tar vapor, CH 4 , H 2 , CO) sent from the carbonization chamber. The specific wood consumption for producing 1 kg of wood char was within 3.6–4.4 kg, which presented an increase trend with increasing the carbonization temperature. Moreover, this carbonization system can deal with different kinds of biomass with various water contents and shapes. For the pelletization process, effects of adding amount of the binder (poval solution), water and the carbonization temperature on the pellet quality were studied so as to explore the optimal condition for making high quality pellets from the crushed wood char. The results indicated that there was an optimal ratio among char, added water, and the binder for making high quality pellets. Considering the energy transfer efficiency and pellet quality, the mass ratio of 0.93:0.32:0.10 for 450 °C-char in the dry basis: added water plus water in char: poval solution was the optimal condition for making high quality pellets. [ABSTRACT FROM AUTHOR]

In this study, corn straw and rice husk were hydrothermally carbonized at 180 °C and 240 °C. The effect of hydrothermal carbonization on the biomass/hydrochar characteristics, fate of heavy metals such as As, Cr, Pb, Ti, Cd, Zn, Fe, Cu, and Ni, global reactivity of the pyrolysis and gasification of biomass and hydrochar were investigated in a thermogravimetric analyzer, followed by kinetic modeling and reactivity prediction. Results showed that hydrothermal carbonization temperature 180 °C is more suitable for producing solid fuel in terms of low heavy metals content. Higher hydrothermal carbonization temperature (240 °C) decreased O/C content and improved various characteristics of the hydrochar such as coalification degree, carbon content, higher heating value and the specific surface area. While hydrothermal carbonization conducted at lower temperature of 180 °C, was advantageous for obtaining higher energy yield efficiency and hydrochar yield. The gasification reactivity of hydrochar was more sensitive to the heating rate than the pyrolysis process. The activation energy (E a) of the pyrolysis process varied significantly with conversion, whereas the gasification activation energy changes were insignificant. Based on the reactivity prediction, the hydrothermal carbonization effect on corn straw and rice husk was almost similar. The hydrochar generated under severe hydrothermal carbonization temperature (240 °C) showed higher thermal stability during pyrolysis in comparison with gasification. Compared with the gasification of rice husk hydrochar, hydrochar gasification of corn straw had lower E a , hence requires less energy to produce syngas. The results of this research imply that biomass hydrochar is a suitable alternative option to produce pulverized solid fuel. [Display omitted] • Gasification and pyrolysis of Agriculture residues-derived hydrochars were performed. • HTC improved coalification degree and carbon content and higher heating value. • 180 °C provided a higher hydrochar and energy yields with lower HMs content. • Changes of E a variation during pyrolysis and gasification by HTC were compared. • Gasification reactivity of CS was more sensitive to HTC temperature than that of RH. [ABSTRACT FROM AUTHOR]