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Biocomposites of a biopolymer and the coproduct of corn bioethanol industry, dried distillers' grains with solubles (DDGS), were produced by reactive melt extrusion and injection molding. The biopolymer matrix was a blend of polyhydroxy(butyrate- co-valrerate), PHBV, and poly(butylene adipate- co-terphthalate), PBAT. The effect of compatibilizer, polymeric methylene diphenyl diisocyanate (PMDI), and corn oil lubricant was studied. The change in melt processing force suggested the occurrence of chemical reactions during the processing. This hypothesis was further investigated by infrared spectroscopy by which the formation of urethane and urea bonds between DDGS and polymeric matrix was approved. Dynamic mechanical analysis confirmed the occurrence of crosslinks at PBAT-PHBV interface showing that the tan δ curves for PBAT and PHBV of the matrix shifted slightly towards each other. Moreover, the calculated parameter of interaction, A, from tan δ curves admitted the stronger bond at the DDGS-matrix interface as a result of addition of PMDI compatibilizer. Also, scanning electron microscopy images revealed improved interfacial adhesion at the DDGS-matrix interface as well as PBAT-PHBV interface within the matrix itself. The obtained crosslinked interfaces resulted in improvement in the strength, modulus, and elongation-at-break of biocomposites. Moreover, a synergism of PMDI and corn oil effects led to a dramatic improvement in impact strength of this biocomposite system so that the respective value for the prepared DDGS biocomposite increased from 75 to 212 J/m with addition of 1 % of PMDI and 3 % of corn oil. [ABSTRACT FROM AUTHOR]

Distiller's dried grains with solubles (DDGS), the main coproduct in the dry mill corn ethanol industry, is finding its way toward a reinforcing filler in polymeric composite applications. In such a journey, thermal stability of DDGS is a critical factor affecting both temperature window of DDGS melt-compounding with polymers and the properties of the final biocomposite material. In this study, DDGS thermal stability was enhanced by washing with water and then used to fabricate biocomposites with Poly(1, 4-butanediol succinate) (PBS). The thermal degradation of DDGS, before and after washing, was studied with thermogravimetric (TG) and derivative thermogravimetric (DTG) analyses, showing up to 50 °C improvement in degradation onset temperature of DDGS after washing. Also, the degradation activation energies for water-washed DDGS were smaller than the respective values for as-received DDGS. Compositional analysis and infrared spectroscopy showed that the water-washed DDGS was higher in protein and fiber content compared to as-received DDGS. As a result of improved thermal stability of DDGS after water-washing, the DDGS burning during melt processing was highly prevented and the biocomposites processed at 160 °C and 190 °C showed constant tensile properties. On the other hand, for as-received DDGS biocomposites the tensile properties decreased as the processing temperature increased. Moreover, the increased fiber content of DDGS after water-washing resulted in biocomposites with higher tensile strength and modulus compared to as-received DDGS biocomposites. [ABSTRACT FROM AUTHOR]