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Start Over Author "Martínez-Prieto, L. M." Topic biomacromolecules
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1. A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles.

Author

Martínez-Prieto, L. M., Urbaneja, C., Palma, P., Cámpora, J., Philippot, K., and Chaudret, B.

Subjects
*BETAINE, *NANOSTRUCTURED materials, *PLATINUM group, *RUTHENIUM compounds, *SUPRAMOLECULAR chemistry, *BIOMACROMOLECULES
Abstract

The betaine adduct of N-heterocyclic carbene and carbodiimide (ICy·(p-tol)NCN) was found to be a very efficient ligand to prepare very small (1–1.3 nm) ruthenium nanoparticles (RuNPs). The coordination of the ligand on the metal surface takes place through the carbodiimide moiety. The resulting RuNPs led to decarbonylation of THF and showed size selectivity for styrene hydrogenation. [ABSTRACT FROM AUTHOR]

Published
2015
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