1. Keggin-Type Polyoxometalate Cluster Functionalized with Dinuclear M-Hbiim (M = Cu, Ag) Metal-Organic Segments.
- Author
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Meng, Cui-Li, Zhang, Peng-Peng, Peng, Jun, Wang, Xiang, Shen, Yan, Liu, Ming-Guan, Wang, Dan-Dan, and Alimaje, Kundawlet
- Subjects
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POLYOXOMETALATES , *PHOTOLUMINESCENCE , *X-ray diffraction , *BLOCKS (Building materials) , *MAGNETISM - Abstract
Three inorganic-organic hybrid complexes, [Cu(Hbiim)(OH)](SiWO)·2HO ( 1), [Cu(Hbiim)](SiWO)·2HO ( 2) and [Ag(Hbiim)](SiWO)·2HO ( 3) (Hbiim = 2, 2′-biimidazole), have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, PXRD, TG and single-crystal X-ray diffraction. The crystallographic analysis reveals that in compounds 1- 3, the Keggin polyanions [ α-SiWO] act as inorganic building blocks, which are linked with the dinuclear metal-organic units via Cu-O bonds in compound 1, or through supramolecular interactions in compounds 2 and 3. Compound 1 shows a 3D supramolecular structure constructed by net-like layers. Compounds 2 and 3 display 2D layer structures which were composed of wave-like chains. In addition, these compounds show electrochemical activities, and photoluminescence properties are measured in the solid state. [ABSTRACT FROM AUTHOR]
- Published
- 2012
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