1. Cobaltacarborane–phthalocyanine conjugates: Syntheses and photophysical properties
- Author
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Li, Hairong, Fronczek, Frank R., and Vicente, M. Graça H.
- Subjects
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CARBORANES , *COBALT compounds , *PHTHALOCYANINES , *ORGANIC synthesis , *BENZENEDICARBONITRILE , *QUINOLINE , *ABSORPTION , *ORGANIC solvents - Abstract
Abstract: Syntheses of two new cobaltacarborane–phthalocyanine conjugates, one anionic (Pc 6) and one zwitterionic (Pc 7), were accomplished via cyclotetramerization of the corresponding cobaltacarborane-substituted phthalonitriles (4 or 5) with excess phthalonitrile in quinoline. X-ray structures of two phthalonitrile precursors (2 and 3) were obtained and are discussed, and the absorption and emission properties of the two cobaltacarborane–phthalocyanine conjugates in several solvents were investigated. The anionic conjugate 6 exists mainly as a monomer in polar organic solvents and has fluorescence quantum yields in the region 0.2–0.3. The zwitterionic conjugate 7 aggregates in solution and displays lower quantum yields ∼0.1 in organic solvents. [Copyright &y& Elsevier]
- Published
- 2009
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