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Start Over Author "Cervilla, Antonio" Topic benzene
2 results on '"Cervilla, Antonio"'

1. X-ray Structure of (Bu[sup n][sub 4]N)[Mo(1,2-Benzenedithiolate)[sub 3]. Trigonal-Prismatic....

Author

Cervilla, Antonio, Llopis, Elisa, Marco, Dolores, and Perez, Francisco

Subjects
*BENZENE, *MOLYBDENUM
Abstract

Examines the correlation between trigonal-prismatic (TP) and octahedral coordination in tris(1,2-benzenedithiolate) complexes. Role of molybdenum (Mo) in stabilizing TP tris(dithiolene) complexes; Characteristics of Mo; Determination of the terabutylammonium salts of anionic Mo.

Published
2001
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2. Reduction of Tris(benzene-1,2-dithiolate)molybdenum(Vl) by Water. A Functional Mo-Hydroxylase Analogue System.

Author

Cervilla, Antonio, Pérez-Pla, Francisco, Llopis, Elisa, and María Piles

Subjects
*BENZENE, *AROMATIC compounds, *MOLYBDENUM, *CHROMIUM group, *WATER, *PROTON transfer reactions, *ORGANIC chemistry
Abstract

MoVI (S2C6H4)3 reacts cleanly and completely with H2O in THF to afford [H3O] + [MoV (S2C6H4)3]-. Kinetic data were fit by the rate equation —d[MoVI (S2C6H4)3]/dt = κ[MoVI (S2C6H4)3]/[H3O+], which is consistent with a coupled electron—proton transfer mechanism involving a coordinated H2O molecule. The MoVI (S2C6H4)3 reduction is accelerated by the presence of PPh3 and affords OPPh3. 18O isotope tracing shows that H2O is the source of oxygen transferred to PPh3. [ABSTRACT FROM AUTHOR]

Published
2005
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