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1. Living alternating copolymerization of N-alkylaziridines and carbon monoxide as a route for synthesis of poly-beta-peptoids.

Author

Jia L, Sun H, Shay JT, Allgeier AM, and Hanton SD

Subjects
Aziridines chemistry, Molecular Mimicry, Peptoids, Polymers chemistry, Aziridines chemical synthesis, Carbon Monoxide chemistry, Peptides chemistry, Polymers chemical synthesis
Abstract

The title copolymerization catalyzed by BnCOCo(CO)4 affords poly-beta-alanoids in excellent yields and selectivity. The poly-beta-alanoids have narrow molecular weight distributions, controllable molecular weights, and definite end groups.

Published
2002
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